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Advanced Single-Atom Electrocatalyst design: Exploration, Evaluation and Evolution from fundamental insights

Objective

Single-atom catalysis has become one of the most active new frontier in heterogeneous catalysis, as well as electrocatalysis. Single-atom catalyst (SAC) represents the ultimate in atomic effiency to minimise the consumption of expensive metals (Pt, Pd, Rh, etc.). Single-atom electrocatalyst (SAEC) also draw public attention to develop cleaner energy technique such as fuel cell to replace traditional fossil fuel. Aided by recent advances in synthetic methodologies, characterization techniques and computational modelling, amounts of SACs have been developed which exhibit distinctive performances for amounts of reactions. SACs are known to have specific active centres which are strongly affected by surrounding coordination structure, such that unique opportunities exist for the rational design of new catalysts with high activities, selectivities and stabilities. However, due to inevitable heterogeneities in SACs such as the nature of active sites and their distribution, understand of structure-performance relationship at atomic level and rational designs from fundamental insights are still challenging.
Herein, we propose the use of the metal/supports SAC model system to understand the fundamental mechanisms, where we can precisely determine and even selectively modify the active site, and unravel the role of structure in catalytic activity. In this project, I describe how we will determine the sites that robustly anchor metal atoms on typical nitrogen doped carbon support in UHV, test their performance in newly-developing electrochemical cells, and further reveal reaction mechanism by in situ spectroscopy (IRAS, Raman) and theoretical calculation. The outcome will be promising to bridge the complexiy gap and recreate the optimal active sites on real SACs and lead the way into a new era where heterogeneous catalysts are designed based on fundermental insights.

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Keywords

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Programme(s)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) HORIZON-MSCA-2021-PF-01

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Coordinator

TECHNISCHE UNIVERSITAET WIEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 183 600,96
Address
KARLSPLATZ 13
1040 Wien
Austria

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Region
Ostösterreich Wien Wien
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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