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Photoelectrochemical Oxidation of Methane using Single Atom Catalysts

Objective

Natural gas (primarily methane, CH4) is still a major energy source that is often simply flared into the atmosphere without being harnessed. As a cumulative result, unprecedented CH4 spikes have been reported lately in Earths atmosphere. Combined with the already existing Global warming concerns posed by other greenhouse gases such as CO2, CO, NOx, etc., CH4 abundance will lead to a worldwide catastrophe. Various attempts to convert and utilize CH4 into useful chemicals in mild reaction conditions have only seen limited success. In this proposal, we aim to target the CH4 molecule by fixing the CO2 molecule to produce acetic acid [CH3COOH, a high-value industrial chemical - the global acetic acid market attained a value of over 8.7 billion EUR in 2020 and is expected to grow at a compound annual growth rate (CAGR) of 5.5% from 2022 to 2027] via Photoelectrochemistry (PEC, using light and electricity) employing a new generation of heterogeneous catalysts called Single Atom Catalysts (SACs, containing abundantly available single transition metal atom embedded on transition metal oxide semiconductors that can rival catalytic efficacy of a well-defined homogeneous catalyst). To achieve this goal, we will mainly study (1) different band-energies of SACs using optical and electrochemical methods; (2) select and examine appropriate SACs with band energies that can enable CH4 oxidation and CO2 reduction; (3) examine their selectivity, efficiency, and recyclability through catalyst and reaction optimizations; (4) characterize the best performing SACs and (5) decipher the reaction mechanism with the aid of computational methods. We will disseminate the results through papers, conference presentations, public outreach events, social media, etc., while gaining several scientific and transferable skills required for career progress. A new pathway towards methane valorization is foreseen through this project, which can be highly attractive in an academic and industrial setting.

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Keywords

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Programme(s)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) HORIZON-MSCA-2022-PF-01

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Coordinator

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 181 152,96
Address
AVENIDA PAISSOS CATALANS 16
43007 TARRAGONA
Spain

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Region
Este Cataluña Tarragona
Activity type
Research Organisations
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Total cost

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