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Functionalized porous organic cages for adsorption and photodegradation of per- and polyfluoroalkyl substances (PFAS)

Project description

Sustainable solution for PFAS removal from water

Energy consumption is rising, natural resources are running out, and pollution is damaging our environment. One of the major pollutants today is PFAS. These are ‘forever chemicals’ that do not break down naturally. These substances are harmful to health and can be found in water, air, and soil, causing widespread environmental damage. Current methods for removing PFAS from water have serious limitations, such as regenerating adsorbents and producing secondary waste. Supported by the Marie Skłodowska-Curie Actions programme, the PhotoClean project will create nanocage adsorbents that can remove PFAS from water. These adsorbents use visible light to break down PFAS in a safe, environmentally friendly way, offering a more sustainable solution for cleaning our water.

Objective

Increasing energy consumption, depletion of natural resources, and environmental pollution are nowadays among the biggest economic and social challenges. Per- and polyfluoroalkyl substances (PFAS), also known as forever chemicals, are persistent emerging pollutants not naturally degraded in the environment. PFAS are anthropogenic compounds with harmful health effects, inert and resistant to heat, and nowadays found in water, air, and soil, thus posing a heavy impact on our environment. Adsorption on activated carbon, ion-exchange resins, cyclodextrins, and nanofiltration are the methods currently used or under study for PFAS removal from water. However, critical gaps, such as the adsorbent regeneration, affinity, production of secondary waste, analytical method limitations, and efficient PFAS degradation pathways are major challenges. PhotoClean aims to synthesize novel palladium functionalized, solvent-responsive nanocage adsorbents able to remove PFAS from water. The nanocages will promote rapid PFAS photodegradation, being excited by visible-light to a photoexcited state able to interact with PFAS through a single electron transfer. Depending on the energy of the photoexcited state, PFAS decomposition is expected to be initiated either through oxidative or reductive events and be sustained by the formation of radicals. The new approach proposed by PhotoClean is based on the development of reusable adsorbent cages and the exploitation of visible-light as the energy source to activate PFAS decomposition; it thus constitutes an environmentally sustainable strategy for PFAS removal and degradation. The project will contribute to understand fundamental structure-property relationships of PFAS adsorption on nanoporous organic cages and integrate photodegradation of PFAS with catalytic activity. The action has the potential to revolutionize methods for PFAS removal from water and tackles a variety of scientific and societal challenges of environmental importance.

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2023-PF-01

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Coordinator

UNIVERSITA DEGLI STUDI DI PADOVA
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 188 590,08
Address
VIA 8 FEBBRAIO 2
35122 PADOVA
Italy

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Region
Nord-Est Veneto Padova
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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