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Unleashing Cellulose Potential: Laser-Driven Structural Modulation

Project description

Understanding cellulose’s potential to transform biopolymer processing

Cellulose is biodegradable and strong, but it cannot be processed using conventional thermoplastic methods due to its tendency to decompose before melting, a result of hydrogen bonding and hydrophobic interactions. The ERC-funded LaserCell project aims to transform biopolymer processing by advancing our understanding of cellulose and other biomaterials. The project will use infrared (IR) laser pulses to disrupt cohesive interactions within cellulose at the molecular level, effectively plasticising it by resonantly exciting specific bonds. By delivering short, high-power laser pulses without causing thermal damage, the project will explore how various laser parameters influence cellulose’s supramolecular structure. Additionally, it will develop tools to analyse these changes under mechanical loads, offering new avenues for cellulose-based materials.

Objective

LaserCell envisions an innovative approach to reshape and rearrange cellulose at the molecular level by
disrupting cohesive interactions through resonant excitation of specific bonds. It will revolutionize the field of
biopolymer processing beyond cellulose and yield fundamental insights into supramolecular structure and
dynamics in biomaterials.
Although cellulose is biodegradable and mechanically strong, it cannot be processed by conventional
thermoplastic polymer methods, which limits its use as high-volume material. Cellulose decomposes before it
melts because of cooperative intermolecular hydrogen bonding and hydrophobic interactions. To plasticise
cellulose, I propose to disrupt these intermolecular bonds with photon energy delivered by infrared (IR) laser
pulses. Employing wavelengths matching specific vibrational modes, the photon energy will be resonantly
absorbed, thus effectively plasticising cellulose. I envision that the rapid energy dissipation in short pulses will
deliver enough peak power to disrupt the intermolecular bonds yet avoiding thermal damage.
I plan to systematically investigate how laser parameters influence the supramolecular structure of cellulose
and establish analytical tools to characterize its structural transitions under mechanical load. Additionally, to
allow processability in different set-ups, I aim to prolong the time window of plasticization and adjust the
flowability, by using the laser irradiation in synergy with the hydrogen disrupting molecules. As a proof of
concept, I will implement this novel photo-plasticization technique into a cellulose fibre spinning process and
post-treatment to modulate the cellulose fibre crystallinity.
I have worked for 10 years on cellulose-based materials and have a strong background in fibre spinning and
material science. My research group will engage 1 PhD student and 2 Postdocs with background in polymer
science and laser physics and technology.

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Programme(s)

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Topic(s)

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HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

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(opens in new window) ERC-2024-STG

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Host institution

TECHNISCHE UNIVERSITAET MUENCHEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 499 969,00
Address
Arcisstrasse 21
80333 Muenchen
Germany

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Region
Bayern Oberbayern München, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 499 969,00

Beneficiaries (1)

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