Project description
Porous organic cages for covalent organic framework porosity
Rising levels of carbon dioxide (CO2) and methane (CH4) pose a threat to global climate stability. CO2 retains heat in the long term, while CH4 is over 25 times more potent than CO2 in warming the atmosphere over a century. With the support of the Marie Skłodowska-Curie Actions programme, the POCOF-CO2 project will transform covalent organic frameworks (COFs) by using porous organic cages (POCs) as monomeric units. These POCs will enhance the porosity, stability, and catalytic efficiency of COFs, thereby improving their gas capture capabilities. The project will simplify production and strengthen the stability of POCs compared to traditional methods through a one-pot multicomponent reaction, thereby increasing chemical stability and yield.
Objective
The escalating atmospheric levels of carbon dioxide (CO2) and methane (CH4) pose a critical threat to global climate stability, with CO2 contributing to prolonged thermal retention and CH4 exhibiting over 25 times the global warming potential of CO2 on a per-molecule basis over a century. To address these pressing challenges, the POCOF-CO2 project aims to revolutionize Covalent Organic Framework (COF) through the integration of Porous Organic Cages (POCs) as monomeric units. The project hypothesizes that POCs, with their precisely engineered cavities and functional groups, will significantly enhance the porosity, stability, and catalytic efficiency of COFs, thereby optimizing their gas capture capabilities. The project aims to optimize POC synthesis through a streamlined one-pot multicomponent reaction to enhance chemical stability and yield, integrate these POCs into COFs to improve structural diversity, stability, and scalability, and rigorously evaluate the COFs for CO2 capture and CO2/CH4 separation using advanced analytical techniques such as temperature-programmed desorption and sophisticated spectroscopy. The innovative one-pot MCR approach not only enhances POC stability but also simplifies production processes compared to conventional multi-step methodologies. This integration of MCR-derived POCs into COFs establishes a new benchmark in COF technology, offering unprecedented stability and performance. Advanced characterization techniques will deliver in-depth mechanistic insights into CO2 capture, addressing existing limitations and pushing the boundaries of COF research. The POCOF-CO2 project represents a significant leap forward in material science and environmental technology, contributing to global climate mitigation efforts and providing transformative applications in catalysis, energy storage and environmental remediation.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences catalysis
- natural sciences chemical sciences organic chemistry aliphatic compounds
- natural sciences physical sciences optics spectroscopy
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Keywords
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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HORIZON.1.2 - Marie Skłodowska-Curie Actions (MSCA)
MAIN PROGRAMME
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Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships
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Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
(opens in new window) HORIZON-MSCA-2024-PF-01
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Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.
10623 Berlin
Germany
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.