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SPEctrally Resolved Action PHOtocurrent Ultrafast Spectroscopy

Project description

Resolving bound states to improve organic solar cell performance

Due to their versatility, low-cost production and low carbon footprint, organic solar cells (OSCs) are promising for capturing light energy. With up to 20 % power conversion efficiency, their capability is still limited by bound states that cause photocurrent losses. Attempts to better understand the dynamics of these bound states have fallen short and, instead, require the use of multiple advanced techniques, mathematical tools and modelling. Supported by the Marie Skłodowska-Curie Actions programme, the SPERAPHOUS project aims to boost the efficiency of OSCs by developing novel design rules. To do so, it will combine experience in photocurrent spectroscopy on optoelectronic devices under operating conditions with expertise in ultra-fast multidimensional spectroscopy to spectro-temporally characterise bound states in OSCs.

Objective

With the rise in global warming, transitioning to renewable energy is more necessary than ever. Organic solar cells (OSC), with their flexibility and lower production costs and footprint, offer promising platforms for efficient light harvesting and net zero greenhouse gas emission. While OSCs nowadays depict 20% power conversion efficiencies, their performance is hindered by the bound states leading to photocurrent losses as they cannot provide free charge carriers. Efforts have been made to understand these bound states such as bound excitons, bound charge transfer states, and localized polarons as mitigating them could boost efficiency. However, identifying and analysing their dynamics requires extensive experimental work involving various techniques, mathematical tools, and modelling, further complicated by linking experimental results to device performance. Herein, by combining my expertise in photocurrent spectroscopy on optoelectronic devices under operando conditions with the host’s expertise in ultrafast multidimensional spectroscopy, I propose the SPEctrally Resolved Action PHOtocurrent Ultrafast Spectroscopy (SPERAPHOUS). This will spectro-temporally characterize bound states in OSCs under operando conditions ultimately leading to the development of design rules to improve OSCs efficiency. To achieve this, an interferometric system combined with ultrafast pulses, providing the spectro-temporal information, will be applied on Non-Fullerene Acceptor (NFA): Donor OSCs whose photocurrent response will be measured. SPERAPHOUS will contribute to the OSC research community and pave the way for investigating other optoelectronic devices, such as those based on perovskites and two-dimensional materials. Furthermore, through SPERAPHOUS, I will gain new knowledge and skills in ultrafast multidimensional spectroscopy, and I will enhance my academic skills broadening my scientific background leading to research independence.

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2024-PF-01

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Coordinator

POLITECNICO DI MILANO
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 193 643,28
Address
PIAZZA LEONARDO DA VINCI 32
20133 Milano
Italy

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Region
Nord-Ovest Lombardia Milano
Activity type
Higher or Secondary Education Establishments
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Total cost

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