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Dynamics, Excitations and Phase transitions of Two-Dimensional encapsulated noble-gas clusters

Project description

Improved techniques to investigate the dynamics of 2D noble gas clusters

Studying how atoms behave in 2D systems has been a key focus in physics for decades. Noble gases, with their simple atomic interactions, are ideal for exploring these phenomena. Early experiments at cryogenic temperatures laid the groundwork but recent advances in graphene technology allowed researchers to trap noble gases between two graphene layers at elevated temperatures. This breakthrough enables the observation of their atomic arrangement and dynamics, revealing unexpected behaviours – unusual diffusion patterns, surprising fluidity in large clusters and small clusters deviating from typical atomic arrangements. With the support of the Marie Skłodowska-Curie Actions programme, the DEPT2D project will use cutting-edge microscopy and spectroscopy to investigate how these 2D clusters evolve under different conditions, offering new insights into 2D physics and confined materials.

Objective

Noble gases are governed by the weak and well-understood van der Waals interaction which makes them an excellent model system for different physical phenomena. Condensed noble gases on surfaces at cryogenic temperatures were the first experimental examples of 2D systems back in the 1960s. By encapsulating them between graphene and a substrate in the 2010s, these structures could also be studied at elevated temperatures via STM. However, here the encapsulation layer often obscures the arrangement of trapped atoms. I recently showed that by trapping noble gases between two graphene layers, the atoms can be observed directly via transmission electron microscopy (Längle et al. 2024, Nature Materials). This provides direct insight into the atomic arrangement and dynamics of this system with surprising properties:

* Anomalous diffusion governed by defects in the encapsulating membrane was observed, mimicking diffusion through a 2D glass.
* Clusters become more fluid when they grow, contrary to what is expected in nanomaterials.
* For small clusters, the atomic arrangement deviates from the close-packed hexagonal structure indicating deviations from the assumed isotropic van der Waals interaction.

In this project, I will track the structure of 2D noble gas clusters in time and space using a laser pump-probe setup in a scanning transmission electron microscope, which provides atomic-scale imaging with nanosecond temporal resolution. With this, I will study the diffusion, atomic arrangement, orientational order, symmetry breaking, and phase transitions of 2D clusters as a function of size, temperature, and pressure. Additionally, the bonding, electronic structure and band gap of these clusters under the same conditions will be probed by monochromated electron energy loss spectroscopy.

This will contribute to the fundamental understanding of 2D physics with exciting possibilities for basic condensed-matter research opening avenues toward other 2D confined systems.

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2024-PF-01

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Coordinator

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 226 420,56
Total cost

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