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Advanced conversion of sulphate salts in circular hydrometallurgy

Project description

Circular hydrometallurgical process for sodium and ammonium sulfate waste

The EU aims for climate neutrality by 2050. This requires the electrification of sectors such as mobility and energy. Lithium-ion batteries (LIBs) play a crucial role in this transition. To boost strategic autonomy, the EU sets targets for domestic extraction (10 %), processing (40 %), and recycling (25 %) of battery materials. A significant challenge for companies is managing sulphate waste generated during lithium extraction and LIB recycling. The EU-funded ADONIS project aims to demonstrate a salt splitting process that transforms sodium sulfate into sodium hydroxide and sulfuric acid, and ammonium sulfate into ammonia and sulfuric acid through simple inorganic reactions at moderate temperatures. This circular hydrometallurgical process could resolve sodium and ammonium sulfate waste issues for EU companies.

Objective

The EU aims to achieve climate neutrality with net-zero greenhouse gas emissions by 2050, necessitating the electrification of key sectors like mobility and energy. Lithium-ion batteries (LIBs) are crucial for this transition. To enhance strategic autonomy amid global competition and an increasingly hostile geopolitical context, the EU targets more strategic autonomy along the entire mine-to battery supply chain. This implies minimum targets for domestic extraction (10%), processing (40%) and recycling (25%) of battery raw materials. Given the strict environmental limits EU companies need to respect, a significant challenge in this mine-to-battery(-recycling) supply chain is the generation of large sulphate waste streams. Sodium sulphate is produced during lithium extraction from spodumene ores, cobalt and nickel sulphate refining, precursor cathode active material (pCAM) production for nickel-manganese-cobalt (NMC) batteries, and LIB recycling. Similarly, lithium-iron-phosphate (LFP) battery production generates ammonium sulphate waste. Addressing these waste streams economically is a major challenge for EU metallurgical and battery (recycling) companies. Prof. Koen Binnemans (KU Leuven, Belgium) proposed a solution, filing a European priority patent on July 18, 2024. The patent describes a “salt splitting process” that converts sodium sulphate into sodium hydroxide and sulphuric acid, and ammonium sulphate into ammonia and sulphuric acid, using simple inorganic reactions at moderate temperatures. The invention is a prime example of a “circular hydrometallurgical process”. The ADONIS project aims to provide the proof-of-concept for this process, while demonstrating its environmental and techno-economic superiority. If successful, ADONIS could solve the sodium and ammonium sulphate waste problem for many EU companies, enhancing their ESG credentials and easing permit acquisition. Commercialising this technology would boost the EU’s envisaged strategic autonomy.

Fields of science (EuroSciVoc)

Programme(s)

Topic(s)

Funding Scheme

HORIZON-ERC-POC - HORIZON ERC Proof of Concept Grants

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Call for proposal

(opens in new window) ERC-2025-POC

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Host institution

KATHOLIEKE UNIVERSITEIT LEUVEN
Net EU contribution
€ 150 000,00
Address
OUDE MARKT 13
3000 Leuven
Belgium
Region
Vlaams Gewest Prov. Vlaams-Brabant Arr. Leuven
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data

Beneficiaries (1)