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Structure and Function: The Development and Application of Novel Ex- and In-situ NMR Approaches to Study Lithium Ion Batteries and Fuel Cell Membranes

Objective

Two new research programs will be established at Cambridge University: 1. Lithium ion batteries (LIBs). New positive and negative electrode materials are required for a range of LIB applications, which are lighter, have higher capacities, and can be operated at higher rates. To this end, I will establish a joint synthesis and characterization program, aimed at understanding how LIB-materials function and sometimes fail, in order to provide the fundamental insight required to design the next generation of LIBs. In particular we will use NMR spectroscopy, with other relevant characterization tools, including pair distribution function analysis, to investigate structure and Li dynamics. The specific objectives are (i) to develop novel in situ NMR techniques to investigate LIBs under realistic operating conditions, including the very high rates required for batteries for transportation. (ii) Utilize these methodologies to investigate a wide range of electrode systems, including conversion reactions, doped phosphates and composite electrodes. 2. Electrolytes for Solid Oxide Fuel Cells. This smaller program will investigate both oxygen and proton transport in ceramic materials, focusing on doped perovskites. Identification of the differences between the local structures of the ions that contribute to the ionic conductivity, and those that remain trapped in the lattice, represents a challenge for many experimental structural probes. Our objectives are to use NMR techniques to determine local structure and motion, in order to identify (i) how doping controls structure and (ii) the conduction mechanisms responsible for ionic conductivity. For the proton conductors, we will determine mechanisms for proton incorporation and investigate proton mobility in the bulk/grain boundaries.

Field of science

  • /social sciences/social and economic geography/transport
  • /engineering and technology/environmental engineering/energy and fuels/fuel cell
  • /natural sciences/chemical sciences/inorganic chemistry/inorganic compounds

Call for proposal

ERC-2009-AdG
See other projects for this call

Funding Scheme

ERC-AG - ERC Advanced Grant

Host institution

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
Address
Trinity Lane The Old Schools
CB2 1TN Cambridge
United Kingdom
Activity type
Higher or Secondary Education Establishments
EU contribution
€ 1 918 270
Principal investigator
Clare Philomena Grey (Prof.)
Administrative Contact
Renata Schaeffer (Ms.)

Beneficiaries (1)

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
United Kingdom
EU contribution
€ 1 918 270
Address
Trinity Lane The Old Schools
CB2 1TN Cambridge
Activity type
Higher or Secondary Education Establishments
Principal investigator
Clare Philomena Grey (Prof.)
Administrative Contact
Renata Schaeffer (Ms.)