Objective
A significant interest has been paid to Ionic Liquids in the last years as innovative and perspective medium for solvent extraction. ILs, a new class of solvents with unusual solvating properties are one of the most interesting and rapidly developing areas of modern chemistry, technology and engineering. They have already proved to be efficient media for the extraction of a large variety of metals. Therefore, to improve the extraction and separation of lanthanoids, the development of solvent extraction ILbased systems which can discriminate between elements based on small differences in size, bond strength, and coordination characteristics are necessary. A very high synergic effect has been achieved accompanied with better selectivity in some investigations in the field of lanthanoid extraction chemistry, but synergistic ILbased studies are few. The choice of the right systems is a key factor for effective process. In the project, the solvent extraction of elements of 4f-series (light (Ce), medium (Eu) and heavy (Lu)) with two types of extracting agents will be investigated: the acidic chelating derivatives of pyrazolone and isoxazolone families and a neutral bifunctional organophosphorous extractant, octyl(phenyl)N,N-diisobutylcarbamoylmethyl)phosphine oxide, as well as their combinations in order to study the extraction efficiency, synergistic enhancement and selectivity using different ILs. The effect of the organic phase and the nature of the ILs on the extraction mechanism will be investigated. A limited extraction experiments of radioactive isotopes and model aqueous Lns solutions will be conducted.Synthesis of acylisoxazolones is important part in the project. The molecular and the IL forms of chelating agents and CMPO will be studied. The modern spectroscopic methods (ICP-MS, NMR, FTIR, fluorescence, EXAFS, UV-Vis) will be used. The data set acquired should be large enough to allow deriving empirical rules, tendencies and performed the chemical modeling.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
This project has not yet been classified with EuroSciVoc.
Be the first one to suggest relevant scientific fields and help us improve our classification service
You need to log in or register to use this function
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
FP7-PEOPLE-2013-IEF
See other projects for this call
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
75794 PARIS
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.