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Molecular Electron Dynamics investigated by IntensE Fields and Attosecond Pulses

Deliverables

Attosecond dynamics in small and large molecules

Pump-probe experiment with femtosecond and attosecond time resolution on large molecules will be conducted. The experimental results will be compared with theoretical models, focusing on the kinetic energy release obtained in attosecond XUV-IR pump-probe spectroscopy. The dominant ionization and dissociative pathways will be theoretically identified.

Nonadiabatic strong-field ionization dynamics

Nonadiabatic effects in the strong-field ionization of hydrocarbons molecules will be investigated using HHG.

Supervisory Board of the network

The Supervisory Board of the network will meet for the first time during the kick-off meeting (January/February 2015). The Supervisory Board will be composed by the will be composed of the scientists-in-charge of the beneficiaries and partner organizations, the WP Coordinators, Prof. Nora Berrah, and a representative of the ESRs elected by the young fellows. The SB will agree on common guidelines regarding the individual training of the fellows and it will provide the guidelines for the drafting of the CDPs of the individual ESRs. During this first meeting a training for unbiased selection and dissemination of common best practises to supervisors will be provided (kick-off meeting).

Structural and dynamical effects in HHG

The interplay between structural and dynamical effects in high-order harmonic generation (HHG) spectroscopy will be elucidated. Advanced alignment techniques will be investigated for the implementation of high-order HHG-based tomography of nonplanar molecules. From the theoretical side, a simulation code for HHG-based spectroscopy of multi-electron dynamics will be developed, considering also the extended harmonic cut-off achieved using mid-IR systems as driving pulses.

High-repetition rate photoelectron spectroscopy

Acquisition of photoelectron/photoion pump-probe data with full energy, angular and temporal resolution using the developed high repetition rate (200 kHz) attosecond source . The network will be involved in the development of new apparatuses and technologies for the generation of ultrashort XUV pulses including novel schemes for the stabilisation of the CEP of high-energy, high-repetition rate laser systems operating up to 10 kHz, the demonstration of thin-disk laser pump delivering up to E=200 mJ energy.

Dissemination and outreach activities plan

A plan for the outreach activities of the ESRs will be drafted. This will be based on the activities to be performed in secondary schools using the Photonics Explorer Kit. Additional outreach activities (for example the participation to specific event such as the Researchers' night) will be also considered.

Time-resolved dynamics in conformer selected beams

Conformer selection will be accomplished and time-resolved dynamics in different conformers will be characterized by pump-probe experiment with attosecond and femtosecond resolution.

Influence of the environment on ultrafast eletronic/nuclear dynamics

1) Experimental evidences of electronic relaxation mechanism (for example Interatomic Coulombic Decay) induced by intense XUV light pulses in atomic clusters/dimers will be obtained. 2) The influence of the helium environment on the rotational, vibrational and electronic dynamics of embedded molecules will be characterized

Demonstration of coherent control schemes using XUV FELs

The consortium will demonstrate new schemes for the generation of multi-color coherent XUV radiation exploiting FELs. Using this approach, the network will investigated coherent control schemes in the XUV spectral range. In particular, the combination of multi-color coherent XUV radiation will be used to control the photoionization process and electronic dynamics in inner-valence shells in atoms and, eventually also in molecules. Finally we will also investigate novel approaches for the generation of attosecond pulse trains using XUV FELs.

Improved HHG tomography of linear molecules

HHG tomography strongly depends on the quality of alignment of molecules in cold gas jets. We will investigate strategies for a reliable reconstruction of molecular orbitals by HHG in simple linear molecules, even in presence of degraded alignment conditions.

Attosecond XUV-pump-XUV-probe on molecules

The ultrafast autoionization dynamics of small molecules such as H2/D2 (hydrogen and deuterium) will be characterized exploiting high-energy low repetition rate laser systems.

Dynamical structure by HHG

Dynamical structure information in simple molecules using XUV light generated by HHG will be obtained

Website design and development, and Social Media presence

The Webpage of the network will be designed during the first four months. The web-page will be used to advertise the network activities, the open positions until the recruitment of all ESRs, and to disseminate the videoclips (virtual lab tours and video tutorials) and to communicate the list of speakers of the webinars. At the same time the LinkedIn group of the network will be created and maintained.

Publications

Coherent diffractive imaging of single helium nanodroplets with a high harmonic generation source

Author(s): Daniela Rupp, Nils Monserud, Bruno Langbehn, Mario Sauppe, Julian Zimmermann, Yevheniy Ovcharenko, Thomas Möller, Fabio Frassetto, Luca Poletto, Andrea Trabattoni, Francesca Calegari, Mauro Nisoli, Katharina Sander, Christian Peltz, Marc J. Vrakking, Thomas Fennel, Arnaud Rouzée
Published in: Nature Communications, Issue 8/1, 2017, Page(s) Article number: 493, ISSN 2041-1723
DOI: 10.1038/s41467-017-00287-z

Original Ti:Sa 10  kHz front-end design delivering 17  fs, 170  mrad CEP stabilized pulses up to 5  W

Author(s): A. Golinelli, X. Chen, E. Gontier, B. Bussière, O. Tcherbakoff, M. Natile, P. d’Oliveira, P.-M. Paul, J.-F. Hergott
Published in: Optics Letters, Issue 42/12, 2017, Page(s) 2326, ISSN 0146-9592
DOI: 10.1364/OL.42.002326

Coulomb-explosion imaging of concurrent CH 2 BrI photodissociation dynamics

Author(s): Michael Burt, Rebecca Boll, Jason W. L. Lee, Kasra Amini, Hansjochen Köckert, Claire Vallance, Alexander S. Gentleman, Stuart R. Mackenzie, Sadia Bari, Cédric Bomme, Stefan Düsterer, Benjamin Erk, Bastian Manschwetus, Erland Müller, Dimitrios Rompotis, Evgeny Savelyev, Nora Schirmel, Simone Techert, Rolf Treusch, Jochen Küpper, Sebastian Trippel, Joss Wiese, Henrik Stapelfeldt, Barbara Cunha
Published in: Physical Review A, Issue 96/4, 2017, ISSN 2469-9926
DOI: 10.1103/PhysRevA.96.043415

Optical Parametric Amplification Techniques for the Generation of High-Energy Few-Optical-Cycles IR Pulses for Strong Field Applications

Author(s): Anna Ciriolo, Matteo Negro, Michele Devetta, Eugenio Cinquanta, Davide Faccialà, Aditya Pusala, Sandro De Silvestri, Salvatore Stagira, Caterina Vozzi
Published in: Applied Sciences, Issue 7/3, 2017, Page(s) 265, ISSN 2076-3417
DOI: 10.3390/app7030265

Micro-focusing of broadband high-order harmonic radiation by a double toroidal mirror

Author(s): Coudert-Alteirac, Hélène; Dacasa, Hugo; Campi, Filippo; Kueny, Emma; Farkas, Balázs; Brunner, Fabian; Maclot, Sylvain; Manschwetus, Bastian; Wikmark, Hampus; Lahl, Jan; Rading, Linnea; Peschel, Jasper; Major, Balázs; Varjú, Katalin; Dovillaire, Guillaume; Zeitoun, Philippe; Johnsson, Per; L'Huillier, Anne; Rudawski, Piotr
Published in: Applied Sciences, Issue 7/11, 1159, 2018, ISSN 2076-3417
DOI: 10.3204/PUBDB-2017-11919

A Versatile Velocity Map Ion-Electron Covariance Imaging Spectrometer for High-Intensity XUV Experiments

Author(s): Linnea Rading, Jan Lahl, Sylvain Maclot, Filippo Campi, Hélène Coudert-Alteirac, Bart Oostenrijk, Jasper Peschel, Hampus Wikmark, Piotr Rudawski, Mathieu Gisselbrecht, Per Johnsson
Published in: Applied Sciences, Issue 8/6, 2018, Page(s) 998, ISSN 2076-3417
DOI: 10.3390/app8060998

Photoexcitation circular dichroism in chiral molecules

Author(s): S. Beaulieu, A. Comby, D. Descamps, B. Fabre, G. A. Garcia, R. Géneaux, A. G. Harvey, F. Légaré, Z. Mašín, L. Nahon, A. F. Ordonez, S. Petit, B. Pons, Y. Mairesse, O. Smirnova, V. Blanchet
Published in: Nature Physics, Issue 14/5, 2018, Page(s) 484-489, ISSN 1745-2473
DOI: 10.1038/s41567-017-0038-z

Monte Carlo wave-packet approach to trace nuclear dynamics in molecular excited states by XUV-pump–IR-probe spectroscopy

Author(s): Qingli Jing, Roger Y. Bello, Fernando Martín, Alicia Palacios, Lars Bojer Madsen
Published in: Physical Review A, Issue 97/4, 2018, ISSN 2469-9926
DOI: 10.1103/PhysRevA.97.043426

Spatial Control of Multiphoton Electron Excitations in InAs Nanowires by Varying Crystal Phase and Light Polarization

Author(s): Erik Mårsell, Emil Boström, Anne Harth, Arthur Losquin, Chen Guo, Yu-Chen Cheng, Eleonora Lorek, Sebastian Lehmann, Gustav Nylund, Martin Stankovski, Cord L. Arnold, Miguel Miranda, Kimberly A. Dick, Johan Mauritsson, Claudio Verdozzi, Anne L’Huillier, Anders Mikkelsen
Published in: Nano Letters, Issue 18/2, 2018, Page(s) 907-915, ISSN 1530-6984
DOI: 10.1021/acs.nanolett.7b04267

Phase control of attosecond pulses in a train

Author(s): Chen Guo, Anne Harth, Stefanos Carlström, Yu-Chen Cheng, Sara Mikaelsson, Erik Mårsell, Christoph Heyl, Miguel Miranda, Mathieu Gisselbrecht, Mette B Gaarde, Kenneth J Schafer, Anders Mikkelsen, Johan Mauritsson, Cord L Arnold, Anne L’Huillier
Published in: Journal of Physics B: Atomic, Molecular and Optical Physics, Issue 51/3, 2018, Page(s) 034006, ISSN 0953-4075
DOI: 10.1088/1361-6455/aa9953

Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom

Author(s): Felix Brauße, Gildas Goldsztejn, Kasra Amini, Rebecca Boll, Sadia Bari, Cédric Bomme, Mark Brouard, Michael Burt, Barbara Cunha de Miranda, Stefan Düsterer, Benjamin Erk, Marie Géléoc, Romain Geneaux, Alexander S. Gentleman, Renaud Guillemin, Iyas Ismail, Per Johnsson, Loïc Journel, Thomas Kierspel, Hansjochen Köckert, Jochen Küpper, Pascal Lablanquie, Jan Lahl, Jason W. L. Lee, Stuart R.
Published in: Physical Review A, Issue 97/4, 2018, Page(s) 043429, ISSN 2469-9934
DOI: 10.1103/PhysRevA.97.043429

Compact 200 kHz HHG source driven by a few-cycle OPCPA

Author(s): Anne Harth, Chen Guo, Yu-Chen Cheng, Arthur Losquin, Miguel Miranda, Sara Mikaelsson, Christoph M Heyl, Oliver Prochnow, Jan Ahrens, Uwe Morgner, Anne L’Huillier, Cord L Arnold
Published in: Journal of Optics, Issue 20/1, 2018, Page(s) 014007, ISSN 2040-8978
DOI: 10.1088/2040-8986/aa9b04

Thin-disk pumped optical parametric chirped pulse amplifier delivering CEP-stable multi-mJ few-cycle pulses at 6 kHz

Author(s): Stephan Prinz, Maximilian Schnitzenbaumer, Dionysios Potamianos, Marcel Schultze, Sebastian Stark, Matthias Häfner, Catherine Y. Teisset, Christoph Wandt, Knut Michel, Reinhard Kienberger, Birgitta Bernhardt, Thomas Metzger
Published in: Optics Express, Issue 26/2, 2018, Page(s) 1108, ISSN 1094-4087
DOI: 10.1364/oe.26.001108

Alignment and Imaging of the CS 2 Dimer Inside Helium Nanodroplets

Author(s): James D. Pickering, Benjamin Shepperson, Bjarke A. K. Hübschmann, Frederik Thorning, Henrik Stapelfeldt
Published in: Physical Review Letters, Issue 120/11, 2018, ISSN 0031-9007
DOI: 10.1103/PhysRevLett.120.113202

Time–frequency representation of autoionization dynamics in helium

Author(s): D Busto, L Barreau, M Isinger, M Turconi, C Alexandridi, A Harth, S Zhong, R J Squibb, D Kroon, S Plogmaker, M Miranda, Á Jiménez-Galán, L Argenti, C L Arnold, R Feifel, F Martín, M Gisselbrecht, A L’Huillier, P Salières
Published in: Journal of Physics B: Atomic, Molecular and Optical Physics, Issue 51/4, 2018, Page(s) 044002, ISSN 0953-4075
DOI: 10.1088/1361-6455/aaa057

Note: Knife edge skimming for improved separation of molecular species by the deflector

Author(s): Sebastian Trippel, Melby Johny, Thomas Kierspel, Jolijn Onvlee, Helen Bieker, Hong Ye, Terry Mullins, Lars Gumprecht, Karol Długołęcki, Jochen Küpper
Published in: Review of Scientific Instruments, Issue 89/9, 2018, Page(s) 096110, ISSN 0034-6748
DOI: 10.1063/1.5026145

High-order harmonic generation spectroscopy by recolliding electron caustics

Author(s): D Faccialà, S Pabst, B D Bruner, A G Ciriolo, M Devetta, M Negro, P Prasannan Geetha, A Pusala, H Soifer, N Dudovich, S Stagira, C Vozzi
Published in: Journal of Physics B: Atomic, Molecular and Optical Physics, Issue 51/13, 2018, Page(s) 134002, ISSN 0953-4075
DOI: 10.1088/1361-6455/aac351

Two-photon double ionization of neon using an intense attosecond pulse train

Author(s): B. Manschwetus, L. Rading, F. Campi, S. Maclot, H. Coudert-Alteirac, J. Lahl, H. Wikmark, P. Rudawski, C. M. Heyl, B. Farkas, T. Mohamed, A. L'Huillier, P. Johnsson
Published in: Physical Review A, Issue 93/6, 2016, ISSN 2469-9926
DOI: 10.1103/PhysRevA.93.061402

Laser-induced dissociative ionization of H 2 from the near-infrared to the mid-infrared regime

Author(s): Qingli Jing, Lars Bojer Madsen
Published in: Physical Review A, Issue 94/6, 2016, ISSN 2469-9926
DOI: 10.1103/PhysRevA.94.063402

Femtosecond laser induced Coulomb explosion imaging of aligned OCS oligomers inside helium nanodroplets

Author(s): James D. Pickering, Benjamin Shepperson, Lars Christiansen, Henrik Stapelfeldt
Published in: The Journal of Chemical Physics, Issue 149/15, 2018, Page(s) 154306, ISSN 0021-9606
DOI: 10.1063/1.5049555

Multiple ionization of argon via multi-XUV-photon absorption induced by 20-GW high-order harmonic laser pulses

Author(s): A. Nayak, I. Orfanos, I. Makos, M. Dumergue, S. Kühn, E. Skantzakis, B. Bodi, K. Varju, C. Kalpouzos, H. I. B. Banks, A. Emmanouilidou, D. Charalambidis, P. Tzallas
Published in: Physical Review A, Issue 98/2, 2018, ISSN 2469-9926
DOI: 10.1103/physreva.98.023426

Generation of ultrashort pulses by four wave mixing in a gas-filled hollow core fiber

Author(s): Anna G Ciriolo, Aditya Pusala, Matteo Negro, Michele Devetta, Davide Faccialà, Giacomo Mariani, Caterina Vozzi, Salvatore Stagira
Published in: Journal of Optics, Issue 20/12, 2018, Page(s) 125503, ISSN 2040-8978
DOI: 10.1088/2040-8986/aaec41

Communication: Gas-phase structural isomer identification by Coulomb explosion of aligned molecules

Author(s): Michael Burt, Kasra Amini, Jason W. L. Lee, Lars Christiansen, Rasmus R. Johansen, Yuki Kobayashi, James D. Pickering, Claire Vallance, Mark Brouard, Henrik Stapelfeldt
Published in: The Journal of Chemical Physics, Issue 148/9, 2018, Page(s) 091102, ISSN 0021-9606
DOI: 10.1063/1.5023441

Generalized perspective on chiral measurements without magnetic interactions

Author(s): Andres F. Ordonez, Olga Smirnova
Published in: Physical Review A, Issue 98/6, 2018, ISSN 2469-9926
DOI: 10.1103/physreva.98.063428

XUV double-pulses with femtosecond to 650 ps separation from a multilayer-mirror-based split-and-delay unit at FLASH

Author(s): Mario Sauppe, Dimitrios Rompotis, Benjamin Erk, Sadia Bari, Tobias Bischoff, Rebecca Boll, Cédric Bomme, Christoph Bostedt, Simon Dörner, Stefan Düsterer, Torsten Feigl, Leonie Flückiger, Tais Gorkhover, Katharina Kolatzki, Bruno Langbehn, Nils Monserud, Erland Müller, Jan P. Müller, Christopher Passow, Daniel Ramm, Daniel Rolles, Kaja Schubert, Lucas Schwob, Björn Senfftleben, Rolf Treusch
Published in: Journal of Synchrotron Radiation, Issue 25/5, 2018, Page(s) 1517-1528, ISSN 1600-5775
DOI: 10.1107/s1600577518006094

Coulomb explosion imaging of CH 3 I and CH 2 ClI photodissociation dynamics

Author(s): Felix Allum, Michael Burt, Kasra Amini, Rebecca Boll, Hansjochen Köckert, Pavel K. Olshin, Sadia Bari, Cédric Bomme, Felix Brauße, Barbara Cunha de Miranda, Stefan Düsterer, Benjamin Erk, Marie Géléoc, Romain Geneaux, Alexander S. Gentleman, Gildas Goldsztejn, Renaud Guillemin, David M. P. Holland, Iyas Ismail, Per Johnsson, Loïc Journel, Jochen Küpper, Jan Lahl, Jason W. L. Lee, Sylvain M
Published in: The Journal of Chemical Physics, Issue 149/20, 2018, Page(s) 204313, ISSN 0021-9606
DOI: 10.1063/1.5041381

Extreme-ultraviolet refractive optics

Author(s): L. Drescher, O. Kornilov, T. Witting, G. Reitsma, N. Monserud, A. Rouzée, J. Mikosch, M. J. J. Vrakking, B. Schütte
Published in: Nature, Issue 564/7734, 2018, Page(s) 91-94, ISSN 0028-0836
DOI: 10.1038/s41586-018-0737-3

Propensity rules in photoelectron circular dichroism in chiral molecules. I. Chiral hydrogen

Author(s): Andres F. Ordonez, Olga Smirnova
Published in: Physical Review A, Issue 99/4, 2019, ISSN 2469-9926
DOI: 10.1103/physreva.99.043416

Propensity rules in photoelectron circular dichroism in chiral molecules. II. General picture

Author(s): Andres F. Ordonez, Olga Smirnova
Published in: Physical Review A, Issue 99/4, 2019, ISSN 2469-9926
DOI: 10.1103/physreva.99.043417

Spatial separation of pyrrole and pyrrole-water clusters

Author(s): Melby Johny, Jolijn Onvlee, Thomas Kierspel, Helen Bieker, Sebastian Trippel, Jochen Küpper
Published in: Chemical Physics Letters, Issue 721, 2019, Page(s) 149-152, ISSN 0009-2614
DOI: 10.1016/j.cplett.2019.01.052

024  TW ultrabroadband, CEP-stable multipass Ti:Sa amplifier

Author(s): Mikayel Musheghyan, Fabian Lücking, Zhao Cheng, Harald Frei, Andreas Assion
Published in: Optics Letters, Issue 44/6, 2019, Page(s) 1464, ISSN 0146-9592
DOI: 10.1364/ol.44.001464

Single-shot extreme-ultraviolet wavefront measurements of high-order harmonics

Author(s): Hugo Dacasa, Hélène Coudert-Alteirac, Chen Guo, Emma Kueny, Filippo Campi, Jan Lahl, Jasper Peschel, Hampus Wikmark, Balázs Major, Erik Malm, Domenico Alj, Katalin Varjú, Cord L. Arnold, Guillaume Dovillaire, Per Johnsson, Anne L’Huillier, Sylvain Maclot, Piotr Rudawski, Philippe Zeitoun
Published in: Optics Express, Issue 27/3, 2019, Page(s) 2656, ISSN 1094-4087
DOI: 10.1364/oe.27.002656

Spatiotemporal coupling of attosecond pulses

Author(s): Hampus Wikmark, Chen Guo, Jan Vogelsang, Peter W. Smorenburg, Hélène Coudert-Alteirac, Jan Lahl, Jasper Peschel, Piotr Rudawski, Hugo Dacasa, Stefanos Carlström, Sylvain Maclot, Mette B. Gaarde, Per Johnsson, Cord L. Arnold, Anne L’Huillier
Published in: Proceedings of the National Academy of Sciences, Issue 116/11, 2019, Page(s) 4779-4787, ISSN 0027-8424
DOI: 10.1073/pnas.1817626116