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Integrated self-assembled SWITCHable systems and materials: towards responsive organic electronics – a multi-site innovative training action

Deliverables

Self-assembly of TTF-PTM dyads on surfaces and their characterization

Self-assembly of TTF-PTM dyads on surfaces and their characterization.

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Publications

Edge Functionalization of Structurally Defined Graphene Nanoribbons for Modulating the Self-Assembled Structures

Author(s): Ashok Keerthi, Boya Radha, Daniele Rizzo, Hao Lu, Valentin Diez Cabanes, Ian Cheng-Yi Hou, David Beljonne, Jérôme Cornil, Cinzia Casiraghi, Martin Baumgarten, Klaus Müllen, Akimitsu Narita
Published in: Journal of the American Chemical Society, Issue 139/46, 2017, Page(s) 16454-16457, ISSN 0002-7863
DOI: 10.1021/jacs.7b09031

Fluorescence Commutation and Surface Photopatterning with Porphyrin Tetradithienylethene Switches

Author(s): Thomas Biellmann, Agostino Galanti, Julien Boixel, Jennifer A. Wytko, Véronique Guerchais, Paolo Samorì, Jean Weiss
Published in: Chemistry - A European Journal, Issue 24/7, 2018, Page(s) 1631-1639, ISSN 0947-6539
DOI: 10.1002/chem.201704222

Diels–Alder polymerization: a versatile synthetic method toward functional polyphenylenes, ladder polymers and graphene nanoribbons

Author(s): Ian Cheng-Yi Hou, Yunbin Hu, Akimitsu Narita, Klaus Müllen
Published in: Polymer Journal, Issue 50/1, 2017, Page(s) 3-20, ISSN 0032-3896
DOI: 10.1038/pj.2017.69

Bulk Heterojunction Solar Cells: The Role of Alkyl Side Chain on Nanoscale Morphology of Sulfur Over-rich Regioregular Polythiophene/Fullerene Blends

Author(s): Elisabetta Salatelli, Martina Marinelli, Massimiliano Lanzi, Alberto Zanelli, Simone Dell’Elce, Andrea Liscio, Massimo Gazzano, Francesca Di Maria
Published in: The Journal of Physical Chemistry C, Issue 122/8, 2018, Page(s) 4156-4164, ISSN 1932-7447
DOI: 10.1021/acs.jpcc.7b11456

Light-Modulation of the Charge Injection in a Polymer Thin-Film Transistor by Functionalizing the Electrodes with Bistable Photochromic Self-Assembled Monolayers

Author(s): Thomas Mosciatti, Maria G. del Rosso, Martin Herder, Johannes Frisch, Norbert Koch, Stefan Hecht, Emanuele Orgiu, Paolo Samorì
Published in: Advanced Materials, Issue 28/31, 2016, Page(s) 6606-6611, ISSN 0935-9648
DOI: 10.1002/adma.201600651

Fluid Mixing for Low-Power ‘Digital Microfluidics’ Using Electroactive Molecular Monolayers

Author(s): Maria Serena Maglione, Stefano Casalini, Stamatis Georgakopoulos, Marianna Barbalinardo, Vitaliy Parkula, Núria Crivillers, Concepció Rovira, Pierpaolo Greco, Marta Mas-Torrent
Published in: Small, Issue 14/10, 2018, Page(s) 1703344, ISSN 1613-6810
DOI: 10.1002/smll.201703344

Polystyrene nanoparticle-templated hollow titania nanosphere monolayers as ordered scaffolds

Author(s): V. Robbiano, G. M. Paternò, G. F. Cotella, T. Fiore, M. Dianetti, M. Scopelliti, F. Brunetti, B. Pignataro, F. Cacialli
Published in: Journal of Materials Chemistry C, Issue 6/10, 2018, Page(s) 2502-2508, ISSN 2050-7534
DOI: 10.1039/C7TC04070A

Energy Level Alignment at Interfaces Between Au (111) and Thiolated Oligophenylenes of Increasing Chain Size: Theoretical Evidence of Pinning Effects

Author(s): Valentin Diez-Cabanes, Sandra Rodriguez Gonzalez, Silvio Osella, David Cornil, Colin Van Dyck, Jérôme Cornil
Published in: Advanced Theory and Simulations, Issue 1/3, 2018, Page(s) 1700020, ISSN 2513-0390
DOI: 10.1002/adts.201700020

Electrochemically driven host–guest interactions on patterned donor/acceptor self-assembled monolayers

Author(s): Maria Serena Maglione, Javier Casado-Montenegro, Eva-Corinna Fritz, Núria Crivillers, Bart Jan Ravoo, Concepció Rovira, Marta Mas-Torrent
Published in: Chemical Communications, Issue 54/24, 2018, Page(s) 3038-3041, ISSN 1359-7345
DOI: 10.1039/C8CC00494C

Sensitive Assays by Nucleophile-Induced Rearrangement of Photoactivated Diarylethenes

Author(s): Sebastian Fredrich, Aurelio Bonasera, Virginia Valderrey, Stefan Hecht
Published in: Journal of the American Chemical Society, Issue 140/20, 2018, Page(s) 6432-6440, ISSN 0002-7863
DOI: 10.1021/jacs.8b02982

Dynamic Photoswitching of Electron Energy Levels at Hybrid ZnO/Organic Photochromic Molecule Junctions

Author(s): Qiankun Wang, Giovanni Ligorio, Valentin Diez-Cabanes, David Cornil, Björn Kobin, Jana Hildebrandt, Marco Vittorio Nardi, Melanie Timpel, Stefan Hecht, Jérôme Cornil, Emil J. W. List-Kratochvil, Norbert Koch
Published in: Advanced Functional Materials, Issue 28/28, 2018, Page(s) 1800716, ISSN 1616-301X
DOI: 10.1002/adfm.201800716

Hexa- peri -hexabenzocoronene with Different Acceptor Units for Tuning Optoelectronic Properties

Author(s): Ashok Keerthi, Ian Cheng-Yi Hou, Tomasz Marszalek, Wojciech Pisula, Martin Baumgarten, Akimitsu Narita
Published in: Chemistry - An Asian Journal, Issue 11/19, 2016, Page(s) 2710-2714, ISSN 1861-4728
DOI: 10.1002/asia.201600638

Photoluminescence Blinking of Single-Crystal Methylammonium Lead Iodide Perovskite Nanorods Induced by Surface Traps

Author(s): Haifeng Yuan, Elke Debroye, Giorgio Caliandro, Kris P. F. Janssen, Jordi van Loon, Christine E. A. Kirschhock, Johan A. Martens, Johan Hofkens, Maarten B. J. Roeffaers
Published in: ACS Omega, Issue 1/1, 2016, Page(s) 148-159, ISSN 2470-1343
DOI: 10.1021/acsomega.6b00107

Influence of the donor unit on the rectification ratio in tunnel junctions based on donor–acceptor SAMs using PTM units as acceptors

Author(s): Manuel Souto, Valentin Díez-Cabanes, Li Yuan, Adriana R. Kyvik, Imma Ratera, Christian A. Nijhuis, Jerome Cornil, Jaume Veciana
Published in: Physical Chemistry Chemical Physics, Issue 20/40, 2018, Page(s) 25638-25647, ISSN 1463-9076
DOI: 10.1039/C8CP05488F

Amorphous CaCO 3 : Influence of the Formation Time on Its Degree of Hydration and Stability

Author(s): Huachuan Du, Mathias Steinacher, Camelia Borca, Thomas Huthwelker, Anna Murello, Francesco Stellacci, Esther Amstad
Published in: Journal of the American Chemical Society, Issue 140/43, 2018, Page(s) 14289-14299, ISSN 0002-7863
DOI: 10.1021/jacs.8b08298

Electronic Decoupling in C 3 -Symmetrical Light-Responsive Tris(Azobenzene) Scaffolds: Self-Assembly and Multiphotochromism

Author(s): Agostino Galanti, Valentin Diez-Cabanes, Jasmin Santoro, Michal Valášek, Andrea Minoia, Marcel Mayor, Jérôme Cornil, Paolo Samorì
Published in: Journal of the American Chemical Society, Issue 140/47, 2018, Page(s) 16062-16070, ISSN 0002-7863
DOI: 10.1021/jacs.8b06324

Accurate chemical analysis of oxygenated graphene-based materials using X-ray photoelectron spectroscopy

Author(s): Alessandro Kovtun, Derek Jones, Simone Dell’Elce, Emanuele Treossi, Andrea Liscio, Vincenzo Palermo
Published in: Carbon, Issue 143, 2019, Page(s) 268-275, ISSN 0008-6223
DOI: 10.1016/j.carbon.2018.11.012

Design of Perchlorotriphenylmethyl (PTM) Radical-Based Compounds for Optoelectronic Applications: The Role of Orbital Delocalization

Author(s): Valentín Diez-Cabanes, Gonca Seber, Carlos Franco, Francesc Bejarano, Nuria Crivillers, Marta Mas-Torrent, Jaume Veciana, Concepció Rovira, Jérôme Cornil
Published in: ChemPhysChem, Issue 19/19, 2018, Page(s) 2572-2578, ISSN 1439-4235
DOI: 10.1002/cphc.201800321

3D to 2D reorganization of silver–thiol nanostructures, triggered by solvent vapor annealing

Author(s): Simone Dell'Elce, Fabiola Liscio, Alessandro Kovtun, Stefano Allegri, Otello M. Roscioni, Cristiano Albonetti, Giovanna De Luca, Heinz W. Amenitsch, Nicola Demitri, Loris Giorgini, Vittorio Morandi, Francesco Stellacci, Andrea Liscio, Vincenzo Palermo
Published in: Nanoscale, Issue 10/48, 2018, Page(s) 23018-23026, ISSN 2040-3364
DOI: 10.1039/c8nr07109h

Modifying the Size of Ultrasound-Induced Liquid-Phase Exfoliated Graphene: From Nanosheets to Nanodots

Author(s): Artur Ciesielski, Sébastien Haar, Alessandro Aliprandi, Mohamed El Garah, Giulia Tregnago, Giovanni F. Cotella, Mirella El Gemayel, Fanny Richard, Haiyan Sun, Franco Cacialli, Francesco Bonaccorso, Paolo Samorì
Published in: ACS Nano, Issue 10/12, 2016, Page(s) 10768-10777, ISSN 1936-0851
DOI: 10.1021/acsnano.6b03823

Optically switchable organic light-emitting transistors

Author(s): Lili Hou, Xiaoyan Zhang, Giovanni F. Cotella, Giuseppe Carnicella, Martin Herder, Bernd M. Schmidt, Michael Pätzel, Stefan Hecht, Franco Cacialli, Paolo Samorì
Published in: Nature Nanotechnology, 2019, ISSN 1748-3387
DOI: 10.1038/s41565-019-0370-9

Dynamically Switching the Electronic and Electrostatic Properties of Indium–Tin Oxide Electrodes with Photochromic Monolayers: Toward Photoswitchable Optoelectronic Devices

Author(s): Qiankun Wang, Valentin Diez-Cabanes, Simone Dell’Elce, Andrea Liscio, Björn Kobin, Hong Li, Jean-Luc Brédas, Stefan Hecht, Vincenzo Palermo, Emil J. W. List-Kratochvil, Jérôme Cornil, Norbert Koch, Giovanni Ligorio
Published in: ACS Applied Nano Materials, Issue 2/2, 2019, Page(s) 1102-1110, ISSN 2574-0970
DOI: 10.1021/acsanm.9b00094

Effect of the Molecular Polarizability of SAMs on the Work Function Modification of Gold: Closed- versus Open-Shell Donor-Acceptor SAMs

Author(s): Valentin Diez-Cabanes, Dayana C. Morales, Manuel Souto, Markos Paradinas, Francesca Delchiaro, Anna Painelli, Carmen Ocal, David Cornil, Jérôme Cornil, Jaume Veciana, Imma Ratera
Published in: Advanced Materials Technologies, 2019, Page(s) 1800152, ISSN 2365-709X
DOI: 10.1002/admt.201800152

ITO based fully-spray coated inverted solar cells with non-toxic solvents: The role of buffer layers interface on low band gap photoactive layer performance

Author(s): Giuseppina Polino, Simone Dell’Elce, Andrea Liscio, Luca La Notte, Giorgio Cardone, Andrea Reale, Aldo Di Carlo, Francesca Brunetti
Published in: Energy Technology, 2019, ISSN 2194-4288
DOI: 10.1002/ente.201800627

A tool box to ascertain the nature of doping and photoresponse in single-walled carbon nanotubes

Author(s): Ana Santidrián, José M. González-Domínguez, Valentin Diez-Cabanes, Javier Hernández-Ferrer, Wolfgang K. Maser, Ana M. Benito, Alejandro Anśon-Casaos, Jérôme Cornil, Tatiana Da Ros, Martin Kalbáč
Published in: Physical Chemistry Chemical Physics, Issue 21/7, 2019, Page(s) 4063-4071, ISSN 1463-9076
DOI: 10.1039/c8cp06961a

Light-Activated Sensitive Probes for Amine Detection

Author(s): Virginia Valderrey, Aurelio Bonasera, Sebastian Fredrich, Stefan Hecht
Published in: Angewandte Chemie International Edition, Issue 56/7, 2017, Page(s) 1914-1918, ISSN 1433-7851
DOI: 10.1002/anie.201609989

Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor

Author(s): Manuel Souto, Dan Bendixen, Morten Jensen, Valentín Díez-Cabanes, Jérôme Cornil, Jan Jeppesen, Imma Ratera, Concepció Rovira, Jaume Veciana
Published in: Magnetochemistry, Issue 2/4, 2016, Page(s) 46, ISSN 2312-7481
DOI: 10.3390/magnetochemistry2040046

A four-state capacitance molecular switch based on a redox active tetrathiafulvalene self-assembled monolayer

Author(s): E. Marchante, M. S. Maglione, N. Crivillers, C. Rovira, M. Mas-Torrent
Published in: RSC Adv., Issue 7/10, 2017, Page(s) 5636-5641, ISSN 2046-2069
DOI: 10.1039/C6RA27011E

Electronic Properties of Optically Switchable Photochromic Diarylethene Molecules at the Interface with Organic Semiconductors

Author(s): Qiankun Wang, Johannes Frisch, Martin Herder, Stefan Hecht, Norbert Koch
Published in: ChemPhysChem, Issue 18/7, 2017, Page(s) 722-727, ISSN 1439-4235
DOI: 10.1002/cphc.201601442

Light-Controlled Reversible Modulation of Frontier Molecular Orbital Energy Levels in Trifluoromethylated Diarylethenes

Author(s): Martin Herder, Fabian Eisenreich, Aurelio Bonasera, Anna Grafl, Lutz Grubert, Michael Pätzel, Jutta Schwarz, Stefan Hecht
Published in: Chemistry - A European Journal, Issue 23/15, 2017, Page(s) 3743-3754, ISSN 0947-6539
DOI: 10.1002/chem.201605511

Estimation of π–π Electronic Couplings from Current Measurements

Author(s): J. Trasobares, J. Rech, T. Jonckheere, T. Martin, O. Aleveque, E. Levillain, V. Diez-Cabanes, Y. Olivier, J. Cornil, J. P. Nys, R. Sivakumarasamy, K. Smaali, P. Leclere, A. Fujiwara, D. Théron, D. Vuillaume, N. Clément
Published in: Nano Letters, Issue 17/5, 2017, Page(s) 3215-3224, ISSN 1530-6984
DOI: 10.1021/acs.nanolett.7b00804

Rheological and physical characterization of PEDOT: PSS/graphene oxide nanocomposites for perovskite solar cells

Author(s): Antonella Giuri, Sofia Masi, Silvia Colella, Andrea Listorti, Aurora Rizzo, Alessandro Kovtun, Simone Dell'Elce, Andrea Liscio, Carola Esposito Corcione
Published in: Polymer Engineering & Science, Issue 57/6, 2017, Page(s) 546-552, ISSN 0032-3888
DOI: 10.1002/pen.24554

Optical Input/Electrical Output Memory Elements based on a Liquid Crystalline Azobenzene Polymer

Author(s): Thomas Mosciatti, Sara Bonacchi, Marco Gobbi, Laura Ferlauto, Fabiola Liscio, Loris Giorgini, Emanuele Orgiu, Paolo Samorì
Published in: ACS Applied Materials & Interfaces, Issue 8/10, 2016, Page(s) 6563-6569, ISSN 1944-8244
DOI: 10.1021/acsami.5b12430

Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

Author(s): Grzegorz Markiewicz, Dawid Pakulski, Agostino Galanti, Violetta Patroniak, Artur Ciesielski, Artur R. Stefankiewicz, Paolo Samorì
Published in: Chem. Commun., Issue 53/53, 2017, Page(s) 7278-7281, ISSN 1359-7345
DOI: 10.1039/C7CC01805C

Asymmetric Injection in Organic Transistors via Direct SAM Functionalization of Source and Drain Electrodes

Author(s): Thomas Mosciatti, Pierpaolo Greco, Tim Leydecker, Matilde Eredia, Fabio Biscarini, Paolo Samorì
Published in: ACS Omega, Issue 2/7, 2017, Page(s) 3502-3508, ISSN 2470-1343
DOI: 10.1021/acsomega.7b00690