Tailoring Ylidic Compounds as Ligands for Organometallic Chemistry

Project Information

YlideLigands

Grant agreement ID: 677749

DOI 10.3030/677749

Project closed

EC signature date 22 December 2015

Start date 1 July 2016

End date 31 December 2021

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 500 000,00

EU contribution € 1 500 000,00

Coordinated by

RUHR-UNIVERSITAET BOCHUM
Germany

Publications

Peer reviewed articles (27)

Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds

Author(s): Abir Sarbajna, V. S. V. S. N. Swamy, Viktoria H. Gessner
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc03278f

Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide

Author(s): Jörges, Mike; Kroll, Alexander; Kelling, Leif; Gauld, Richard; Mallick, Bert; Huber, Stefan M.; Gessner, Viktoria H.
Published in: ChemistryOpen, Issue 6, 2021, Page(s) 1089 - 1094, ISSN 2191-1363
Publisher: John Wiley & Sons, Ltd
DOI: 10.1002/open.202100187

Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature

Author(s): Jens Tappen, Ilja Rodstein, Katie McGuire, Angela Großjohann, Julian Löffler, Thorsten Scherpf, Viktoria H. Gessner
Published in: Chemistry – A European Journal, Issue 26/19, 2020, Page(s) 4281-4288, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201905535

Synthesis of Low‐Valent Dinuclear Group 14 Compounds with Element–Element Bonds by Transylidation

Author(s): Chandrajeet Mohapatra, Heidar Darmandeh, Henning Steinert, Bert Mallick, Kai‐Stephan Feichtner, Viktoria H. Gessner
Published in: Chemistry – A European Journal, Issue 26/66, 2020, Page(s) 15145-15149, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004242

Kupplung von Reformatsky‐Reagenzien und Arylchloriden ermöglicht durch Ylid‐funktionalisierte Phosphanliganden

Author(s): Zhiyong Hu; Xiao‐Jing Wei; Jens Handelmann; Ann‐Katrin Seitz; Ilja Rodstein; Viktoria H. Gessner; Lukas J. Gooßen
Published in: Angewandte Chemie, Issue 5, 2021, Page(s) 6852 - 6858, ISSN 0044-8249
Publisher: John Wiley & Sons, Ltd
DOI: 10.1002/ange.202016048

Unraveling the High Activity of Ylide-Functionalized Phosphines in Palladium-Catalyzed Amination Reactions: A Comparative Study with Cy JohnPhos and P t Bu 3

Author(s): Lennart T. Scharf, Ilja Rodstein, Michelle Schmidt, Thorsten Scherpf, Viktoria H. Gessner
Published in: ACS Catalysis, Issue 10/2, 2019, Page(s) 999-1009, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.9b04666

A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

Author(s): Alexander Kroll, Henning Steinert, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Viktoria H. Gessner
Published in: Chemical Communications, Issue 56/58, 2020, Page(s) 8051-8054, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc02496a

Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone: Angle Dependence of the Donor Strength

Author(s): Julian Löffler; Richard M. Gauld; Kai-Stephan Feichtner; Ilja Rodstein; Jana-Alina Zur; Jens Handelmann; Christopher Schwarz; Viktoria H. Gessner
Published in: Organometallics, Issue 1, 2021, Page(s) 2888–2900, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00349

Au⋅⋅⋅H−C Hydrogen Bonds as Design Principle in Gold(I) Catalysis

Author(s): Heidar Darmandeh; Julian Löffler; Nikolaos V. Tzouras; Busra Dereli; Thorsten Scherpf; Kai‐Stephan Feichtner; Sofie Vanden Broeck; Kristof Van Hecke; Marina Saab; Catherine S. J. Cazin; Luigi Cavallo; Steven P. Nolan; Viktoria H. Gessner
Published in: Angewandte Chemie (International Ed. in English), Issue 2, 2020, ISSN 1521-3773
Publisher: John Wiley & Sons, Ltd
DOI: 10.1002/ange.202108581

Single‐Site and Cooperative Bond Activation Reactions with Ylide‐Functionalized Tetrylenes: A Computational Study

Author(s): Henning Steinert; Julian Löffler; Viktoria H. Gessner
Published in: European Journal of Inorganic Chemistry, Issue 47, 2021, Page(s) 5004 - 5013, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202100816

Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)

Author(s): Ilja Rodstein, Daniel Sowa Prendes, Leon Wickert, Maurice Paaßen, Viktoria H. Gessner
Published in: The Journal of Organic Chemistry, Issue 85/22, 2020, Page(s) 14674-14683, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.0c01771

Mono- and diylide-substituted phosphines (YPhos): impact of the ligand properties on the catalytic activity in gold( i )-catalysed hydroaminations

Author(s): Christopher Schwarz, Jens Handelmann, Daniel M. Baier, Alina Ouissa, Viktoria H. Gessner
Published in: Catalysis Science & Technology, Issue 9/23, 2019, Page(s) 6808-6815, ISSN 2044-4753
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cy01861a

Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes

Author(s): Henning Steinert, Christopher Schwarz, Alexander Kroll, Viktoria H. Gessner
Published in: Molecules, Issue 25/4, 2020, Page(s) 796, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules25040796

Coupling of Reformatsky Reagents with Aryl Chlorides Enabled by Ylide‐Functionalized Phosphine Ligands

Author(s): Zhiyong Hu; Xiao‐Jing Wei; Jens Handelmann; Ann‐Katrin Seitz; Ilja Rodstein; Viktoria H. Gessner; Lukas J. Gooßen
Published in: Angewandte Chemie (International Ed. in English), Issue 3, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202016048

Towards the Rational Design of Ylide-Substituted Phosphines for Gold(I)-Catalysis: From Inactive to ppm-level Catalysis

Author(s): Jens Handelmann; Chatla Naga Babu; Henning Steinert; Christopher Schwarz; Thorsten Scherpf; Alexander Kroll; Viktoria H. Gessner
Published in: Chemical Science, Issue 12, 2021, Page(s) 4329-4337, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc00105a

Efficient Pd‐Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents

Author(s): Thorsten Scherpf, Henning Steinert, Angela Großjohann, Katharina Dilchert, Jens Tappen, Ilja Rodstein, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, Issue 59/46, 2020, Page(s) 20596-20603, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008866

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogenous Catalysis

Author(s): Thorsten Scherpf, Christopher Schwarz, Lennart T. Scharf, Jana-Alina Zur, Andreas Helbig, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201805372

Isolation of the Metalated Ylides [Ph 3 P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation

Author(s): Christopher Schwarz, Lennart T. Scharf, Thorsten Scherpf, Julia Weismann, Viktoria H. Gessner
Published in: Chemistry - A European Journal, Issue 25/11, 2019, Page(s) 2793-2802, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201805421

Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

Author(s): Christopher Schwarz, Thorsten Scherpf, Ilja Rodstein, Julia Weismann, Kai‐Stephan Feichtner, Viktoria H. Gessner
Published in: ChemistryOpen, Issue 8/5, 2019, Page(s) 621-626, ISSN 2191-1363
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/open.201900094

Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment

Author(s): Chandrajeet Mohapatra, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Kai-Stephan Feichtner, Christopher Schwarz, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, Issue 58/22, 2019, Page(s) 7459-7463, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201902831

Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition

Author(s): Thorsten Scherpf, Ilja Rodstein, Maurice Paaßen, Viktoria H. Gessner
Published in: Inorganic Chemistry, Issue 58/12, 2019, Page(s) 8151-8161, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00948

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties

Author(s): Lennart T. Scharf, Viktoria H. Gessner
Published in: Inorganic Chemistry, Issue 56/15, 2017, Page(s) 8599-8607, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.7b00099

The Bonding Situation in Metalated Ylides

Author(s): Lennart T. Scharf, Diego M. Andrada, Gernot Frenking, Viktoria H. Gessner
Published in: Chemistry - A European Journal, Issue 23/18, 2017, Page(s) 4422-4434, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201605997

Using Ylide Functionalization to Stabilize Boron Cations

Author(s): Thorsten Scherpf, Kai-Stephan Feichtner, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, Issue 56/12, 2017, Page(s) 3275-3279, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201611677

Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy 3 P‐C‐SO 2 Tol]M (M = Li, Na, K)

Author(s): Heidar Darmandeh, Thorsten Scherpf, Kai‐Stephan Feichtner, Christopher Schwarz, Viktoria H. Gessner
Published in: Zeitschrift für anorganische und allgemeine Chemie, Issue 646/13, 2020, Page(s) 835-841, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201900333

Isolierung eines diylidstabilisierten Stannylens und Germylens: Erhöhte Donorstärke durch coplanare Anordnung freier Elektronenpaare

Author(s): Chandrajeet Mohapatra, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Kai‐Stephan Feichtner, Christopher Schwarz, Viktoria H. Gessner
Published in: Angewandte Chemie, Issue 131/22, 2019, Page(s) 7537-7541, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201902831

Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and C sp 3 –H Activation

Author(s): Alexander Kroll, Henning Steinert, Mike Jörges, Tim Steinke, Bert Mallick, Viktoria H. Gessner
Published in: Organometallics, Issue 39/23, 2020, Page(s) 4312-4319, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.0c00412

Intellectual Property Rights

Patent (3)

Ylid-funktionalisierte Phosphane zur Verwendung in Metallkomplexen und der homogenen Katalyse

Application/Publication number: DA 102017213817A1
Date: 2017-08-08

Ylid-funktionalisierte Phosphane zur Verwendung in Metallkomplexen und der homogenen Katalyse

Application/Publication number: DA 102017213817A1
Date: 2017-08-08

Ylid-funktionalisierte Phosphane zur Verwendung in Metallkomplexen und der homogenen Katalyse

Application/Publication number: DA 102017213817A1
Date: 2017-08-08
Applicant(s): RUHR-UNIVERSITAET BOCHUM