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Palladium catalyzed C(sp3)‒H late-stage diversification of biologically active molecules

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Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C−H Bonds in Aliphatic Amines

Author(s): Jaime R. Cabrera-Pardo, Aaron Trowbridge, Manuel Nappi, Kyohei Ozaki, Matthew J. Gaunt
Published in: Angewandte Chemie International Edition, Issue 56/39, 2017, Page(s) 11958-11962, ISSN 1433-7851
DOI: 10.1002/anie.201706303

Selective Reductive Elimination at Alkyl Pd(IV) via Dissociative Ligand Ionization Enables Catalytic C(sp3)-H Amination to Azetidines

Author(s): Matthew James Gaunt, Manuel Nappi, Chuan He, William Whitehurst, Ben Chappell
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
DOI: 10.1002/anie.201800519