Fundamentals of ASymmeTric Organo-CATalysis

Project Information

FASTO-CAT

Grant agreement ID: 714691

DOI

10.3030/714691

Project closed

EC signature date 5 October 2016

Start date 1 April 2017

End date 30 September 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 892 500,00

EU contribution

€ 1 892 500,00

Coordinated by

MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN EV
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (21)

Nature of Cations Critically Affects Water at the Negatively Charged Silica Interface

Author(s): Johannes Hunger, Jan Schaefer, Patrick Ober, Takakazu Seki, Yongkang Wang, Leon Prädel, Yuki Nagata, Mischa Bonn, Douwe Jan Bonthuis, and Ellen H. G. Backus
Published in: J. Am. Chem. Soc., 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c02777

Dielectric response of light, heavy and heavy-oxygen water: isotope effects on the hydrogen-bonding network's collective relaxation dynamics

Author(s): Bence Kutus, Andrey Shalit, Peter Hamm, Johannes Hunger
Published in: Physical Chemistry Chemical Physics, Issue 23/9, 2021, Page(s) 5467-5473, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cp06460b

The dielectric function profile across the water interface through surface-specific vibrational spectroscopy and simulations

Author(s): Kuo-Yang Chiang, Takakazu Seki, Chun-Chieh Yu, Tatsuhiko Ohto, Johannes Hunger, Mischa Bonn, Yuki Nagata
Published in: PNAS, 2022, ISSN 0027-8424
Publisher: National Academy of Sciences
DOI: 10.1073/pnas.2204156119

Composition-Dependent Hydrogen-Bonding Motifs and Dynamics in Brønsted Acid–Base Mixtures

Author(s): Christian Malm, Leon A. Prädel, Bogdan A. Marekha, Maksim Grechko, Johannes Hunger
Published in: The Journal of Physical Chemistry B, Issue 124/33, 2020, Page(s) 7229-7238, ISSN 1520-6106
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcb.0c04714

Ion-pairing equilibria and kinetics of dimethyl phosphate: A model for counter-ion binding to the phosphate backbone of nucleic acids

Author(s): Bence Kutus, Kenneth Wagner, Manfred Wagner, Johannes Hunger
Published in: Journal of Molecular Liquids, Issue 01677322, 2022, ISSN 0167-7322
Publisher: Elsevier BV
DOI: 10.1016/j.molliq.2022.119868

Enhancement of Ion Pairing of Sr(II) and Ba(II) Salts by a Tritopic Ion‐Pair Receptor in Solution

Author(s): Bence Kutus, Jun Zhu, Jian Luo, Qi‐Qiang Wang, Alexandru Lupan, Amr A. A. Attia, De‐Xian Wang, Johannes Hunger
Published in: ChemPhysChem, Issue 21/17, 2020, Page(s) 1957-1965, ISSN 1439-4235
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.202000507

Vibrational couplings and energy transfer pathways of water’s bending mode

Author(s): Chun-Chieh Yu, Kuo-Yang Chiang, Masanari Okuno, Takakazu Seki, Tatsuhiko Ohto, Xiaoqing Yu, Vitaly Korepanov, Hiro-o Hamaguchi, Mischa Bonn, Johannes Hunger, Yuki Nagata
Published in: Nature Communications, Issue 11/1, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-19759-w

Spezifische Ionen-Effekte am Beispiel eines Oligopeptids: die Rolle zweizähniger Koordination beim Guanidinium-Kation

Author(s): Vasileios Balos, Bogdan Marekha, Christian Malm, Manfred Wagner, Yuki Nagata, Mischa Bonn, Johannes Hunger
Published in: Angewandte Chemie, Issue 131/1, 2019, Page(s) 338-343, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201811029

Elucidating Conformation and Hydrogen-Bonding Motifs of Reactive Thiourea Intermediates

Author(s): Amelie A. Ehrhard, Lucas Gunkel, Sebastian Jäger, Arne C. Sell, Yuki Nagata, Johannes Hunger
Published in: ACS Catalysis, 2022, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.2c03382

Interfacial Water Structure of Binary Liquid Mixtures Reflects Nonideal Behavior

Author(s): Xiaoqing Yu, Takakazu Seki, Chun-Chieh Yu, Kai Zhong, Shumei Sun, Masanari Okuno, Ellen H. G. Backus, Johannes Hunger, Mischa Bonn, Yuki Nagata
Published in: The Journal of Physical Chemistry B, Issue 125/37, 2021, Page(s) 10639-10646, ISSN 1520-6106
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcb.1c06001

Association Equilibria of Organo-Phosphoric Acids with Imines from a Combined Dielectric and Nuclear Magnetic Resonance Spectroscopy Approach

Author(s): Christian Dreier, Leon Prädel, Amelie A. Ehrhard, Manfred Wagner, Johannes Hunger
Published in: Analytical Chemistry, Issue 93/8, 2021, Page(s) 3914-3921, ISSN 0003-2700
Publisher: American Chemical Society
DOI: 10.1021/acs.analchem.0c04669

Ion-specific binding of cations to the carboxylate and of anions to the amide of alanylalanine

Author(s): Carola Sophie Krevert, Lucas Gunkel, Constantin Haese, Johannes Hunger 
Published in: Communications Chemistry, 2022, ISSN 2399-3669
Publisher: Nature Portfolio
DOI: 10.1038/s42004-022-00789-y

A single methyl group drastically chnages urea's hydration dynamics

Author(s): Bogdan A. Marenkha; Johannes Hunger
Published in: The Journal of Chemical Pysics, Issue 156; 164504, 2022, ISSN 0021-9606
Publisher: American Institute of Physics
DOI: 10.1063/5.0085461

Complexity in Acid-Base Titrations: Multimer Formation Between Phosphoric Acids and Imines

Author(s): Christian Malm, Heejae Kim, Manfred Wagner, Johannes Hunger
Published in: Chemistry - A European Journal, Issue 23/45, 2017, Page(s) 10853-10860, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201701576

Specific Ion Effects on an Oligopeptide: Bidentate Binding Matters for the Guanidinium Cation

Author(s): Vasileios Balos, Bogdan Marekha, Christian Malm, Manfred Wagner, Yuki Nagata, Mischa Bonn, Johannes Hunger
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201811029

Large Hydrogen-Bond Mismatch between TMAO and Urea Promotes Their Hydrophobic Association

Author(s): Wen Jun Xie, Seoncheol Cha, Tatsuhiko Ohto, Wataru Mizukami, Yuezhi Mao, Manfred Wagner, Mischa Bonn, Johannes Hunger, Yuki Nagata
Published in: Chem, Issue 4/11, 2018, Page(s) 2615-2627, ISSN 2451-9294
Publisher: Elsevier
DOI: 10.1016/j.chempr.2018.08.020

Dynamics of Dicyanamide in Ionic Liquids is Dominated by Local Interactions

Author(s): Hunger, Johannes; Roy, Soham; Grechko, Maksim; Bonn, Mischa
Published in: The Journal of Physical Chemistry. B, Issue 2, 2019, ISSN 1520-6106
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcb.8b10849

Hydrogen-bond structure and dynamics of TADDOL asymmetric organo‐catalysts correlate with catalytic activity

Author(s): Cha, S.; Marekha, B.; Wagner, M.; Hunger, J.
Published in: Chemistry A European Journal, 2019, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201901594

CF3-groups critically enhance the binding of thiourea catalysts to ketones - a NMR and FT-IR study

Author(s): Amelie A.Ehrhard, Sebastian Jäger, Christian Malm, Selim Basaran, Johannes Hunger
Published in: Journal of Molecular Liquids, 2019, ISSN 0167-7322
Publisher: Elsevier BV
DOI: 10.1016/j.molliq.2019.111829

Hydrophobic pattern of alkylated ureas markedly affects water rotation and hydrogen bond dynamics in aqueous solution

Author(s): Bogdan A. Marekha, Johannes Hunger
Published in: Physical Chemistry Chemical Physics, Issue 21/37, 2019, Page(s) 20672-20677, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cp04108g

Macroscopic conductivity of aqueous electrolyte solutions scales with ultrafast microscopic ion motions

Author(s): Vasileios Balos, Sho Imoto, Roland R. Netz, Mischa Bonn, Douwe Jan Bonthuis, Yuki Nagata, Johannes Hunger
Published in: Nature Communications, Issue 11/1, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-15450-2

Thesis and dissertations (2)

Catalyst Substrate Interaction of Organo Phosphate Brønsted Acid Catalysts with Imines

Author(s): Christian Malm
Published in: 2020
Publisher: Johannes Gutenberg-Universität Mainz
DOI: 10.25358/openscience-5330

Fundamentals of (Thio)urea Catalysis

Author(s): Amelie A Ehrhard
Published in: 2022
Publisher: Johannes Gutenberg-Universität Mainz
DOI: 10.25358/openscience-6226