Extending the science perspectives of linear wires of carbon atoms from fundamental research to emerging materials

Project Information

EspLORE

Grant agreement ID: 724610

DOI

10.3030/724610

Project closed

EC signature date 1 February 2017

Start date 1 May 2017

End date 30 April 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 981 875,00

EU contribution

€ 1 981 875,00

Coordinated by

POLITECNICO DI MILANO
Italy

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (26)

Designing All Graphdiyne Materials as Graphene Derivatives: Topologically Driven Modulation of Electronic Properties

Author(s): Patrick Serafini; Alberto Milani; Davide M. Proserpio; Carlo S. Casari
Published in: J. Phys Chem C, Issue 2, 2021, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.1c04238

Thiophen‐basierte konjugierte acetylenische Polymere mit dualen aktiven Zentren für effiziente Cokatalysator‐freie photoelektrochemische Wasserreduktion im alkalischen Medium

Author(s): Mino Borrelli; Christine Joy Querebillo; Dominik L. Pastoetter; Tao Wang; Alberto Milani; Carlo Casari; Hoang Khoa Ly; Fan He; Yang Hou; Christof Neumann; Andrey Turchanin; Hanjun Sun; Inez M. Weidinger; Xinliang Feng
Published in: Angewandte Chemie - German Edition, Issue 9, 2021, ISSN 1521-3757
Publisher: Wiley
DOI: 10.1002/ange.202104469

Solvent-dependent termination, size and stability in polyynes synthesized via laser ablation in liquids.

Author(s): Sonia Peggiani; Pietro Marabotti; Riccardo Alberto Lotti; Anna Facibeni; Patrick Serafini; Alberto Milani; Valeria Russo; Andrea Bassi; Carlo Spartaco Casari
Published in: Physical Chemistry Chemical Physics, Issue 1, 2020, ISSN 1463-9084
Publisher: RSC - Royal Society of Chemistry
DOI: 10.1039/d0cp04132g

In situ synthesis of polyynes in a polymer matrix via pulsed laser ablation in a liquid

Author(s): Sonia Peggiani; Anna Facibeni; Alberto Milani; Chiara Castiglioni; Valeria Russo; Andrea Bassi; Carlo Spartaco Casari
Published in: Materials Advances, Issue 1, 2021, ISSN 2633-5409
Publisher: RSC - Royal Society of Chemistry
DOI: 10.1039/d0ma00545b

In situ surface-enhanced Raman spectroscopy to investigate polyyne formation during pulsed laser ablation in liquid

Author(s): P. Marabotti; S. Peggiani; A. Facibeni; P. Serafini; A. Milani; V. Russo; A. Li Bassi; C.S. Casari
Published in: Carbon, Issue 2, 2022, Page(s) 219-229, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2021.12.060

Topology-dependent conjugation effects in graphdiyne molecular fragments

Author(s): Patrick Serafini; Alberto Milani; Matteo Tommasini; Carlo E. Bottani; Carlo S. Casari
Published in: Carbon, Issue 2, 2021, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2021.04.094

Vibrational and nonlinear optical properties of amine-capped push-pull polyynes by infrared and Raman spectroscopy

Author(s): Pietro Marabotti; Alberto Milani; Andrea Lucotti; Luigi Brambilla; Matteo Tommasini; Chiara Castiglioni; Patrycja Męcik; Bartłomiej Pigulski; Sławomir Szafert; Carlo Spartaco Casari
Published in: Carbon Trends, Issue 1, 2021, ISSN 2667-0569
Publisher: Elsevier
DOI: 10.1016/j.cartre.2021.100115

Pulsed laser deposition of single-layer MoS 2 on Au(111): from nanosized crystals to large-area films

Author(s): Francesco Tumino, Carlo S. Casari, Matteo Passoni, Valeria Russo, Andrea Li Bassi
Published in: Nanoscale Advances, 2019, ISSN 2516-0230
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8na00126j

Copper-surface-mediated synthesis of acetylenic carbon-rich nanofibers for active metal-free photocathodes

Author(s): Tao Zhang, Yang Hou, Volodymyr Dzhagan, Zhongquan Liao, Guoliang Chai, Markus Löffler, Davide Olianas, Alberto Milani, Shunqi Xu, Matteo Tommasini, Dietrich R. T. Zahn, Zhikun Zheng, Ehrenfried Zschech, Rainer Jordan, Xinliang Feng
Published in: Nature Communications, Issue 9/1, 2018, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-03444-0

Carbyne: from the elusive allotrope to stable carbon atom wires

Author(s): C.S. Casari, A. Milani
Published in: MRS Communications, Issue 8/02, 2018, Page(s) 207-219, ISSN 2159-6859
Publisher: Cambridge University Press
DOI: 10.1557/mrc.2018.48

Bottom-Up Synthesis of Heteroatom-Doped Chiral Graphene Nanoribbons

Author(s): Xiao-Ye Wang, José I. Urgel, Gabriela Borin Barin, Kristjan Eimre, Marco Di Giovannantonio, Alberto Milani, Matteo Tommasini, Carlo A. Pignedoli, Pascal Ruffieux, Xinliang Feng, Roman Fasel, Klaus Müllen, Akimitsu Narita
Published in: Journal of the American Chemical Society, Issue 140/29, 2018, Page(s) 9104-9107, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b06210

One-pot synthesis and characterization of polyynes end-capped by biphenyl groups (α,ω-biphenylpolyynes)

Author(s): Franco Cataldo, Ornella Ursini, Alberto Milani, Carlo S. Casari
Published in: Carbon, Issue 126, 2018, Page(s) 232-240, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2017.09.098

Structure modulated charge transfer in carbon atomic wires

Author(s): Milani, A.; Barbieri, V.; Facibeni, A.; Russo, V.; Li Bassi, A.; Lucotti, A.; Tommasini, M.; Tzirakis, M. D.; Diederich, F.; Casari, C. S.
Published in: Scientific Reports, Vol 9, Iss 1, Pp 1-10 (2019), Issue 2, 2019, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.3929/ethz-b-000325573

Fingerprints of sp1 Hybridized C in the near-edge X-ray absorption spectra of surface-grown materials

Author(s): Fratesi, Guido; Achilli, Simona; Manini, Nicola; Onida, Giovanni; Baby, Anu; Ravikumar, Abhilash; Ugolotti, Aldo; Brivio, Gian Paolo; Milani, Alberto; Casari, Carlo Spartaco
Published in: Materials, Vol 11, Iss 12, p 2556 (2018), Issue 1, 2018, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma11122556

Scanning tunneling microscopy and Raman spectroscopy of polymeric sp–sp 2 carbon atomic wires synthesized on the Au(111) surface

Author(s): Andi Rabia, Francesco Tumino, Alberto Milani, Valeria Russo, Andrea Li Bassi, Simona Achilli, Guido Fratesi, Giovanni Onida, Nicola Manini, Qiang Sun, Wei Xu, Carlo S. Casari
Published in: Nanoscale, Issue 11/39, 2019, Page(s) 18191-18200, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9nr06552k

A Field-Effect Transistor Based on Cumulenic sp-Carbon Atomic Wires

Author(s): Alberto D. Scaccabarozzi, Alberto Milani, Sonia Peggiani, Stefano Pecorario, Bozheng Sun, Rik R. Tykwinski, Mario Caironi, Carlo S. Casari
Published in: The Journal of Physical Chemistry Letters, Issue 11/5, 2020, Page(s) 1970-1974, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.0c00141

Size-selected polyynes synthesised by submerged arc discharge in water

Author(s): Sonia Peggiani, Andrea Senis, Anna Facibeni, Alberto Milani, Patrick Serafini, Gianmarco Cerrato, Andrea Lucotti, Matteo Tommasini, Daniele Fazzi, Chiara Castiglioni, Valeria Russo, Andrea Li Bassi, Carlo S. Casari
Published in: Chemical Physics Letters, Issue 740, 2020, Page(s) 137054, ISSN 0009-2614
Publisher: Elsevier BV
DOI: 10.1016/j.cplett.2019.137054

Raman and IR spectra of graphdiyne nanoribbons

Author(s): Patrick Serafini, Alberto Milani, Matteo Tommasini, Chiara Castiglioni, Carlo S. Casari
Published in: Physical Review Materials, Issue 4/1, 2020, ISSN 2475-9953
Publisher: American Physical Society
DOI: 10.1103/PhysRevMaterials.4.014001

Interface-Driven Assembly of Pentacene/MoS2 Lateral Heterostructures

Author(s): Francesco Tumino; Andi Rabia; Andrea Li Bassi; Sergio Tosoni; Carlo S. Casari
Published in: J. Phys. Chem. C, Issue 126, 2022, Page(s) 1132–1139, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.1c06661

Vibrational properties of graphdiynes as 2D carbon materials beyond graphene

Author(s): P. Serafini, A. Milani, M. Tommasini, C. Castiglioni, D. M. Proserpio, C. E. Bottani, C. S. Casari
Published in: Physical Chemistry Chemical Physics, Issue 24, 2022, Page(s) 10524-10536, ISSN 1463-9084
Publisher: Royal Society of Chemistry RSC
DOI: 10.1039/d2cp00980c

Steric hindrance in the on-surface synthesis of diethynyl-linked anthracene polymers

Author(s): Simona Achilli, Francesco Tumino, Andi Rabia, Alessio Orbelli Biroli, Andrea Li Bassi, Alberto Bossi, Nicola Manini, Giovanni Onida, Guido Fratesi, Carlo Spartaco Casari
Published in: Physical Chemistry Chemical Physics, Issue 24, 2022, Page(s) 13616-13624, ISSN 1463-9084
Publisher: Royal Society of Chemistry RSC
DOI: 10.1039/d2cp00730d

Stable and Solution‐Processable Cumulenic sp‐Carbon Wires: A New Paradigm for Organic Electronics

Author(s): Stefano Pecorario; Alberto D. Scaccabarozzi; Daniele Fazzi; Edgar Gutiérrez‐Fernández; Vito Vurro; Lorenzo Maserati; Mengting Jiang; Tommaso Losi; Bozheng Sun; Rik R. Tykwinski; Carlo S. Casari; Mario Caironi
Published in: Advanced Materials, Issue 2110468, 2022, Page(s) 1-10, ISSN 1521-4095
Publisher: Wiley-VCH GmbH
DOI: 10.1002/adma.202110468

Hydrophilic Character of Single-Layer MoS2 Grown on Ag(111)

Author(s): Francesco Tumino; Carlo Grazianetti; Christian Martella; Marina Ruggeri; Valeria Russo; Andrea Li Bassi; Alessandro Molle; Carlo S. Casari
Published in: J. Phys. Chem. C, Issue 6, 2021, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.1c01768

Structural, Electronic, and Vibrational Properties of a Two-Dimensional Graphdiyne-like Carbon Nanonetwork Synthesized on Au(111): Implications for the Engineering of sp-sp2 Carbon Nanostructures.

Author(s): Andi Rabia; Francesco Tumino; Alberto Milani; Valeria Russo; Andrea Bassi; Nicolò Bassi; Andrea Lucotti; Simona Achilli; Guido Fratesi; Nicola Manini; Giovanni Onida; Qiang Sun; Wei Xu; Carlo Spartaco Casari
Published in: ACS Applied Nano Materials, Issue 1, 2020, ISSN 2574-0970
Publisher: ACS
DOI: 10.1021/acsanm.0c02665

Thiophene-Based Conjugated Acetylenic Polymers with Dual Active Sites for Efficient Co-Catalyst-Free Photoelectrochemical Water Reduction in Alkaline Medium.

Author(s): Mino Borrelli; Christine Joy Querebillo; Dominik L. Pastoetter; Tao Wang; Alberto Milani; Carlo Casari; Hoang Khoa Ly; Fan He; Yang Hou; Christof Neumann; Andrey Turchanin; Hanjun Sun; Inez M. Weidinger; Xinliang Feng
Published in: Angewandte Chemie, Issue 9, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202104469

Graphdiynes interacting with metal surfaces: first-principles electronic and vibrational properties

Author(s): Simona Achilli; Alberto Milani; Guido Fratesi; Francesco Tumino; Nicola Manini; Giovanni Onida; Carlo S Casari
Published in: 2D Materials, Issue 1, 2021, ISSN 2053-1583
Publisher: IOP - Institute of Physics
DOI: 10.1088/2053-1583/ac26ad

Book chapters (1)

Handbook of Graphene, Volume 3: Graphene-Like 2D Materials

Author(s): Milani, Alberto; LI BASSI, Andrea; Russo, Valeria; Tommasini, MATTEO MARIA SAVERIO; Casari, Carlo S.
Published in: Handbook of Graphene, Volume 3: Graphene-Like 2D Materials, Issue 3, 2019
Publisher: Wiley

Other (1)

Corrigendum to “One-pot synthesis and characterization of polyynes end-capped by biphenyl groups (α,ω-biphenylpolyynes)” [Carbon 126 (2018) 232–240]

Author(s): Franco Cataldo; Ornella Ursini; Alberto Milani; Carlo Spartaco Casari
Published in: Carbon-Corrigendum, Issue 3, 2020, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2020.02.056