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A European Training Network for Functional Hybrid Coatings by Molecular Layer Deposition

Deliverables

Press releases

Press releases at M1 (announcing the network kick-off), M6 (announcing the first training school), M18, M30 (announcing intermediate results), M42 (announcing the network conference) and M48 (reporting on the network conference).

Wikipedia page on Hybrid functional coatings & MLD

The ESRs and their advisors will author and maintain a Wikipedia page on hybrid coating and MLD.

Public part hycoat.eu

An interactive website hycoat.eu will be published to allow world-wide dissemination of the activities and results of the project. The public part of the website will contain general information on MLD, hybrid coatings and public HYCOAT results, and will be continually updated by the ESRs and their supervisors. Both non-expert overviews and in-depth technical information will be available, so that it can be referred to from other more terse forms of communications (e.g. press-releases or public engagement activities.

Li-ion battery demonstrator with porous solid electrolyte and dual conductor coatings (Dem4)

Report on the demonstrator of WP5, including a description of the materials and processes used, and an overview of the key functional properties of the demonstrator device.

Thermoelectric thin-film module demonstrator (Dem3)

Report on the demonstrator of WP4, including a description of the materials and processes used, and an overview of the key functional properties of the demonstrator device.

CMOS interconnect demonstr. with hybrid low-k (Dem2)

Report on the demonstrator of WP4, including a description of the materials and processes used, and an overview of the key functional properties of the demonstrator device.

Demonstrator with hybrid encapsulation of OLED (Dem1)

Report on the demonstrator of WP2, including a description of the materials and processes used, and an overview of the key functional properties of the demonstrator device.

Recruitment

Report on the status of recruitment, including an overview of the candidates that postulated, a description of the selection procedure and the Declarations on Conformity of the selected ESRs.

For each ESR 2+ main author manuscripts
15 Science communication projects

Each ESR will implement a science communication project for public engagement using the tools taught in WS3, targeting a medium and audience of their own choosing. This will develop the ESR’s skills in communicating their research and research experience with society, and vice versa, will have an impact in making the public aware of nanotechnology and HYCOAT research in particular.

Workshops

Report on the organisation of Workshop 1 (M6), Workshop 2 (M9), Workshop 3 (M12), Workshop 4 (M18), Workshop 5 (M24), Workshop 6 (M30), Workshop 7 (M33), Workshop 8 (M36), Workshop 9 (M42).

Network conference

A final network conference will be organized at the end of the HYCOAT Action, targeting an audience from academia and industry to highlight state-of-the-art results in the field of MLD.

Publications

Ultrathin Hybrid SiAlCOH Dielectric Films through Ring-Opening Molecular Layer Deposition of Cyclic Tetrasiloxane

Author(s): Kristina Ashurbekova,* Karina Ashurbekova, Iva Saric, Marco Gobbi, Evgeny Modin, Andrey Chuvilin, Mladen Petravic, Ilmutdin Abdulagatov, and Mato Knez
Published in: Chemistry of Materials, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c04408

Visible-Light Absorbing TiO2

Author(s): Philip, Anish; Ghiyasi, Ramin; Karppinen, Maarit
Published in: Chemistry of nanomaterials for energy, biology and more, Issue 2, 2021, ISSN 2199-692X
Publisher: Wiley-VCH Verlag GmbH & Co
DOI: 10.1002/cnma.202000638

Organic-Component Dependent Crystal Orientation and Electrical Transport Properties in ALD/MLD Grown ZnO-Organic Superlattices.

Author(s): Ramin Ghiyasi; Girish C. Tewari; Maarit Karppinen
Published in: The Journal of Physical Chemistry C, Issue 15, 2020, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.0c03053

Organic-component dependent thermalconductivity reduction in ALD/MLD grownZnO:organic superlattice thin films

Author(s): Ramin Ghiyasi, Milena Milich, John Tomko, Patrick E. Hopkins, and Maarit Karppinen
Published in: Applied physics letters, 2021, ISSN 0003-6951
Publisher: American Institute of Physics
DOI: 10.1063/5.0052450

Converting molecular layer deposited alucone films into Al2O3/alucone hybrid multilayers by plasma densification

Author(s): Juan Santo Domingo Penaranda; Mikko Nisula; Sofie S. T. Vandenbroucke; Sofie S. T. Vandenbroucke; Matthias Minjauw; Jin Li; Andreas Werbrouck; Jonas Keukelier; Jonas Keukelier; Andrea I Pitillas Martínez; Andrea I Pitillas Martínez; Jolien Dendooven; Christophe Detavernier
Published in: Dalton Transactions, Issue 14779226, 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt03896b

Effect of different oxide and hybrid precursors on MOF-CVD of ZIF-8 films

Author(s): Alexander John Cruz; Alexander John Cruz; Giel Arnauts; Martin Obst; Dmitry E. Kravchenko; Philippe M. Vereecken; Steven De Feyter; Ivo Stassen; Tom Hauffman; Rob Ameloot
Published in: Dalton Transactions, Issue 24, 2021, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt00927c

Atomic Layer Deposition of Intermetallic Fe<sub>4</sub>Zn<sub>9</sub> Thin Films from Diethyl Zinc

Author(s): Ramin Ghiyasi; Anish Philip; Ji Liu; Jaakko Julin; Timo Sajavaara; Michael Nolan; Maarit Karppinen
Published in: Chemistry of Materials, Issue 2, 2022, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.2c00907

Templated Solvent-Free Powder Synthesis and MOF-CVD Films ofthe Ultramicroporous Metal−Organic Framework α‑MagnesiumFormate

Author(s): Dmitry E. Kravchenko, Alexander John Cruz, Sabina Rodríguez-Hermida, Nathalie Wauteraerts, Tom Hauffman, and Rob Ameloot
Published in: Chem. Mater., 2020, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c03212

A study on the influence of ligand variation on formamidinate complexes of yttrium: new precursors for atomic layer deposition of yttrium oxide.

Author(s): Sebastian M. J. Beer; Nils Boysen; Arbresha Muriqi; David Zanders; Thomas Berning; Detlef Rogalla; Claudia Bock; Michael Nolan; Anjana Devi
Published in: Dalton Transactions, Issue 1, 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt01634b

Selective Vapor-Phase Doping of Pt Nanoparticles into Phase-Controlled Nanoalloys

Author(s): Nithin Poonkottil; Ranjith K. Ramachandran; Eduardo Solano; Nadadur Veeraraghavan Srinath; Ji-Yu Feng; Andreas Werbrouck; Michiel Van Daele; Matthias Filez; Matthias M. Minjauw; Hilde Poelman; Alessandro Coati; Christophe Detavernier; Jolien Dendooven
Published in: JOURNAL OF PHYSICAL CHEMISTRY C, Issue 4, 2021, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.1c10143

Photoactive Zr-aromatic hybrid thin films made by molecular layer deposition

Author(s): M. Rogowska, E. Bruzell, H. Valen and O. Nilsen,
Published in: RSC Advances, 2022, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2ra02004a

Aerosol Jet Printing of the Ultramicroporous Calcium Squarate Metal–Organic Framework

Author(s): Dmitry E. Kravchenko, Aleksander Matavž, Víctor Rubio-Giménez, Hanne Vanduffel, Margot Verstreken, and Rob Ameloot
Published in: Chemistry of Materials, 2022, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.2c00947

About the importance of purge time in molecular layer deposition of alucone films

Author(s): Hardik Jain; Paul Poodt
Published in: Dalton Transactions, Issue 13, 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt00623a

"Molecular Layer Deposition of ""Magnesicone"", a Magnesium-based Hybrid Material"

Author(s): Jeroen Kint; Felix Mattelaer; Sofie S. T. Vandenbroucke; Sofie S. T. Vandenbroucke; Arbersha Muriqi; Matthias Minjauw; Mikko Nisula; Philippe M. Vereecken; Michael Nolan; Jolien Dendooven; Christophe Detavernier
Published in: Chemistry of Materials, Issue 15, 2020, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b05116

Ferromagnetic Europium Sulfide Thin Films: Influence of Precursors on Magneto-Optical Properties

Author(s): Sebastian M. J. Beer, Arbresha Muriqi, Patrick Lindner, Manuela Winter, Detlef Rogalla, Michael Nolan, Andreas Ney, Jörg Debus, and Anjana Devi
Published in: Chemistry of materials, Issue 08974756, 2022, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c02958

Molecular Layer Deposition of Thermally Stable Polybenzimidazole-Like Thin Films and Nanostructures

Author(s): Saba Ghafourisaleh,Timo Hatanpää,Anton Vihervaara,Kenichiro Mizohata,Marko Vehkamäki,Markku Leskelä,Matti Putkonen,Mikko Ritala
Published in: Advanced Materials Interfaces, 2022, ISSN 2196-7350
Publisher: Wiley-VCH GmbH
DOI: 10.1002/admi.202200370

A carbene stabilized precursor for the spatial atomic layer deposition of copper thin films

Author(s): Nils Boysen; Bujamin Misimi; Arbresha Muriqi; Jan-Lucas Wree; Tim Hasselmann; Detlef Rogalla; Tobias Haeger; Detlef Theirich; Michael Nolan; Michael Nolan; Thomas Riedl; Anjana Devi
Published in: Chemical Communications, Issue 3, 2020, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc05781a

Simultaneously enhanced electrical conductivity and suppressed thermal conductivity for ALD ZnO films via purge-time controlled defects

Author(s): Ramin Ghiyasi; Milena Milich; John Tomko; Girish C. Tewari; Mika Lastusaari; Patrick E. Hopkins; Maarit Karppinen
Published in: Applied Physics Letters, Issue 8, 2022, ISSN 0003-6951
Publisher: American Institute of Physics
DOI: 10.1063/5.0081657

Vapor phase processing: a novelapproach for fabricating functionalhybrid materials

Author(s): Ka Ashurbekova, Kr Ashurbekova, G Botta, O Yurkevich and M Knez
Published in: Nanotechnology, 2020, ISSN 0957-4484
Publisher: Institute of Physics Publishing
DOI: 10.1088/1361-6528/ab8edb

Molecular layer deposition of photoactive metal-naphthalene hybrid thin films.

Author(s): Melania Rogowska; Per-Anders Hansen; Henrik Hovde Sønsteby; Joanna Dziadkowiec; Håkon Valen; Ola Nilsen
Published in: Dalton Transactions, Issue 15, 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt02201f

Photoactive Thin-Film Structures of Curcumin, TiO2 and ZnO.

Author(s): Anish Philip; Ramin Ghiyasi; Maarit Karppinen
Published in: Molecules, Issue 3, 2021, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules26113214

Radical-triggered cross-linking for molecular layer deposition of SiAlCOH hybrid thin films.

Author(s): Kristina Ashurbekova; Karina Ashurbekova; Iva Šarić; Evgeny Modin; Mladen Petravic; Ilmutdin M. Abdulagatov; A. I. Abdulagatov; Mato Knez; Mato Knez
Published in: Chemical Communications, Issue 13597345, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc07858a

First principles study of reactions in alucone growth: the role of the organic precursor

Author(s): A. Muriqi, M. Nolan
Published in: Dalton Transactions, 2020, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01376e

Atomic Layer Deposition of Insulating AlF3/Polyimide Nanolaminate Films

Author(s): Xinzhi Li; Marko Vehkamäki; Mikko Heikkilä; Miika Mattinen; Matti Putkonen; Markku Leskelä; Mikko Ritala
Published in: Coatings, 11(3):355. Multidisciplinary Digital Publishing Institute (MDPI), Issue 7, 2021, ISSN 2079-6412
Publisher: MDPI
DOI: 10.3390/coatings11030355

Template‐mediated control over polymorphism in the vapor‐assisted formation of zeolitic imidazolate framework powders and films

Author(s): Min Tu; Dmitry E. Kravchenko; Benzheng Xia; Víctor Rubio-Giménez; Nathalie Wauteraerts; Rhea Verbeke; Ivo F.J. Vankelecom; Timothée Stassin; Werner Egger; Marcel Dickmann; Heinz Amenitsch; Rob Ameloot
Published in: Angewandte chemie International Edition, Issue 23, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202014791

Atomic/molecular layer deposition of cerium(iii) hybrid thin films using rigid organic precursors

Author(s): Parmish Kaur, Arbresha Muriqi, Jan-Lucas Wree, Ramin Ghiyasi, Muhammad Safdar, Michael Nolan, Maarit Karppinen and Anjana Devi
Published in: Dalton Transactions, 2022, ISSN 1477-9234
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d2dt00353h

Rational Development of Guanidinate and Amidinate Based Cerium and Ytterbium Complexes as Atomic Layer Deposition Precursors: Synthesis, Modeling, and Application

Author(s): Parmish Kaur,Lukas Mai,Arbresha Muriqi,David Zanders,Ramin Ghiyasi,Dr. Muhammad Safdar,Nils Boysen,Manuela Winter,Prof. Michael Nolan,Prof. Maarit Karppinen,Prof. Anjana Devi
Published in: Chemistry -A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202003907

Role of Terminal Groups in Aromatic Molecules on the Growth of Al2O3-Based Hybrid Materials

Author(s): Arbresha Muriqi; Maarit Karppinen; Michael Nolan;
Published in: Dalton Transactions, Issue 14779234, 2021, ISSN 1477-9234
Publisher: American Chemical Society
DOI: 10.1039/d1dt03195c

Oxidative MLD of Conductive PEDOT Thin Films with EDOT and ReCl5 as Precursors

Author(s): Saba Ghafourisaleh, Georgi Popov, Markku Leskelä, Matti Putkonen, and Mikko Ritala
Published in: ACS Omega, 2021, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.1c02029

Biocompatible Silicon-Based Hybrid Nanolayers for Functionalization of Complex Surface Morphologies

Author(s): Karina Ashurbekova; Kristina Ashurbekova; Borja Alonso-Lerma; Iva Šarić; Leire Barandiaran; Evgeny Modin; Mladen Petravić; Raul Perez-Jimenez; Mato Knez
Published in: ACS Applied Nanomaterials, Issue 10, 2022, ISSN 2574-0970
Publisher: American Chemical Society
DOI: 10.1021/acsanm.1c04428

Spatial atmospheric pressure molecular layer deposition of alucone films using dimethylaluminum isopropoxide as the precursor

Author(s): H. Jain, M. Creatore, P. Poodt
Published in: Dalton Transactions, 2022, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt00570k

Entropy-Driven Self-Healing of Metal Oxides Assisted by Polymer–Inorganic Hybrid Materials

Author(s): Oksana Yurkevich,Evgeny Modin,Iva Šarić,Mladen Petravić,Mato Knez
Published in: Advanced Materials, 2022, ISSN 1521-4095
Publisher: Wiley-VCH GmbH
DOI: 10.1002/adma.202202989

ALD coating of centrifugally spun polymeric fibers and postannealing: case study for nanotubular TiO2 photocatalyst

Author(s): Martina Rihova; Oksana Yurkevich; Martin Motola; Ludek Hromadko; Zdenek Spotz; Raul Zazpe; Raul Zazpe; Mato Knez; Jan M. Macak; Jan M. Macak
Published in: Nanoscale Advances, Issue 25160230, 2021, ISSN 2516-0230
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1na00288k

Direct X-ray and electron-beam lithography of halogenated zeolitic imidazolate frameworks

Author(s): Tu, M., Xia, B., Kravchenko, D. E., Tietze, M. L., Cruz, A. J., Stassen, I., ... & Ameloot, R.
Published in: Nature Materials, 2021, ISSN 1476-1122
Publisher: Nature Publishing Group
DOI: 10.1038/s41563-020-00827-x

Cover Feature: Rational Development of Guanidinate and Amidinate Based Cerium and Ytterbium Complexes as Atomic Layer Deposition Precursors: Synthesis, Modeling, and Application (Chem. Eur. J. 15/2021)

Author(s): Parmish Kaur,Lukas Mai,Arbresha Muriqi,David Zanders,Ramin Ghiyasi,Dr. Muhammad Safdar,Nils Boysen,Manuela Winter,Prof. Michael Nolan,Prof. Maarit Karppinen,Prof. Anjana Devi
Published in: 2021
Publisher: Wiley-VCH
DOI: 10.1002/chem.202005268

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