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CORDIS

Double Dynamics for design of new responsive polymer networks and gels

Deliverables

Relating chain stretching and strain hardening to adhesive properties

Led by tesa ESR11

Structure and homogeneity of DD hydrogels

ESR4

Mechanical and adhesive properties of slide-ring DDNs

ESR13

Nonlinear shear behavior of new DDNs (category 2)

ESR8

Relating statistical composition and properties for reversible covalent DDNs

ESR9

Mesh sizes, phase-separated domains and homogeneity of model DDN

ESR10

Mechanical behavior of reversible covalent DDNs and link to potential for new applications

ESR3

Synthesis and basic characterization of DD-slide ring gels

ESR2

Fracture mechanisms and self-healing properties of new DDNs

ESR8

Relating Elasto-capillarity and shear properties of DDNs

ESR7

Relating structure and possible inhomogeneities to nonlinear behavior in model DDNs

ESR5

Yearly ESR progress reports

see title

Structure and homogeneity of reversible covalent DDNs

ESR3

Statistical composition of DD-TPEs and relation to rheology

ESR6

Linear viscoelastic properties of model DDNs

ESR1

Linear viscoelastic properties of DD-slide ring gels

ESR2

Modelling the diffusion processes in DDNs

ESR12

Material parameters and extensibility of new DDNs (Category 2)

ESR6

Study the influence of synthesis protocol on the structure of DDNs

ESR10

Importance of structure and diffusion in coating applications

Led by Allnex ESR10

Relating extensional behavior and their mechanical properties

ESR6

Multiple dynamics in reversible DDNs

ESR11

Nonlinear shear behavior of model DDNs - a

ESR1

Relating elongation behavior to adhesive properties

Ledby tesa ESR6

Synthesis strategies towards large scale production of smart DDNs

ESR1

Role of heterogeneities on application properties of the DDNs

Led by JGU ESPCI ESR10

Extensibility and elasticity of DD-slide ring gels

ESR2

Relating Elasto-capillarity and adhesive properties of DDNs

ESR7

Main parameters in DDNs for governing their rheology

ESR6

Elasto-capillarity in DDNs

ESR7

Ageing, self-healing and slow dynamics mechanisms of reversible covalent DD hydrogels

ESR4

Modelling the linear rheological properties of DDNs

ESR12

Nonlinear shear behavior of model DDNs - b

ESR1

Nonlinear extension behavior of model DDNs

ESR6

Synthesis and basic characterization of model DDNs

ESR1

Modelling the nonlinear viscoelastic properties of sticky DDNs

ESR11

Fracture mechanisms in model DDNs

ESR13

Adhesive and self-adhesive properties of reversible covalent DDNs

ESR13

Synthesis and basic characterization of reversible covalent DDNs

ESR3

Influence of chain stretching on the lifetime of reversible bonds

ESR11

Relating shear thickening behavior and properties of DDNs

ESR5

Synthesis strategies towards well-controlled DD hydrogels based on reversible covalent chemistry

ESR4

Nonlinear shear behavior of model DDNs

ESR5

Time evolution and equilibrium state of phase-separated domains and their influence on the diffusion coefficient

Led by JGU and FORTH ESR10

Relating fracture process to mechanical properties of DDNs

ESR9

Advanced Modules II

The Advanced modules will provide ESRs with a deeper knowledge in a specific field related to their individual research project. Several two-days advanced modules will be offered (see Table in Annex 1.B), covering the different topics of DoDyNet, and credited with 2 ECTS. Advanced Modules II will be organized together with the intermediate meeting II at DTU (Copenhagene). The exact topic will be discussed at the kick-off meeting.

International (final) DoDyNet Conference

Organization of the final conference open to a large audience

Advanced Modules III

The Advanced modules will provide ESRs with a deeper knowledge in a specific field related to their individual research project Several twodays advanced modules will be offered see Table in Annex 1B covering the different topics of DoDyNet and credited with 2 ECTS Advanced Modules III will be organized together with the annual meeting III at the University of Mainz The exact topic will be discussed at the kickoff meeting

Elementary Modules II

The Elementary modules shall provide the basics in each sub-field at a level appropriate for all ESRs, since all must broaden their knowledge and establish a common language with other researchers. They will be given in a three-days course and will be offered twice (at M7 and M18) to ensure that all ESRs will take it. Student performance will be assessed via written examination (small project) and participation to class. A credit of 2 ECTS will be granted.

Statistical tools to determine the composition of DDNs

ESR12

Advanced Modules I

The Advanced modules will provide ESRs with a deeper knowledge in a specific field related to their individual research project. Several two-days advanced modules will be offered (see Table in Annex 1.B), covering the different topics of DoDyNet, and credited with 2 ECTS. Advanced Modules I will be organized together with the project meeting at DSM (Geleen). The exact topic will be discussed at the kick-off meeting.

Elementary Modules I

The Elementary modules shall provide the basics in each sub-field at a level appropriate for all ESRs, since all must broaden their knowledge and establish a common language with other researchers. They will be given in a three-days course and will be offered twice (at M7 and M18) to ensure that all ESRs will take it. Student performance will be assessed via written examination (small project) and participation to class. A credit of 2 ECTS will be granted.

Summer school

A 4-days Summer School will be organized in conjunction with the second annual meeting and mid-term assessment of the network (see Table 1.2b), with the active participation of external expert researchers. These world-leaders will lecture on selected topics of relevance to DoDyNet (see table below). To enhance the impact of this event, the summer school will be open to a selected number of young researchers outside the ITN, with a maximum number of participants of 70. All ESRs will participate and present their research work in posters, as it will be a unique opportunity for them to interact with the visiting experts.

Publication of special Issue on DDNs

see title

2 Articles by ESR in international journals

see title

Creation of an e-course on DDNs

As part of their training programme the ESRs will be asked to develop a general ecourse given as a podcast on DDNs discussing and linking their different aspects synthesis properties modelling with the objective to present it to a large audience on internet This important project will last from Month 12 to Month 36 and will require strong collaboration among ESRs as well as proper supervision from the senior scientists In such a way the ESRs will be taught how to be Marie Sklodowska Curie Ambassadors and inspire the next generation by conveying their passion for research and innovation This work will grant 2 ECTS to each ESR

Website

On month 3, the website should be working.

Publications

Self-Organization at the Crack Tip of Fatigue-Resistant Thermoplastic Polyurethane Elastomers

Author(s): Giorgia Scetta, Eric Euchler, Jianzhu Ju, Nathan Selles, Patrick Heuillet, Matteo Ciccotti, Costantino Creton
Published in: Macromolecules, Issue 54/18, 2021, Page(s) 8726-8737, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.1c00934

Dually Crosslinked Polymer Networks Incorporating Dynamic Covalent Bonds

Author(s): Larissa Hammer, Nathan J. Van Zee, Renaud Nicolaÿ
Published in: Polymers, Issue 13/3, 2021, Page(s) 396, ISSN 2073-4360
Publisher: Polymers
DOI: 10.3390/polym13030396

Nonlinear Shear Rheology of Entangled Polymer Rings

Author(s): Daniele Parisi; Salvatore Costanzo; Youncheol Jeong; Junyoung Ahn; Taihyun Chang; Dimitris Vlassopoulos; Jonathan D. Halverson; Kurt Kremer; Ting Ge; Michael Rubinstein; Gary S. Grest; Watee Srinin; Alexander Y. Grosberg
Published in: Macromolecules, 2021, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.0c02839

Competitive Supramolecular Associations Mediate the Viscoelasticity of Binary Hydrogels

Author(s): Emmanouil Vereroudakis; Minaspi Bantawa; René P. M. Lafleur; Daniele Parisi; Nicholas M. Matsumoto; Joris W Peeters; Emanuela Del Gado; E. W. Meijer; Dimitris Vlassopoulos
Published in: ACS Central Science, 2021, ISSN 2374-7951
Publisher: American Chemical Society
DOI: 10.1021/acscentsci.0c00279

Reversible Hydrogels with Switchable Diffusive Permeability

Author(s): Paola Nicolella, Daniel Lauxen, Mostafa Ahmadi, Sebastian Seiffert
Published in: Macromolecular Chemistry and Physics, Issue 222/16, 2021, Page(s) 2100076, ISSN 1022-1352
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/macp.202100076

Transient dynamics of soft particle glasses in startup shear flow. Part I: Microstructure and time scales

Author(s): Fardin Khabaz, Bruno Flavio Di Dio, Michel Cloitre, Roger T. Bonnecaze
Published in: Journal of Rheology, Issue 65/2, 2021, Page(s) 241-255, ISSN 0148-6055
Publisher: Society of Rheology
DOI: 10.1122/8.0000165

Supramolecular Superparamagnetic Nanocomposites Based on a Magnetite-Filled Unentangled Terpyridine-Functionalized Polymer

Author(s): Guillaume Falco, Pablo Griffiths, Clément Coutouly, Charles-André Fustin, Guilhem P. Baeza
Published in: Macromolecules, Issue 53/13, 2020, Page(s) 5361-5370, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.0c00182

Molecular Dynamics Reveals a Dramatic Drop of the Friction Coefficient in Fast Flows of Polymer Melts

Author(s): Giovanni Ianniruberto; Giuseppe Marrucci
Published in: Macromolecules, 2020, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.0c00230

Melts of Linear Polymers in Fast Flows

Author(s): Giovanni Ianniruberto; Giuseppe Marrucci; Yuichi Masubuchi
Published in: Macromolecules, 2020, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.0c00693

Improvement of Mechanical Properties of Anisotropic Glassy Polystyrene by Introducing Heat-Labile Reversible Bonds

Author(s): Wendi Wang, Jeppe Madsen, Anne L. Skov, Qian Huang
Published in: Macromolecules, Issue 52/23, 2019, Page(s) 9261-9271, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.9b01843

Modeling Unentangled Polystyrene Melts in Fast Elongational Flows

Author(s): Giovanni Ianniruberto, Antonio Brasiello, Giuseppe Marrucci
Published in: Macromolecules, Issue 52/12, 2019, Page(s) 4610-4616, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.9b00658

Origin of Shear Thinning in Unentangled Polystyrene Melts

Author(s): Giovanni Ianniruberto; Giuseppe Marrucci
Published in: Macromolecules, 2020, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.9b02330

Spinning elastic beads: a route for simultaneous measurements of the shear modulus and the interfacial energy of soft materials

Author(s): Alessandro Carbonaro, Kennedy-Nexon Chagua-Encarnacion, Carole-Ann Charles, Ty Phou, Christian Ligoure, Serge Mora, Domenico Truzzolillo
Published in: Soft Matter, Issue 16/36, 2020, Page(s) 8412-8421, ISSN 1744-683X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sm01024c

Selective Initiation from Unprotected Aminoalcohols for the N -Heterocyclic Carbene-Organocatalyzed Ring-Opening Polymerization of 2-Methyl- N- tosyl Aziridine: Telechelic and Block Copolymer Synthesis

Author(s): Camille Bakkali-Hassani, Clément Coutouly, Tassilo Gleede, Joan Vignolle, Frederik R. Wurm, Stéphane Carlotti, Daniel Taton
Published in: Macromolecules, Issue 51/7, 2018, Page(s) 2533-2541, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.7b02493

Threading–Unthreading Transition of Linear-Ring Polymer Blends in Extensional Flow

Author(s): Anine Borger, Wendi Wang, Thomas C. O’Connor, Ting Ge, Gary S. Grest, Grethe V. Jensen, Junyoung Ahn, Taihyun Chang, Ole Hassager, Kell Mortensen, Dimitris Vlassopoulos, Qian Huang
Published in: ACS Macro Letters, Issue 9/10, 2020, Page(s) 1452-1457, ISSN 2161-1653
Publisher: American Chemical Society
DOI: 10.1021/acsmacrolett.0c00607

Morphological origins of temperature and rate dependent mechanical properties of model soft thermoplastic elastomers

Author(s): Simone Sbrescia, Jianzhu Ju, Tom Engels, Evelyne Van Ruymbeke, Michelle Seitz
Published in: Journal of Polymer Science, Issue 59/6, 2021, Page(s) 477-493, ISSN 2642-4150
Publisher: Journal of Polymer Science
DOI: 10.1002/pol.20200791

Competition between shear and biaxial extensional viscous dissipation in the expansion dynamics of Newtonian and rheo-thinning liquid sheets

Author(s): Ameur Louhichi, Carole-Ann Charles, Srishti Arora, Laurent Bouteiller, Dimitris Vlassopoulos, Laurence Ramos, Christian Ligoure
Published in: Physics of Fluids, Issue 33/7, 2021, Page(s) 073109, ISSN 1070-6631
Publisher: American Institute of Physics
DOI: 10.1063/5.0057316

Strain induced strengthening of soft thermoplastic polyurethanes under cyclic deformation

Author(s): Giorgia Scetta, Jianzhu Ju, Nathan Selles, Patrick Heuillet, Matteo Ciccotti, Costantino Creton
Published in: Journal of Polymer Science, Issue 59/8, 2021, Page(s) 685-696, ISSN 2642-4150
Publisher: Journal of Polymer Science
DOI: 10.1002/pol.20210060

Toward a Design for Flowable and Extensible Ionomers: An Example of Diamine-Neutralized Entangled Poly(styrene- co -4-vinylbenzoic acid) Ionomer Melts

Author(s): Wendi Wang, Jeppe Madsen, Natalja Genina, Ole Hassager, Anne L. Skov, Qian Huang
Published in: Macromolecules, Issue 54/5, 2021, Page(s) 2306-2315, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.0c02408

Viscoelasticity and elastocapillarity effects in the impact of drops on a repellent surface

Author(s): Carole-Ann Charles, Ameur Louhichi, Laurence Ramos, Christian Ligoure
Published in: Soft Matter, Issue 17/23, 2021, Page(s) 5829-5837, ISSN 1744-683X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sm00438g

Biaxial extensional viscous dissipation in sheets expansion formed by impact of drops of Newtonian and non-Newtonian fluids

Author(s): Ameur Louhichi, Carole-Ann Charles, Ty Phou, Dimitris Vlassopoulos, Laurence Ramos, Christian Ligoure
Published in: Physical Review Fluids, Issue 5/5, 2020, ISSN 2469-990X
Publisher: Physical Review Fluids
DOI: 10.1103/physrevfluids.5.053602

"Data for paper ""Multispeckle diffusing wave spectroscopy as a tool to study heterogeneous mechanical behavior in soft solids"""

Author(s): Ju, Jianzhu; Cipelletti, Luca; Zoellner, Stephan; Narita, Tetsuharu; Creton, Costantino
Published in: Issue 1, 2022
Publisher: OpenAire
DOI: 10.5281/zenodo.5912067

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