Mechanics with Molecules

Project Information

MEMO

Grant agreement ID: 766864

DOI

10.3030/766864

Project closed

EC signature date 10 August 2017

Start date 1 October 2017

End date 31 March 2022

Funded under

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Total cost

€ 3 997 843,75

EU contribution

€ 3 997 843,75

Coordinated by

TECHNISCHE UNIVERSITAET DRESDEN
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Documents, reports (10)

Exploitation and use plan
Report on cooperative effects on self-assembled layers driving a solid-state nano-gear

Report on cooperative effects on selfassembled layers driving a solidstate nanogear

Dissemination and Academy-Industry day report and planning, 2nd period
10 mm to 1 mm and 1 mm to 10 µm nodes assessed
Report on 1st molecule-car race
Report on the implementation of different axle strategies
Dissemination and Academy-Industry day report and planning, 1st period
Dissemination and Academy-Industry day report, 3rd period

Dissemination and AcademyIndustry day report 3rd period

Report on 2nd molecule-car race

Report on 2nd moleculecar race

Report on the transmission of motion between molecule-gears and a solid state nano-gear

Report on the transmission of motion between moleculegears and a solid state nanogear

Websites, patent fillings, videos etc. (1)

Project website and logo

Other (1)

"2 vol. Springer series ""Advances in Atom and single molecule machines"""

2 vol Springer series Advances in Atom and single molecule machines

Publications

Peer reviewed articles (40)

Ruthenium complexes of sterically-hindered pentaphenylcyclopentadienyl ligands

Author(s): R. Asato, C.J. Martin, Y. Gisbert, S. Abid, T. Kawai, C. Kammerer, G. Rapenne
Published in: RSC Advances, Issue 2022, Issue 20, 2021, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1ra03875c

Desymmetrised pentaporphyrinic gears mounted on metallo-organic anchors

Author(s): S. Abid, Y. Gisbert, M. Kojima, N. Saffon-Merceron, J. Cuny, C. Kammerer, G. Rapenne
Published in: Chemical Science, 2021, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc06379g

STM induced manipulation of azulene-based molecules and nanostructures: the role of the dipole moment

Author(s): T. Kühne, Kwan H. Au-Yeung, Frank Eisenhut, O. Aiboudi, D. A. Ryndyk, G. Cuniberti, F. Lissel, F. Moresco
Published in: Nanoscale, Issue 2020,12, 2020, Page(s) 24471-24476, ISSN 2040-3372
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d0nr06809h

A Nanographene Disk Rotating a single Molecule Gear on a Cu(111) surface

Author(s): H.H. Lin, A. Croy, R. Gutierrez, C. Joachim, and G. Cuniberti
Published in: Nanotechnology, 33, 175701, 2022, ISSN 1361-6528
Publisher: IOP Science
DOI: 10.1088/1361-6528/ac4b4b

Mechanics of molecule-gears with six long teeth

Author(s): W.-H. Soe, M. Kleinwachter, C. Kammerer, G. Rapenne, C. Joachim
Published in: Journal of Physical Chemistry C, Issue 124, 22625-22630, 2020, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.0c08194

Control of long-distance motion of single molecules on a surface.

Author(s): Donato Civita; Marek Kolmer; Grant J. Simpson; An-Ping Li; Stefan Hecht; Stefan Hecht; Stefan Hecht; Leonhard Grill
Published in: Sience, Issue 1, 2020, Page(s) 957-960, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.abd0696

Transmitting Stepwise Rotation among Three Molecule-Gear on the Au(111) Surface.

Author(s): Kwan Ho Au Yeung; Tim Kühne; Frank Eisenhut; Michael Kleinwächter; Yohan Gisbert; Roberto Robles; Nicolás Lorente; Nicolás Lorente; Gianaurelio Cuniberti; Christian Joachim; Gwénaël Rapenne; Gwénaël Rapenne; Claire Kammerer; Francesca Moresco
Published in: The Journal of Physical Chemistry Letters, Issue 1, 2020, Page(s) 15208–15213, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.0c01747

On-Surface Formation of Cyano-Vinylene Linked Chains by Knoevenagel Condensation

Author(s): K. H. Au-Yeung, T. Kühne, D. Becker, M. Richter, D. A. Ryndyk, G. Cuniberti, T. Heine, X. Feng, F. Moresco
Published in: Chemistry. A European Journal, Issue Vol 27, Issue 69, 2021, Page(s) 17336-17340, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103094

Local heat generated by a focused He + ion beam

Author(s): M. Sakukai, S. Nagano and C. Joachim
Published in: Nanotechnology, 31, 345708, 2020, ISSN 1361-6528
Publisher: IOP Publishing
DOI: 10.1088/1361-6528/ab91f3

Electronic decoupling of polyacenes from the underlying metal substrate by sp3 carbon atoms

Author(s): Mohammed, M.S.G., Colazzo, L., Robles, R. et al.
Published in: Communications Physics, 2020, ISSN 2399-3650
Publisher: Springer Nature
DOI: 10.1038/s42005-020-00425-y

A Single Molecule Full Digital Adder

Author(s): W.H. Soe, P. de Mendoza, A.M. Echavarren, C.Joachim
Published in: J. Phys. Chem. Lett, 12, 8528–8532, 2021, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.1c02449

Power discontinuity and shift of the energy onset of a molecular de-bromination reaction induced by hot-electron tunneling

Author(s): Ana Barragán; Ana Barragán; Ana Barragán; Roberto Robles; Nicolás Lorente; Nicolás Lorente; Lucia Vitali
Published in: Nanoscale, Issue 1, 2021, Page(s) 15215-15219, ISSN 2040-3372
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1nr04229g

A molecular rotor functionalized with a photoresponsive brake

Author(s): R. Asato, C.J. Martin, S. Abid, Y. Gisbert, F. Asanoma, T. Nakashima, C. Kammerer, T. Kawai, G. Rapenne
Published in: Inorg. Chem., Issue 60, 3492-3501, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c03330

A dipolar nanocar based on a porphyrin backbone

Author(s): T. Nishino, C.J. Martin, H. Takeuchi, F. Lim, K. Yasuhara, Y. Gisbert, S. Abid, N. Saffon-Merceron, C. Kammerer, G. Rapenne
Published in: Chemistry A European Journal, Issue 26, 12010-12018, 2020, ISSN 1521-3765
Publisher: European Chemical Societies
DOI: 10.1002/chem.202001999

The Emergence of Multiple Coordination Numbers in Gold–Cyanoarene Complexes: A Study of the On-Surface Coordination Mechanism

Author(s): W. Nakanishi, A. Nakata, P. Perez, M. Takeuchi, C. Joachim; K. Sagisaka
Published in: J. Phys. Chem. C. 2021, 125, 9937–9946, 2021, ISSN 2399-3669
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.1c02456

Doublet-Singlet-Doublet Transition in a Single Organic Molecule Magnet On-Surface Constructed with up to 3 Aluminum Atoms

Author(s): W-H. Soe, R. Robles, P. de Mendoza, A.M. Echavarren, N. Lorente, C. Joachim
Published in: Nano Letters, 2021, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.1c02881

Time-dependent framework for energy and charge currents in nanoscale systems

Author(s): Thomas Lehmann, Alexander Croy, Rafael Gutiérrez, Gianaurelio Cuniberti
Published in: Chemical Physics, Issue 514, 2018, Page(s) 176-182, ISSN 0301-0104
Publisher: Elsevier BV
DOI: 10.1016/j.chemphys.2018.01.011

Reversible Photoswitching and Isomer-Dependent Diffusion of Single Azobenzene Tetramers on a Metal Surface

Author(s): Christophe Nacci, Massimo Baroncini, Alberto Credi, Leonhard Grill
Published in: Angewandte Chemie International Edition, Issue 57/46, 2018, Page(s) 15034-15039, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201806536

Surface manipulation of a curved polycyclic aromatic hydrocarbon-based nano-vehicle molecule equipped with triptycene wheels

Author(s): W-H Soe, C Durand, O Guillermet, S Gauthier, H-P Jacquot de Rouville, S Srivastava, C Kammerer, G Rapenne, C Joachim
Published in: Nanotechnology, Issue 29/49, 2018, Page(s) 495401, ISSN 0957-4484
Publisher: Institute of Physics Publishing
DOI: 10.1088/1361-6528/aae0d9

Expedient Synthesis of Thioether-Functionalized Hydrotris(indazolyl)borate as an Anchoring Platform for Rotary Molecular Machines

Author(s): Guillaume Erbland, Yohan Gisbert, Gwénaël Rapenne, Claire Kammerer
Published in: European Journal of Organic Chemistry, Issue 2018/34, 2018, Page(s) 4731-4739, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.201800990

Mechanical Transmission of Rotational Motion between Molecular-Scale Gears

Author(s): H.-H. Lin, A. Croy, R. Gutierrez, C. Joachim, G. Cuniberti
Published in: Physical Review Applied, Issue 13/3, 2020, ISSN 2331-7019
Publisher: Phys. Rev. Applied
DOI: 10.1103/physrevapplied.13.034024

Train of Single Molecule-Gears

Author(s): We-Hyo Soe, Saurabh Srivastava, Christian Joachim
Published in: The Journal of Physical Chemistry Letters, Issue 10/21, 2019, Page(s) 6462-6467, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.9b02259

How to control single-molecule rotation

Author(s): Grant J. Simpson, Víctor García-López, A. Daniel Boese, James M. Tour, Leonhard Grill
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-12605-8

Dodecacene Generated on Surface: Reopening of the Energy Gap

Author(s): Frank Eisenhut, Tim Kühne, Fátima García, Saleta Fernández, Enrique Guitián, Dolores Pérez, Georges Trinquier, Gianaurelio Cuniberti, Christian Joachim, Diego Peña, Francesca Moresco
Published in: ACS Nano, Issue 14/1, 2020, Page(s) 1011-1017, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.9b08456

Atomic-scale spin sensing with a single molecule at the apex of a scanning tunneling microscope

Author(s): B. Verlhac, N. Bachellier, L. Garnier, M. Ormaza, P. Abufager, R. Robles, M.-L. Bocquet, M. Ternes, N. Lorente, L. Limot
Published in: Science, Issue 366/6465, 2019, Page(s) 623-627, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aax8222

Star‐Shaped Ruthenium Complexes as Prototypes of Molecular Gears

Author(s): Guillaume Erbland, Seifallah Abid, Yohan Gisbert, Nathalie Saffon‐Merceron, Yuichiro Hashimoto, Leonardo Andreoni, Théo Guérin, Claire Kammerer, Gwénaël Rapenne
Published in: Chemistry – A European Journal, Issue 25/71, 2019, Page(s) 16328-16339, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201903615

Modular synthesis of pentaarylcyclopentadienyl Ru-based molecular machines via sequential Pd-catalysed cross couplings

Author(s): Yohan Gisbert, Seifallah Abid, Gaëlle Bertrand, Nathalie Saffon-Merceron, Claire Kammerer, Gwénaël Rapenne
Published in: Chemical Communications, Issue 55/97, 2019, Page(s) 14689-14692, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc08384g

Directionality in van der Waals Interactions: The Case of 4-Acetylbiphenyl Adsorbed on Au(111)

Author(s): Vladimír Zobač, Roberto Robles, Nicolás Lorente
Published in: The Journal of Physical Chemistry C, Issue 124/8, 2020, Page(s) 4545-4551, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.9b09599

Biomimetic and Technomimetic Single Molecular Machines

Author(s): Claire Kammerer, Guillaume Erbland, Yohan Gisbert, Toshio Nishino, Kazuma Yasuhara, Gwénaël Rapenne
Published in: Chemistry Letters, Issue 48/4, 2019, Page(s) 299-308, ISSN 0366-7022
Publisher: Chemical Society of Japan/Nippon Kagakukai
DOI: 10.1246/cl.181019

Inducing the controlled rotation of single o-MeO-DMBI molecules anchored on Au(111)

Author(s): Frank Eisenhut, Jörg Meyer, Justus Krüger, Robin Ohmann, Gianaurelio Cuniberti, Francesca Moresco
Published in: Surface Science, Issue 678, 2018, Page(s) 177-182, ISSN 0039-6028
Publisher: Elsevier BV
DOI: 10.1016/j.susc.2018.05.003

On-surface synthesis of nitrogen-doped nanographenes with 5–7 membered rings

Author(s): Dmitry Skidin, Frank Eisenhut, Marcus Richter, Seddigheh Nikipar, Justus Krüger, Dmitry A. Ryndyk, Reinhard Berger, Gianaurelio Cuniberti, Xinliang Feng, Francesca Moresco
Published in: Chemical Communications, Issue 55/32, 2019, Page(s) 4731-4734, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc00276f

Current-induced rotations of molecular gears

Author(s): H H Lin, A Croy, R Gutierrez, C Joachim, G Cuniberti
Published in: Journal of Physics Communications, Issue 3/2, 2019, Page(s) 025011, ISSN 2399-6528
Publisher: IOP Science
DOI: 10.1088/2399-6528/ab0731

Molecular approach for engineering interfacial interactions in magnetic/topological insulator heterostructures

Author(s): M.G. Cuxart, M.A. Valbuena, R. Robles, C. Moreno, F. Bonell, G. Sauthier, I. Imaz, H. Xu, C. Nistor, P. Gargiani, M. Valvidares, D. Maspoch, P. Gambardella
Published in: ACS Nano, Issue 2020, 14, 5, 2020, Page(s) 6285–6294, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.0c02498

Molecular gears from solution to surfaces

Author(s): Y. Gisbert, S. Abid, C. Kammerer, G. Rapenne
Published in: Chemistry A European Journal, Issue 27, 12019-12031, 2021, ISSN 1521-3765
Publisher: European Chemical Societies
DOI: 10.1002/chem.202101489

Divergent synthesis of molecular winch prototypes

Author(s): Y. Gisbert, C. Kammerer, G. Rapenne
Published in: Chemistry A European Journal, Issue 27, 16242-16249, 2021, ISSN 1521-3765
Publisher: European Chemical Societies
DOI: 10.1002/chem.202103126

Inducing Open-Shell Character in Porphyrins through Surface-Assisted Phenalenyl π-Extension

Author(s): Q. Sun, L.M. Mateo, R. Robles, P. Ruffieux, N. Lorente, G. Bottari, T. Torres, R. Fasel
Published in: Journal of the American Chemical Society, 2020, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c07781

Photophysical properties of 1,2,3,4,5-pentaphenylcyclopentadienyl hydrotris(indazolyl) borate ruthenium(II) complexes

Author(s): S. Gao, Y. Gisbert, G. Erbland, S. Abid, C. Kammerer, A. Venturini, G. Rapenne, B. Ventura, N. Armaroli
Published in: Physical Chemistry Chemical Physics, 2021, ISSN 1463-9084
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cp02261j

One-way rotation of a chemically anchored single molecule-rotor

Author(s): F. Eisenhut, T. Kühne, J. Monsalve, S. Srivastava, D. A. Ryndyk, G. Cuniberti, O. Aiboudi, F. Lissel, V. Zobac, R. Robles, N. Lorente, C. Joachim and F. Moresco
Published in: Nanoscale, Issue 2021,13, 2021, Page(s) 16077-16083, ISSN 2040-3372
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d1nr04583k

Superconducting Scanning Tunneling Microscope Tip to Reveal Sub-millielectronvolt Magnetic Energy Variations on Surfaces

Author(s): C. Mier, B. Verlhac, L. Garnier, R. Robles, L. Limot, N. Lorente, D-J. Choi
Published in: The Journal of Physical Chemistry Letters, 2021, Page(s) 2983–2989, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.1c00328

4-acetylbiphenyl on Au (111): on-surface supramolecular chemistry

Author(s): Robles, Roberto; Zobač, Vladimír; Au Yeung , Kwan Ho; Moresco, Francesca; Joachim, Christian; Lorente, Nicolás
Published in: Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2020, Issue 2, 2020, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cp01657h

Book chapters (4)

Mechanical transmission of rotation for molecule gears and solid-state gears

Author(s): Huang-Hsiang Lin; Jonathan Heinze; Alexander Croy; Rafael Gutierrez; Gianaurelio Cuniberti
Published in: Building and Probing Small for Mechanics. Advances in Atom and Single Molecule Machines., 2020, Page(s) 165 - 180, ISBN 978-3-030-56777-4
Publisher: Springer
DOI: 10.1007/978-3-030-56777-4_11

Design and synthesis of a nano-winch

Author(s): Y. Gisbert, A.M. Sirven, G. Rapenne, C. Kammerer
Published in: Building and Probing Small for Mechanics. Advances in Atom and Single Molecule Machines., 2020, ISBN 978-3-030-56777-4
Publisher: Springer
DOI: 10.1007/978-3-030-56777-4_6

Anchoring Molecular Rotors by On-Surface Synthesis

Author(s): Au Yeung, K.H., Kühne, T., Eisenhut, F., Moresco, F.
Published in: Building and Probing Small for Mechanics. Advances in Atom and Single Molecule Machines., 2020, Page(s) 117–130, ISBN 978-3-030-56777-4
Publisher: Springer, Cham
DOI: 10.1007/978-3-030-56777-4_8

Prototypes of Molecular Gears with an Organometallic Piano-Stool Architecture

Author(s): S. Abid, G. Erbland, C. Kammerer, G. Rapenne
Published in: Building and Probing Small for Mechanics. Advances in Atom and Single Molecule Machines., 2020, ISBN 978-3-030-56777-4
Publisher: Springer
DOI: 10.1007/978-3-030-56777-4_5