Sulfur-based solutions for the selective functionalization of organic substrates

Project Information

SULFOSOL

Grant agreement ID: 771295

DOI 10.3030/771295

Project closed

EC signature date 30 January 2018

Start date 1 May 2018

End date 31 January 2024

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 997 500,00

EU contribution € 1 997 500,00

Coordinated by

GEORG-AUGUST-UNIVERSITAT GOTTINGEN STIFTUNG OFFENTLICHEN RECHTS
Germany

Publications

Non-peer reviewed articles (3)

5-(Trifluorovinyl)dibenzothiophenium Triflate: Introducing the 1,1,2-Trifluoroethylene Tether in Drug-Like Structures

Author(s): Zeyu Feng, Xavier Marset, Jaime Tostado, Johannes Kircher, Zhijie She, Christopher Golz, Ricardo A. Mata, Martin Simon, Manuel Alcarazo
Published in: Chemistry A European Journal, 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202203966

Pentafluorocyclopropanation of (Hetero)arenes Using Sulfonium Salts: Applications in Late-Stage Functionalization

Author(s): Zeyu Feng, Lucas Riemann, Zichen Guo, David Herrero, Martin Simon, Christopher Golz, Ricardo A. Mata, and Manuel Alcarazo
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202306764

α-Diazo-λ3-iodanes and α-diazo sulfonium salts: the umpolung of diazo compounds

Author(s): Svenn Timmann, Manuel Alcarazo
Published in: Chem. Commun., 2023, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cc01620j

Peer reviewed articles (11)

Synthesis of 6H-Benzo[c]chromene Scaffolds from O-Benzylated Phenols through a C–H Sulfenylation/Radical Cyclization Sequence

Author(s): Steve Karreman; Simon B. H. Karnbrock; Sebastian Kolle; Christopher Golz; Manuel Alcarazo
Published in: ACS Organic Letters, Issue 2, 2021, Page(s) 23, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c00087

Polymorphism of bis(1,3-benzothiazol-2-yl) trithiocarbonate

Author(s): Kevin Kafuta, Christopher Golz, Manuel Alcarazo
Published in: Acta Crystallographica Section E Crystallographic Communications, Issue 76/7, 2020, Page(s) 1126-1130, ISSN 2056-9890
Publisher: W. T. A. Harrison
DOI: 10.1107/s2056989020008105

Synthetic Applications of Sulfonium Salts

Author(s): Sergei I. Kozhushkov, Manuel Alcarazo
Published in: European Journal of Inorganic Chemistry, Issue 2020/26, 2020, Page(s) 2486-2500, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000249

5-(Diarylimino)- and 5-(sulfoximido)dibenzothiophenium triflates: syntheses and applications as electrophilic aminating reagents

Author(s): Zhen Li; Gonela Vijaykumar; Xiangdong Li; Christopher Golz; Manuel Alcarazo
Published in: Organic & Biomolecular Chemistry, Issue 1, 2021, Page(s) 2941–2948, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1ob00285f

Electrophilic Cyanative Alkenylation of Arenes

Author(s): Mingyue Zhao, Alejandro G. Barrado, Kristin Sprenger, Christopher Golz, Ricardo A. Mata, Manuel Alcarazo
Published in: Organic Letters, Issue 22/13, 2020, Page(s) 4932-4937, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.0c01204

Protein Conjugation by Electrophilic Alkynylation Using 5-(Alkynyl)dibenzothiophenium Triflates

Author(s): Victor Laserna, Alena Istrate, Kevin Kafuta, Tuuli A. Hakala, Tuomas P. J. Knowles, Manuel Alcarazo, Gonçalo J. L. Bernardes
Published in: Bioconjugate Chemistry, Issue 32/8, 2021, Page(s) 1570-1575, ISSN 1043-1802
Publisher: American Chemical Society
DOI: 10.1021/acs.bioconjchem.1c00317

5-(Cyano)dibenzothiophenium Triflate: A Sulfur-Based Reagent for Electrophilic Cyanation and Cyanocyclizations

Author(s): Xiangdong Li, Christopher Golz, Manuel Alcarazo
Published in: Angewandte Chemie International Edition, Issue 58/28, 2019, Page(s) 9496-9500, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201904557

Synthesis, Structure and Reactivity of 5-(Aryl)dibenzothiophe-nium Triflates

Author(s): Manuel Alcarazo, Kafuta Kevin, André Korzun, Marvin Böhm, Christopher Golz
Published in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201912383

Preparation of 5-(Triisopropylalkynyl) dibenzo[b,d]thiophenium triflate

Author(s): Bernd Waldecker
Published in: Organic Syntheses, Issue 96, 2019, Page(s) 258-276, ISSN 2333-3553
Publisher: Organic Syntheses, Inc.
DOI: 10.15227/orgsyn.096.0258

α-Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1-(Dialkylamino)-1,2,3-triazoles.

Author(s): Xiangdong Li; Christopher Golz; Manuel Alcarazo
Published in: Angewandte Chemie (International Ed. in English), Issue 1, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202014775

Reactivity of 5‐(Alkynyl)dibenzothiophenium Salts: Synthesis of Diynes, Vinyl Sulfones, and Phenanthrenes

Author(s): Kevin Kafuta, Christian J. Rugen, Tobias Heilmann, Tianshu Liu, Christopher Golz, Manuel Alcarazo
Published in: European Journal of Organic Chemistry, Issue 2021/29, 2021, Page(s) 4038-4048, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202100323