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Quantum Enhanced Organic Photovoltaics by Strong Coupling of IR Vibrations to an Optical Cavity

Objective

In the quest for solar cell technologies, organic photovoltaics (OPVs) are playing a leading role as a potentially cost-effective and clean solution. Thus, much research has been devoted into increasing power conversion efficiencies (PCE), currently ~10% by optimising material properties at the different steps involved in the conversion of light into charge. There is evidence that charge delocalization and hot charge transfer (CT) states facilitate charge separation at the electron donor/acceptor interface. State-of-the-art OPVs already exhibit very high (>90%) internal quantum efficiencies (IQE). However, PCE relies not only on high IQE but also on minimizing energy loses (e.g. exciton relaxation) and avoiding charge recombination. A possible strategy to increase PCE is to find ways to optimise charge separation that allow simultaneously for high quantum efficiencies and architectures with longer exciton diffusion lengths or lower charge recombination rates. In QuESt we will investigate how to enhance OPV functionality by the emerging approach of modifying material properties through the hybridization of matter and photon states under strong light matter coupling. In particular, the aim of this project is to modify charge separation and eventually PCE in OPVs by engineering strong coupling between IR molecular vibrations and an optical cavity mode. We will develop a theoretical framework to describe the energy structure and charge dynamics in OPVs under strong vibrational coupling that will be benchmarked with non-linear spectroscopy experiments.

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

Multi-annual funding programmes that define the EU’s priorities for research and innovation.

Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2017

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Coordinator

SCUOLA INTERNAZIONALE SUPERIORE DI STUDI AVANZATI DI TRIESTE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 262 269,00
Address
VIA BONOMEA 265
34136 Trieste
Italy

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Region
Nord-Est Friuli-Venezia Giulia Trieste
Activity type
Higher or Secondary Education Establishments
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 262 269,00

Partners (1)

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