Periodic Reporting for period 1 - FREENERGY (Lead-free halide perovskites for the highest efficient solar energy conversion)
Reporting period: 2019-02-01 to 2020-07-31
The ultimate challenge for photovoltaics is to achieve the highest solar energy conversion efficiency, i.e. the 28.8% value reached by GaAs solar cells, using inexpensive and environmentally friendly materials. The PI deems in tin-based halide perovskites as the core material to address the ultimate photovoltaic challenge. Tin-based halide perovskites have all it takes to reach this ambitious goal except for the oxidative instability of tin. Therefore, FREENERGY proposes a ground-breaking approach to overcome this issue, developing new stable tin-based halide perovskites and proving them in the highest efficiency solar cells. The PI designed the research strategy twofold: (i) the synthesis of new materials, focusing on inorganic mixed ion compositions to engineer the perovskite lattice towards intrinsically more stable tin-based perovskites; (ii) the application of new specific supramolecular interactions to create inert self-assembly monolayers onto the perovskite surface that passivate defects and prevent the degradation at the interface with other device components. FREENERGY will reveal the disruptive potential of tin halide perovskites as photovoltaic materials by crossing borders of materials, chemistry and physics science, ultimately aiming at the highest solar energy conversion with inexpensive and environmentally friendly solar cells.
• Going inorganic. The presence of organics enhances oxidative instability during device manufacturing and functioning. The PI expects that working with inorganics, including the perovskite, the contact materials and solvent-free processing, will enable an intrinsically more stable system.
• Tuning the lattice parameters. The oxidative stability of Sn2+ within the bulk of the perovskite crystals hinges on the formation energy of lattice defects, which the PI aims to control tuning the lattice parameters with mixed compositions of inorganic ions.
• Fluorinating the surface. The degradation of the perovskite starts at the surface and then propagates within the bulk of the crystals. The PI will make use of specific supramolecular interactions to passivate the perovskite surface with fluorinated self-assembly monolayers.
Since the beginning of the project, we advanced more rapidly in the last strategic approach - Fluorinating the surface. The interface between the perovskite and the charge-selective contacts composing the device is of paramount importance to control the stability. Undercoordinated ions at the surface are particularly reactive, and they cause rapid oxidation of Sn2+. We demonstrated that self-assembly of Lewis acids or bases on specific sites at the surface of the perovskite enabled to stabilize the surface of the perovskite. We are now ready to implement this material in devices to measure the effective lifetime in working condition.
We are working in parallel on both the strategic approaches Going inorganic and Tuning the lattice parameters, which we expect to provide results within the next reporting period.
Since the first demonstrations of lead halide perovskite as photovoltaic materials, several scientific works proposed alternative lead-free compositions. Sn-based halide perovskites are among the most promising lead-free alternatives. However, the oxidative stability of Sn2+ under solar cells operation need to be addressed. State-of-the-art approaches to this challenge aimed at identifying the best antioxidants to preserve the perovskite from external sources of degradation, such as oxygen and water, or at reducing the interaction with them. While these approaches enabled to achieve longer material lifetimes, they did not directly face the intrinsic oxidative instability of Sn2+ with the result that the photovoltaic efficiency is still far from the real potential of this material. Implementing the strategies described in the previous section, we expected the following results until the end of the project:
1. Lead-free perovskite solar cells with power conversion efficiency over 20%: state-of-the-art PSCs contain lead despite the restrictions of the European Union on hazardous substances in electronics. The PI will demonstrate tin-based PSCs with the highest light-to-electricity power conversion efficiency.
2. Solvent-free perovskite crystallization: manufacturing without solvents reduces the environmental impact. The PI will establish physical vapour deposition as a solvent-free method to crystallize the perovskite and other solar cell components. Physical vapour deposition will enable green and large-scale manufacturing.
3. Stable devices for 25 years outdoor usage: the long-term energy production defines the energy-yield and thus the return on investment. The PI aims to a profitable energy conversion by providing lead-free perovskite in stable solar cells under working condition.