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Energy-efficient membranes for carbon capture by crystal engineering of two-dimensional nanoporous materials

Publications

Towards ultrathin metal-organic frameworks membranes for high- performance separation

Author(s): Liu, Qi Chi, Heng-yu Song, Shuqing Goswami, Ranadip Agrawal, Kumar Varoon
Published in: APL Materials, Issue 11, 2023, ISSN 2166-532X
Publisher: American Institute of Physics
DOI: 10.1063/5.0169507

Nanometer-thick crystalline and amorphous zeolitic imidazolate framework films for membrane and patterning applications

Author(s): Qi Liu; Yurun Miao; Luis Francisco Villalobos; Shaoxian Li; Deepu J. Babu; Cailing Chen; Heng-Yu Chi; Mohammad Tohidi Vahdat; Jian Hao; Shuqing Song; Yu Han; Michael Tsapatsis; Kumar Varoon Agrawal
Published in: Nature Materials, Issue 22, 2023, Page(s) 1387-1393, ISSN 1476-1122
Publisher: Nature Publishing Group
DOI: 10.1038/s41563-023-01669-z

Multipulsed Millisecond Ozone Gasification for Predictable Tuning of Nucleation and Nucleation-Decoupled Nanopore Expansion in Graphene for Carbon Capture.

Author(s): Kuang-Jung Hsu; Luis Francisco Villalobos; Shiqi Huang; Heng-Yu Chi; Mostapha Dakhchoune; Wan-Chi Lee; Guangwei He; Mounir Mensi; Kumar Varoon Agrawal
Published in: ACS Nano, Issue 15 (8), 2021, Page(s) 13230-13239, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.1c02927

Metal Soap Membranes for Gas Separation

Author(s): Qi Liu, Deepu J. Babu, Jian Hao, Mohammad Tohidi Vahdat, Davide Campi, Kumar Varoon Agrawal
Published in: Advanced Functional Materials, Issue 31/1, 2021, Page(s) 2005629, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.202005629

Bottom-up synthesis of graphene films hosting atom-thick molecular-sieving apertures

Author(s): Villalobos, Luis Francisco Van Goethem, Cédric Hsu, Kuang-Jung Li, Shaoxian Moradi, Mina Zhao, Kangning Dakhchoune, Mostapha Huang, Shiqi Shen, Yueqing Oveisi, Emad Boureau, Victor Agrawal, Kumar Varoon
Published in: Proceedings of the National Academy of Sciences, Issue 118 (37), 2021, Page(s) e2022201118, ISSN 0027-8424
Publisher: National Academy of Sciences
DOI: 10.1073/pnas.2022201118

Gas Separation Membranes with Atom-Thick Nanopores: The Potential of Nanoporous Single-Layer Graphene

Author(s): Luis Francisco Villalobos; Deepu J. Babu; Kuang-Jung Hsu; Cédric Van Goethem; Kumar Varoon Agrawal
Published in: Accounts of Materials Research, Issue 3, 2022, Page(s) 1073-1087, ISSN 2643-6728
Publisher: American Chemical Society
DOI: 10.1021/accountsmr.2c00143

Systematic design of millisecond gasification reactor for the incorporation of gas-sieving nanopores in single-layer graphene

Author(s): Huang, Shiqi Li, Shaoxian Hsu, Kuang-jung Villalobos, Luis Francisco Agrawal, Kumar Varoon
Published in: Journal of Membrane Science, Issue 637, 2021, Page(s) 119628, ISSN 0376-7388
Publisher: Elsevier BV
DOI: 10.1016/j.memsci.2021.119628

Mechanistic Insights on Functionalization of Graphene with Ozone

Author(s): Mohammad Tohidi Vahdat; Shaoxian Li; Shiqi Huang; Luc Bondaz; Nicéphore Bonnet; Kuang-Jung Hsu; Nicola Marzari; Kumar Varoon Agrawal
Published in: The Journal of Physical Chemistry C, Issue 127, 2023, Page(s) 22015-22022, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.3c03994

Synthesis of high-performance polycrystalline metal–organic framework membranes at room temperature in a few minutes

Author(s): Jian Hao, Deepu J. Babu, Qi Liu, Heng-Yu Chi, Chunxiang Lu, Yaodong Liu, Kumar Varoon Agrawal
Published in: Journal of Materials Chemistry A, Issue 8/16, 2020, Page(s) 7633-7640, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9ta12027k

Millisecond lattice gasification for high-density CO 2 - and O 2 -sieving nanopores in single-layer graphene

Author(s): Huang, Shiqi Li, Shaoxian Villalobos, Luis Francisco Dakhchoune, Mostapha Micari, Marina Babu, Deepu J. Vahdat, Mohammad Tohidi Mensi, Mounir Oveisi, Emad Agrawal, Kumar Varoon
Published in: Science Advances, Issue 7(9), 2021, Page(s) eabf0116, ISSN 2375-2548
Publisher: AAAS
DOI: 10.1126/sciadv.abf0116

Ultrathin permselective membranes: the latent way for efficient gas separation

Author(s): Roberto Castro-Muñoz, Kumar Varoon Agrawal, Joaquín Coronas
Published in: RSC Advances, Issue 10/21, 2020, Page(s) 12653-12670, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ra02254c

Demonstrating and Unraveling a Controlled Nanometer‐Scale Expansion of the Vacancy Defects in Graphene by CO<sub>2</sub>

Author(s): Mojtaba Rezaei; Luis Francisco Villalobos; Kuang‐Jung Hsu; Kumar Varoon Agrawal
Published in: Angewandte Chemie International Edition, Issue 61, 2022, Page(s) e202200321, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202200321

In Situ Nucleation‐Decoupled and Site‐Specific Incorporation of Å‐Scale Pores in Graphene Via Epoxidation

Author(s): Shiqi Huang; Luis Francisco Villalobos; Shaoxian Li; Mohammad Tohidi Vahdat; Heng‐Yu Chi; Kuang‐Jung Hsu; Luc Bondaz; Victor Boureau; Nicola Marzari; Kumar Varoon Agrawal
Published in: Advanced Materials, Issue 34, 2022, Page(s) 2206627, ISSN 1521-4095
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adma.202206627

Unraveling the Oxidation of a Graphitic Lattice: Structure Determination of Oxygen Clusters

Author(s): Mohammad Tohidi Vahdat; Shaoxian Li; Shiqi Huang; Carlo A. Pignedoli; Nicola Marzari; Kumar Varoon Agrawal
Published in: Physical Review Letters, Issue 131, 2023, Page(s) 168001, ISSN 0031-9007
Publisher: American Physical Society
DOI: 10.1103/physrevlett.131.168001

Mechanistic Study on Thermally Induced Lattice Stiffening of ZIF-8.

Author(s): Jian Hao; Deepu J. Babu; Qi Liu; Pascal Schouwink; Mehrdad Asgari; Wendy L. Queen; Kumar Varoon Agrawal
Published in: Chemistry of Materials, Issue 33 (11), 2021, Page(s) 4035-4044, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c00455

Structure Evolution of Graphitic Surface upon Oxidation: Insights by Scanning Tunneling Microscopy

Author(s): Li, Shaoxian Vahdat, Mohammad Tohidi Huang, Shiqi Hsu, Kuang-jung Rezaei, Mojtaba Mensi, Mounir Marzari, Nicola Agrawal, Kumar Varoon
Published in: JACS Au, Issue jacsau.1c00570, 2022, Page(s) jacsau.1c00570, ISSN 2691-3704
Publisher: ACS
DOI: 10.1021/jacsau.1c00570

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