Periodic Reporting for period 1 - REMADYL (Removal of Legacy Substances from polyvinylchloride (PVC) via a continuous and sustainable extrusion process)
Reporting period: 2019-06-01 to 2020-11-30
The presence of legacy substances (LS) is a persistent barrier for PVC recycling as there are currently no economically viable solutions for their removal. This seriously hampers the recycling of PVC. Indeed, although the material itself is intrinsically very well suited for recycling (almost 800.000 tons of PVC were recyled in 2019 within VinylPlus), the situation is as follows:
* No viable methods exist to remove lead and plasticizers from PVC
* Mechanical recycling does not remove any of the hazardous substances from PVC
* Lead content in the PVC remains and is transferred into the new product
To reach our ambitious overall project goal, REMADYL has the following key objectives:
* A lab-scale process for rejuvenating PVC
* Detection and sorting process for PVC containing legacy substances
* Pilot line development for a continuous extractive extrusion process for rejuvenating PVC
* Demonstration of the re-use of rejuvenated PVC materials streams
* Safe handing and re-use of the by-products
* Policy contribution at European, national and regional level
The technical R&D work took important steps forward in the first reporting period:
*LS detection techniques were selected, both for lead and plasticizers, that can be further developed towards inline application
*suitable co-solvents and operating conditions for the removal of DEHP have been determined, achieving high extraction rates (>70%)
*first trials for the continuous removal of DEHP using scCO2 extractive extrusion were started. These first results show a stable extrusion process. However the extrusion conditions will require further optimization as so far only fairly low continuous extraction yields have been achieved
*an evaluation of the contaminants and of the by-products have been made, leading to guidelines and a methodology for their safe handling
The work on Health, Safety and Environmental aspects started with compiling data collection templates for the life cycle and other assessments.
Several online dissemination channels to communicate the REMADYL activities and results were created. The project has been presented several times (online) and is part of the Plastics Circularity Multiplier initiative.
Two different pilots are planned:
*Demonstration of the re-use of rejuvenated PVC for soft applications, eg PVC sheets
*Demonstration of the re-use of rejuvenated PVC for rigid applications, eg window frames
In order to establish these demonstrations, we intend to combine a continuous lab-scale and pilot extraction processes with the recycling/re-use of the byproducts. A further attention point is the safe handling of these byproducts.
Furthermore, the sustainability of the entire process will be demonstrated. Further, we will also focus on the regulatory framework and take into account the relevant health, safety and environmental aspects linked to the REMADYL activities.
REMADYL will deliver a breakthrough support to the Circular Economy Package and resource efficiency targets for Europe as recovered PVC will reduce incineration and landfilling. The expected developments are expected to bring the following impacts:
*Increased purity and/or desirable quality of Secondary Raw Materials
*Increased recycling rate for, and reduced landfill and incineration of, Secondary Raw Materials
*Reduced risk of retaining hazardous substances in recycled materials
*The implementation of the European Commission Strategy on Plastics in a Circular Economy and of the SPIRE PPP Roadmap
*Improving industries innovation capacity and creating market opportunities
*Contribution to climate protection: recycling generates lower CO2 emission than producing virgin PVC.