Project description DEENESFRITPL A versatile method to explore and discover sustainable hybrid materials for solar energy conversion Although a popular choice for solar cells, hybrid lead halide perovskites contain toxic lead and lack long-term stability. Moreover, the lack of fully versatile deposition techniques that grow these hybrid films reproducibly and controllably has hindered the full exploration of lead-free and stable hybrid halides. A revolutionary method is needed that will lead to the discovery of new sustainable complex hybrid materials. In response, the EU-funded CREATE project aims to develop a new approach that allows stoichiometric and layer-by-layer in-vacuum deposition of wide families of organic-inorganic materials, and their mixture in any pre-determined ratio. The project’s work will lead to the design of a new generation of stable, non-toxic, hybrid films, opening up new possibilities in solar energy conversion. Show the project objective Hide the project objective Objective With an unprecedented rise in solar cell efficiencies and ease of fabrication, hybrid lead halide perovskites (PbHP) have gained worldwide popularity. However, these materials still rely on the use of toxic Pb and lack of long-term stability. Moreover, distracted by a race for higher conversion efficiencies, the development of in-vacuum deposition techniques to reproducibly and controllably grow these hybrid films has been highly overlooked. This is now the main hurdle for the full exploration of Pb-free and stable hybrid halides, which might not be as defect tolerant or easily produced by solution process as PbHP. Therefore, a revolutionary method allowing the discovery of new sustainable complex hybrid materials is now, more than ever, of paramount importance. Here I describe a completely new approach that allows stoichiometric and layer-by-layer in-vacuum deposition of wide families of organic-inorganic materials, and their mixture in any pre-determined ratio. To overcome the specific challenges of hybrid film growth (incompatible volatility and solubility) I propose Pulsed Dual-Laser Deposition (PDLD) to decouple the deposition of the inorganic and organic sources with two distinct laser sources, a high energy (UV) and a low energy (IR), all in one vacuum system. Only this decoupling will allow the control and versatility to bridge the hybrid materials discovery gap and to tackle open scientific questions regarding the interplay between the organic and inorganic components, defect nature and their influence on optical properties, carrier scattering and recombination phenomena. Combining these fundamental insights with controlled growth, will enable the design of a new generation of stable and non-toxic hybrid films. My extensive experience in in-vacuum materials synthesis for solar cells, supported by the unique PLD expertise at the host institution will enable a leap in the discovery and understanding of hybrid materials for solar energy conversion and beyond. Fields of science engineering and technologyenvironmental engineeringenergy and fuelsrenewable energysolar energynatural sciencesphysical sciencesopticslaser physicsengineering and technologyenvironmental engineeringenergy and fuelsenergy conversion Programme(s) H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC) Main Programme Topic(s) ERC-2019-STG - ERC Starting Grant Call for proposal ERC-2019-STG See other projects for this call Funding Scheme ERC-STG - Starting Grant Host institution UNIVERSITEIT TWENTE Net EU contribution € 1 750 000,00 Address DRIENERLOLAAN 5 7522 NB Enschede Netherlands See on map Region Oost-Nederland Overijssel Twente Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Total cost € 1 750 000,00 Beneficiaries (1) Sort alphabetically Sort by Net EU contribution Expand all Collapse all UNIVERSITEIT TWENTE Netherlands Net EU contribution € 1 750 000,00 Address DRIENERLOLAAN 5 7522 NB Enschede See on map Region Oost-Nederland Overijssel Twente Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Total cost € 1 750 000,00
