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Phase map of dynamic, adaptive colloidal crystals far from equilibrium

Project description

Colloidal crystal interactions under scrutiny

Recent research has demonstrated that colloidal crystals display characteristics similar to living organisms such as self-replication, self-healing, adaptation, competition and motility. The aim of the EU-funded Ph.D. project is to further investigate how dynamic adaptive colloidal crystals behave far from equilibrium, and how to control interactions down to nanometre scale. In this context, researchers will employ an ultrafast laser to drive a quasi-2D confined colloidal system far from thermodynamic equilibrium. The team expect to observe the formation of a rich set of dynamic adaptive colloidal crystals from pure polystyrene spheres of 500 nm diameter. Uncovering the principles of complex, dynamic adaptive systems will have important implications in a number of different fields including microfluidics, biology and nanoscience.

Objective

We recently reported the first observation of dynamic adaptive colloidal crystals exhibiting characteristics similar to those commonly associated with living organisms: self-replication, self-healing, adaptation, competition, motility. Here, I propose to do the first experiments to clarify precisely how dynamic adaptive behavior arises far from equilibrium and how to control it. The key to both is a fundamental question at the heart of condensed matter, statistical and nonlinear physics: When far from equilibrium, in the presence of fluctuations and faced with multiple steady states with small energy differences, how does a system evolve? Specifically, my objectives are (1) to form crystals with periodic and aperiodic patterns, e.g. 2D Bravais lattices, quasicrystals, using passive identical particles, (2) to quantify their formation energies through the effective temperature of Brownian particles, (3) to identify the conditions for emergence and control of adaptive behavior. Then, I will draw a complete phase map of these dynamic adaptive colloidal crystals using fitness landscapes to characterize each pattern. I will further ask to what extent this control is extendable down to the few-nm scale, where fluctuations are even stronger and if and how these findings change when using nonidentical, in size or shape, but still passive particles. My system comprises quasi-2D-confined pure-polystyrene 500-nm spheres suspended in water. An energy flux to drive the system far from equilibrium and sustain it there is supplied by an ultrafast laser. My method exploits only three physical tenets, nonlinearity, fluctuations and positive/negative feedback mechanisms acting on identical passive particles, yet generates extremely rich emergent dynamics. A full understanding of how such dynamics arise from so few basic ingredients will advance our understanding of complex systems in addition to numerous practical applications to self-assembly, microfluidics, nanoscience and biology.

Fields of science (EuroSciVoc)

Programme(s)

Topic(s)

Funding Scheme

ERC-STG - Starting Grant

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Call for proposal

(opens in new window) ERC-2019-STG

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Host institution

RUHR-UNIVERSITAET BOCHUM
Net EU contribution
€ 918 353,75
Address
UNIVERSITAETSSTRASSE 150
44801 Bochum
Germany
Region
Nordrhein-Westfalen Arnsberg Bochum, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
Links
Total cost
€ 918 353,75

Beneficiaries (2)