Helical systems for chiral organic light emitting diodes

Project Information

HEL4CHIROLED

Grant agreement ID: 859752

DOI 10.3030/859752

Project closed

EC signature date 9 August 2019

Start date 1 January 2020

End date 30 June 2024

Funded under

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Total cost € 4 108 852,94

EU contribution € 4 108 852,94

Coordinated by

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Open Research Data Pilot (2)

Data Management Plan

Description of the Data Management Plan It will be updated when neccessary

HEL4CHIROLED web portal

Conception and diffusion of the website dedicated to the HEL4CHIROLED project

Other (9)

Project Identity Set

Identity and information related to the project advertised.

Advertising vacancies for PhD fellowship

Diffusion of doctoral positions at each beneficiary.

Workshop W1

First workshop dedicated on soft skills organized

Recruitment completion

All ESR's recruited.

Workshop W2

Second workshop organized on scientific topics related to the project

Third Workshop W3

Organization of a workshop focused on Entrepreneurship and Private Sector items including intellectual properties, interviews training, visit of companies (coorganized with partner from private sector).

Doctoral HEL4CHIROLED conference

Young researchers European Symposium fully organized by all ESRs

Summer school N3

Organization of a summer school focused on chiral nanotechnologies and chiral optoelectronic devices together with theoretical aspects Courses on biological imaging

Selection of training session

Training session of all ESRs organized

Demonstrators, pilots, prototypes (1)

Completion of the career development plans - PhD degree deliveries

Delivery of all doctoral grades for all ESRs.

Publications

Peer reviewed articles (32)

Porphyrin- and Bodipy-helicene conjugates: syntheses, separation of enantiomers and chiroptical properties

Author(s): V. Silber, M. Jean, N. Vanthuyne, N. del Rio, P. Matozzo, J. Crassous*, R. Ruppert*
Published in: Org. Biomol. Chem., 2023, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3ob01459b

Mutual Monomer Orientation To Bias the Supramolecular Polymerization of [6]Helicenes and the Resulting Circularly Polarized Light and Spin Filtering Properties

Author(s): R. Rodriguez, C. Naranjo, A. Kumar, P. Matozzo, T. Kumar Das, Q. Zhu, N. Vanthuyne, R. Gomez, R. Naaman*, L. Sanchez*, J. Crassous*
Published in: Journal of American Chemistry Society, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c00556

How Subtle Changes Can Make a Difference: Reproducibility in Complex Supramolecular Systems

Author(s): T. Schnitzer, M. D. Preuss, J. van Basten, S. M. C. Schoenmakers, A. J. H. Spiering, G. Vantomme, E. W. Meijer
Published in: Angew. Chem. Int. Ed., Issue 14337851, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202206738

Fast Near-Infrared Photodetectors Based on Nontoxic andSolution-Processable AgBiS2

Author(s): Y-T. Huang, D. Nodari, F. Furlan, Y. Zhang, M. Rusu, L. Dai, Z. Andaji-Garmaroudi, D. Darvill, X. Guo, M. Rimmele, T. Unold, M. Heeney, S. D. Stranks, H. Sirringhaus, A. Rao, N. Gasparini,* R. L. Z. Hoye*
Published in: Small, 2023, ISSN 1613-6829
Publisher: Wiley-VCH GmbH
DOI: 10.1002/smll.202310199

Mesitylated trityl radicals, a platform for doublet emission symmetry breaking, charge-transfer states and conjugated polymers

Author(s): P. Murto, R. Chowdhury, S. Gorgon, E. Guo, W. Zeng, B. Li, Y. Sun, H. Francis, R. H. Friend, H. Bronstein
Published in: Nature Communications, 2023, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-023-39834-2

Chemo- and Regioselective Multiple C(sp2)-H Insertions of Malonate Metal Carbenes for Late-Stage Functionalizations of Azahelicenes

Author(s): Y. Nikolova, B. Fabri, P. Moneva Lorente, A. Guarnieri-Ibañez, A. de Aguirre, Y. Soda, G. Pescitelli, F. Zinna, C. Besnard, L. Guénée, D. Moreau, L. di Bari, E. Bakker, A. I. Poblador-Bahamonde, J. Lacour*
Published in: Angew. Chem. Int. Ed., 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202210798

Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes

Author(s): B. Fabri, T. Funaioli, L. Fréderic, C. Elsner, E. Bordignon, F. Zinna, L. Di Bari, G. Pescitelli, J. Lacour*
Published in: J. Am. Chem. Soc., 2024, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c13487

An S-Shaped Double Helicene Showing both Multi-Resonance Thermally Activated Delayed Fluorescence and Circularly Polarized Luminescence

Author(s): John Dos Santos, Dianming Sun, Juan Manuel Moreno Naranjo, David Hall, Francesco Zinna, Sean T. J. Ryan, Wenda Shi, Tomas Matulaitis, David B. Cordes, Alexandra M. Z. Slawin, David Beljonne, Stuart L. Warriner, Yoann Olivier, Matthew J. Fuchter, Eli Zysman-Colman
Published in: Journal of Material Chemistry C, 2022, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2tc00198e

Exciton coupling chirality in helicene-porphyrin conjugates

Author(s): Kais Dhbaibi, Paola Matozzo, Laura Abella, Marion Jean, Nicolas Vanthuyne, Jochen Autschbach, Ludovic Favereau, Jeanne Crassous
Published in: Chemical Communications, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc03314j

Spin Filtering in Supramolecular Polymers Assembled from Achiral Monomers Mediated by Chiral Solvents

Author(s): Amit Kumar Mondal, Marco D. Preuss, Marcin L. Ślęczkowski, Tapan Kumar Das, Ghislaine Vantomme, E. W. Meijer, Ron Naaman
Published in: Journal of the American Chemical Society, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c02983

Tuning Halide Composition Allows Low Dark Current Perovskite Photodetectors With High Specific Detectivity

Author(s): F. Furlan, D. Nodari, E. Palladino, E. Angela, L. Mohan, J. Briscoe, M. J. Fuchter, T. J. Macdonald, G. Grancini, M. A. McLachlan, N. Gasparini
Published in: Adv. Optical Mater., 2022, ISSN 2195-1071
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adom.202201816

Rational Design of New Conjugated Polymers with Main Chain Chirality for Efficient Optoelectronic Devices: Carbo[6]Helicene and Indacenodithiophene Copolymers as Model Compounds

Author(s): C. Gédéon, N. del Rio, F. Furlan, A. Taddeucci, N. Vanthuyne, V. G. Gregoriou, M. J. Fuchter, G. Siligardi, N. Gasparini, J. Crassous*, C. L. Chochos*
Published in: Adv. Materials, 2024, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202314337

Pasteur and chirality: A story of how serendipity favors the prepared minds

Author(s): Ghislaine Vantomme, Jeanne Crassous
Published in: Chirality, 2021, Page(s) 597-601, ISSN 0899-0042
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/chir.23349

Spatially Resolved Chiroptical Spectroscopies Emphasizing Recent Applications to Thin Films of Chiral Organic Dyes

Author(s): G. Albano, A. Taddeucci, G. Pescitelli, L. Di Bari
Published in: Chem. Eur. J., 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202301982

Unlocking same-sign CPL: solvent effects on spectral form and racemisation kinetics in nine-coordinate chiral europium(III) complexes

Author(s): D. F. De Rosa, M. Starck, D. Parker, R. Pal*
Published in: Chem. Eur. J., 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202303227

Two-Photon Circularly Polarized Luminescence of Chiral Eu Complexes

Author(s): O. G. Willis, F. Petri, D. F. De Rosa, A. Mandoli, R. Pal*, F. Zinna*, L. Di Bari*
Published in: J. Am. Chem. Soc., 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c05957

Insights into the origins of inverted circular dichroism in thin films of a chiral side chain polyfluorene

Author(s): L. Minion, J. Wade, J. M. Moreno-Naranjo, S. Ryan, G. Siligardi, M. J. Fuchter
Published in: Chirality, 2023, ISSN 0899-0042
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/chir.23601

Triple Regioselective Functionalization of Cationic [4]Helicenes via Iridium-Catalyzed Borylation and Suzuki Cross-Coupling Reactivity

Author(s): L. Frédéric, B. Fabri, L. Guénée, F. Zinna, L. di Bari, J. Lacour*
Published in: Chem. Eur. J., 2022, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202201853

Circularly Polarized Luminescence from New Heteroleptic Eu(III) and Tb(III) Complexes

Author(s): S. Ruggieri, S. Mizzoni, C. Nardon, E. Cavalli, C. Sissa, M. Anselmi, P. G. Cozzi, A. Gualandi, M. Sanadar, A. Melchior, F. Zinna, O. G. Willis, L. Di Bari, F. Piccinelli
Published in: Inorganic Chemistry, 2023, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c00196

Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)-Based Ravels

Author(s): I. Regini, R. Chowdhury, K. Terlinden, S. Horiuchi, J. J. Holstein, S. Feldmann, G. H. Clever*
Published in: Angew. Chem. Int. Ed., 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202308288

Remarkable near-infrared chiroptical properties of chiral Yb, Tm and Er complexes

Author(s): O. G. Willis, F. Zinna, G. Pescitelli, C. Micheletti, L. di Bari
Published in: Dalton Transactions, Issue 14779234, 2022, Page(s) 518-523, ISSN 1477-9234
Publisher: RSC
DOI: 10.1039/d1dt03843e

Circularly polarized luminescence from Tb(III) interacting with chiral polyether macrocycles

Author(s): A. Homberg, F. Navazio, A. Le Tellier, F. Zinna, A. Furstenberg, C. Besnard, L. di Bari, J. Lacour
Published in: Dalton Transactions, Issue 14779226, 2022, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dt02627a

Efficient 1400-1600 nm Circularly Polarized Luminescence from a Tuned ChiralErbiumComplex

Author(s): O. G. Willis, F. Petri, G. Pescitelli, A. Pucci, E. Cavalli, A. Mandoli, F. Zinna,* L. Di Bari*
Published in: Angew. Chem. Int. Ed., 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202208326

Circularly Polarized Microscopy of Thin Films of Chiral Organic Dyes

Author(s): A. Taddeucci, F. Zinna, G. Siligardi, L. di Bari
Published in: Chem. Biomed. Imaging, 2023, ISSN 2832-3637
Publisher: ACS
DOI: 10.1021/cbmi.3c00049

Chiral Diketopyrrolo[3,4-c]pyrrole-1,2,3-1H-triazole Dyes with Highly Tuneable Properties in Solution and Thin Films

Author(s): G. Albano, F. Zinna, A. Taddeucci, M. A. M. Capozzi, G. Pescitelli, A. Punzi*, L. Di Bari*, G. M. Farinola
Published in: Chem. Eur. J., 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202300291

Weakly Self-Assembled [6]Helicenes: Circularly Polarized Light and Spin Filtering Properties

Author(s): R. Rodriguez, C. Naranjo, A. Kumar, K. Dhbaibi, P. Matozzo, F. Camerel, N. Vanthuyne, R. Gomez, R. Naaman, L. Sanchez, J. Crassous
Published in: Chem. Eur. J., 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202302254

Dinuclear Rhenium Complexes with a Bridging Helicene‐bis‐bipyridine Ligand: Synthesis, Structure, and Photophysical and Chiroptical Properties

Author(s): Nidal Saleh, Debsouri Kundu, Nicolas Vanthuyne, Joanna Olesiak‐Banska, Anna Pniakowska, Katarzyna Matczyszyn, Victoria Y. Chang, Gilles Muller, J. A. Gareth Williams, Monika Srebro‐Hooper, Jochen Autschbach, Jeanne Crassous
Published in: ChemPlusChem, Issue 85/11, 2020, Page(s) 2446-2454, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202000559

Functionalization of Supramolecular Polymers by Dynamic Covalent Boroxine Chemistry

Author(s): M. D. Preuss, T. Schnitzer, S. A. H. Jansen, S. C. J. Meskers, T. H. R. Kuster, X. Lou, E. W. Meijer, G. Vantomme
Published in: Angew. Chem. Int. Ed., 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202402644

Versatile para‐substituted pyridine lanthanide coordination complexes allow late stage tailoring of complex function

Author(s): David Parker, Matthieu Starck, Jack Fradgley, Andrei Batsanov, Davide F De Rosa, Janet Lovett, Michael Taylor, Maria Papa, Jacob Lutter, Matthew Allen
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103243

Chirality and Supramolecular Copolymerizations – The Elusive Role of Subtle Solvation Effects

Author(s): Marco D. Preuss, Stef A. H. Jansen, Ghislaine Vantomme, E. W. Meijer
Published in: Israel Journal of Chemistry, 2021, ISSN 0021-2148
Publisher: Laser Pages Publishing Ltd.
DOI: 10.1002/ijch.202100078

Synthesis, structural characterization, and chiroptical properties of planarly and axially chiral boranils

Author(s): A. Mace, K. Hamrouni, P. Matozzo, M. Coehlo, J. Firlej, F. Aloui, N. Vanthuyne, E. Caytan, M. Cordier, G. Pieters, M. Srebro-Hooper, F. Berree, B. Carboni, J. Crassous
Published in: Chirality, 2023, ISSN 0899-0042
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/chir.23537

Circularly polarised luminescence laser scanning confocal microscopy to study live cell chiral molecular interactions

Author(s): Patrycja Stachelek, Lewis MacKenzie, David Parker, Robert Pal
Published in: Nature Communications, 2022, Page(s) 553, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-022-28220-z