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Next Generation solid oxide fuel cell and electrolysis technology

Deliverables

Innovative SOCs manufacturing routes

Report about requirements of the innovative SOCs manufacturing routes

Optimized SOCs

Optimized SOCs through innovativedeposition of barrier layer

Structural, morphological and electrochemical analyses of SOCs

Report on the structural morphological and electrochemical analyses of SOCs

Plan for Communication & Dissemination updated, 2

Draft Plan for Communication Dissemination updated

Final report
Industrial targets

Definition of the industrial targets

Report on the electrochemical performance

Report on the electrochemicalperformance of novel and robustelectrodes

Performances of single cells

Report on performances of single cells

Electrokinetic analysis

Report on electrokinetic analysis of EIS by physical modeling simulation for H2O electrolysis and rSOC operations

Environmental assessment report

Environmental assessment report of the new SOC materials and processing routes

Test matrix

Test matrix and protocol definition

Optimized fabrication parameters for 3D printing

Report about optimized fabricationparameters for 3D printing large areaSOCs

Performances and durability of short stacks

Report on performances and durability of short stacks

Plan for Communication & Dissemination updated, 1

Draft Plan for Communication & Dissemination updated

Mid-term report

Midterm report

Proposed design of deposition system for industrial scaling-up

Report on proposed design of deposition system for industrial scalingup 3D print sputtering and ALD

Set of recommendations

Set of recommendations to progress SOC beyond NewSOC

Management Tools

Management Tools (templates etc.) available on the web site

Publications

Hole polarons in LaFeO3 and La1−xSrxFeO3−δ: Stability, trapping, mobility, effect of Sr concentration, and oxygen vacancies

Author(s): C. Hartmann, J. Laurencin, and G. Geneste
Published in: Physical Review B, Issue 107, 2023, Page(s) 024104, ISSN 2469-9969
Publisher: American Physical Society
DOI: 10.1103/physrevb.107.024104

Effect of Steam to Carbon Dioxide Ratio on the Performance of a Solid Oxide Cell for H2O/CO2 Co-Electrolysis

Author(s): Bimpiri, N., Konstantinidou, A. Tsiplakides, D., Balomenou, S., Papazisi, K.M.
Published in: Nanomaterials, Issue 13 (2), 2023, Page(s) 299, ISSN 1687-4129
Publisher: MDPI
DOI: 10.3390/nano13020299

Electrical characterization of glass-ceramic sealant-metallic interconnect joined samples under solid oxide electrolysis cell conditions; influence on the microstructure and composition at the different polarized interfaces

Author(s): Hassan Javed, Kai Herbrig, Antonio Gianfranco Sabato, Domenico Ferrero, Massimo Santarelli, Christian Walter, Federico Smeacetto
Published in: Ceramics International, Issue 47/6, 2021, Page(s) 8184-8190, ISSN 0272-8842
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.ceramint.2020.11.176

Enhancement of the intrinsic Ni/GDC activity under rSOC operation by means of Fe–Au doping: An electro-kinetic study

Author(s): F. Zaravelis, D.K. Niakolas
Published in: International Journal of Hydrogen Energy, 2023, ISSN 0360-3199
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2023.06.034

A multiscale model validated on local current measurements for understanding the solid oxide cells performances

Author(s): E. Da Rosa Silva, G. Sassone, M. Prioux, M. Hubert, B. Morel, J. Laurencin
Published in: Journal of Power Sources, Issue 556, 2023, Page(s) 232499, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2022.232499

The promoting effect of Fe on Ni/ GDC for the Solid Oxide H 2 O electrolysis

Author(s): Charalampos Neofytidis, Evangelia Ioannidou, Maria Kollia, Stylianos G. Neophytides, Dimitrios K. Niakolas
Published in: International Journal of Energy Research, Issue 44/13, 2020, Page(s) 10982-10995, ISSN 0363-907X
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/er.5837

Understanding the Ni Migration in Solid Oxide Cell: A Coupled Experimental and Modeling Approach

Author(s): Léa Rorato, Yijing Shang, Shenglan Yang, Maxime Hubert, Karine Couturier, Lijun Zhang, Julien Vulliet, Ming Chen, Jérôme Laurencin
Published in: Journal of The Electrochemical Society, Issue 170, 2023, Page(s) 034504, ISSN 1945-7111
Publisher: The Electrochemical Society
DOI: 10.1149/1945-7111/acc1a3

Transition metals in Ni/GDC for the reversible solid oxide cell operation: Optimization of the Mo-Au-Ni synergy and further enhancement via substitution of Mo with Fe

Author(s): F. Zaravelis, L. Sygellou, A. Soyvalioti and D.K. Niakolas
Published in: Electrochimica Acta, Issue 453, 2023, Page(s) 142343, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2023.142343

Effect of the PH2O/PCO2 and PH2 on the intrinsic electro-catalytic interactions and the CO production pathway on Ni/GDC during solid oxide H2O/CO2 co-electrolysis

Author(s): E. Ioannidou, M. Chavani, S.G. Neophytides, D.K. Niakolas
Published in: Journal of Catalysis, Issue 404, 2021, Page(s) 174-186, ISSN 0021-9517
Publisher: Academic Press
DOI: 10.1016/j.jcat.2021.09.024

Torsional behaviour of glass-joined, laser-processed Crofer 22 APU interconnect: Unravelling the effect of surface roughness on the shear strength

Author(s): F. Smeacetto; E. Zanchi; D. Meena Narayana Menon; D. Janner; S. Lamnini; M. Salvo; S. De La Pierre; H. Javed; M. Ferraris
Published in: Ceramics International, Issue 48, 2022, Page(s) 32837-32843, ISSN 0272-8842
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.ceramint.2022.07.210

Electrode kinetics of porous Ni-3YSZ cermet operated in fuel cell and electrolysis modes for solid oxide cell application

Author(s): Federico Monaco, Elisa Effori, Maxime Hubert, Elisabeth Siebert, Gregory Geneste, Bertrand Morel, Elisabeth Djurado, Dario Montinaro, Jérôme Laurencin
Published in: Electrochimica Acta, Issue 389, 2021, Page(s) 138765, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2021.138765

An Elementary Kinetic Model for the LSCF and LSCF-CGO Electrodes of Solid Oxide Cells: Impact of Operating Conditions and Degradation on the Electrode Response

Author(s): E. Effori, J. Laurencin, E. Da Rosa Silva, M. Hubert, T. David, M. Petitjean, G. Geneste, L. Dessemond, E. Siebert
Published in: Journal of The Electrochemical Society, Issue 168/4, 2021, Page(s) 044520, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abf40a

Electrophoretic deposition of MnCo2O4 coating on Solid Oxide Cell interconnects manufactured through powder metallurgy

Author(s): Zanchi E., Sabato A. G., Monterde M. C., Bernadet L., Torrell M., Calero J. A., Tarancón A., Smeacetto F.
Published in: Materials & Design, Issue 227, 2023, Page(s) 111768, ISSN 0264-1275
Publisher: Elsevier BV
DOI: 10.1016/j.matdes.2023.111768

Large Area Deposition by Radio Frequency Sputtering of Gd0.1Ce0.9O1.95 Buffer Layers in Solid Oxide Fuel Cells: Structural, Morphological and Electrochemical Investigation

Author(s): Coppola, N.; Polverino, P.; Carapella, G.; Ciancio, R.; Rajak, P.; Dario, M.; Martinelli, F.; Maritato, L.; Pianese, C.
Published in: Materials, Issue 14, 2021, Page(s) 5826, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma14195826

The promoting effect of Fe on Ni/ GDC for the Solid Oxide H 2 O electrolysis

Author(s): Charalampos Neofytidis, Evangelia Ioannidou, Maria Kollia, Stylianos G. Neophytides, Dimitrios K. Niakolas
Published in: International Journal of Energy Research, 2020, ISSN 0363-907X
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/er.5837

Low Temperature Performance and Durability of Solid Oxide Fuel Cells with Titanate Based Fuel Electrodes Using Reformate Fuel

Author(s): Christensen, J. O., Sudireddy, B. R., & Hagen, A.
Published in: Journal of The Electrochemical Society, Issue 170, 2023, Page(s) 024515, ISSN 1945-7111
Publisher: The Electrochemical Society
DOI: 10.1149/1945-7111/acbb31

3D printing the next generation of enhanced solid oxide fuel and electrolysis cells

Author(s): Arianna Pesce, Aitor Hornés, Marc Núñez, Alex Morata, Marc Torrell, Albert Tarancón
Published in: Journal of Materials Chemistry A, Issue 8/33, 2020, Page(s) 16926-16932, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ta02803g

Novel SrO-Containing Glass-Ceramic Sealants for Solid Oxide Electrolysis Cells (SOEC): Their Design and Characterization under Relevant Conditions

Author(s): Hassan Javed; Elisa Zanchi; Fabiana D’Isanto; Chiara Bert; Domenico Ferrero; Massimo Santarelli; Federico Smeacetto
Published in: Materials, Issue 15 (17), 2022, Page(s) 5805, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma15175805

Large Area Solid Oxide Fuel Cells with room temperature sputtered barrier layers: the role of the layer thickness and uniformity in the enhancement of the electrochemical performances and durability

Author(s): N. Coppola, H. S.U. Rehman, G. Carapella, P. Polverino, D. Montinaro, F. Martinelli, V. Granata, A. Galdi, L. Maritato, C. Pianese
Published in: International Journal of Hydrogen Energy, 2023, ISSN 0360-3199
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2023.04.170

Printability of carboxymethyl cellulose/glass-containing inks for robocasting deposition in reversible solid oxide cell applications

Author(s): Soukaina Lamnini; Francesco Baino; Giorgia Montalbano; Hassan Javed; Federico Smeacetto
Published in: Materials Letters, Issue 318, 2022, Page(s) 132239, ISSN 0167-577X
Publisher: Elsevier BV
DOI: 10.1016/j.matlet.2022.132239

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