NA ION MATERIALS AS ESSENTIAL COMPONENTS TO MANUFACTURE ROBUST BATTERY CELLS FOR NON-AUTOMOTIVE APPLICATIONS

Deliverables

This deliverable will be the website of the project. This deliverable is linked with the task T8.2.

Dissemination, Communication and Exploitation Plan

This deliverable will establish the basis for the development of common dissemination & exploitation plan in the project. This deliverable is linked with the task T8.1.

Project Management Handbook

This report will consist of a guideline for ensuring the quality of the documents generated in the NAIMA project. The report will give a quick overview of the most relevant management aspects of the project, setting the rules and responsibilities of the partners aimed at ensuring a good quality and progress of the work. This report is associated to the task T9.1.

Report on communication and dissemination activities

This report will monitor the impact of dissemination and communication activities developed in the project It will be a periodic report released on months 12 24 and 36 This deliverable is linked with the task T82

Specification sheets for 6 prototypes

Technical and operational needs (weight of active materials, electrolytes, functionnal BMS, etc.) will be assessed to carry out the project successfully and be in capacity to integrate the cells into modules by the end of the project. The specification sheets for the targeted performances will be translated back into key materials and BMS performances. This deliverable is linked with task T1.2.

General framework of assessment and monitoring protocol

In order to be fully aligned during the project within the consortium, electrochemical testing protocol will be agreed between the partners, along with the final testing procedures for the modules and packs. This deliverable consists mostly in testing protocols and other characterisation procedures. This deliverable is linked with task T1.3.

Gender equality action plan

This action plan will identify all activities to follow during the implementation phase to achieve gender balance in the governance of the project and during the recruitment. This action plan will be committed to provide equal opportunities and will, to the extent possible, aim for gender balance both in the research teams and in the different management bodies. This report is associated to the task T9.1.

Test validation procedure for 3 Business scenarios

The deliverable D51 will present the project management plan for the test validation procedure in the 3 BSs clarifying a the placement of the SIB prototypes within the BSs 1 SIB prototype in each BS b the logistics plan c installation and tuning of the 3 SIB prototypes according to the nature of the 3 real environments The deliverable will be evaluated on describing ac and how clearly the BSs match the endusers requirements set in WP1 for each BS The deliverable 51 matches the activities in task 51

Technology development roadmap

Based on the results obtained on the different applications technology roadmaps will be updated and a forecast of the best performances for the Naion technologies made This will allow a comprehensive study of the competitivity of the technology against other energy storage solutions as well as markets analysis and the best positioning of the Naion cells for the future This deliverable is linked with the task T54

Report on post-mortem cells

This deliverable gathers the results of postmortem tests This deliverable is linked with task T43

Cell prototypes testing under post-mortem conditions in 2 configurations

Post mortem analyses will be carried out on the cells in order to understand ageing mechanisms and how we can further improve our design and materials The deliverable consists in physicochemical characterisation studies and further electrochemical tests This deliverable is linked with task T43

Data Management Plan

This report will establish how data will be managed during the project and after it is completed.This deliverable is linked with the task T8.3.

Publications

The role of specific and active surface areas in optimizing hard carbon irreversible capacity loss in sodium ion batteries†

Author(s): Adrian Beda, Cyril Vaulot, François Rabuel, Matthieu Morcrette and Camélia Matei Ghimbeu
Published in: Energy Advances, 2022, ISSN 2753-1457
Publisher: RSC Publishing
DOI: 10.1039/d2ya00004k

Correlating Structural Properties with Electrochemical Behavior of Non-graphitizable Carbons in Na-Ion Batteries

Author(s): Blaž Tratnik, Nigel Van de Velde, Ivan Jerman, Gregor Kapun, Elena Tchernychova, Matija Tomšič, Andrej Jamnik, Boštjan Genorio, Alen Vizintin*, and Robert Dominko
Published in: ACS Applied Energy Materials, Issue 15205126, 2022, ISSN 1520-5126
Publisher: American Chemical Society
DOI: 10.1021/acsaem.2c01390

Non‐Aqueous Electrolytes for Sodium‐Ion Batteries: Challenges and Prospects Towards Commercialization.

Author(s): Hussein Hijazi, Parth Desai, Sathiya Mariyappan
Published in: Batteries & Supercaps, 2021, ISSN 2566-6223
Publisher: Wiley
DOI: 10.1002/batt.202000277

Deciphering Interfacial Reactions via Optical Sensing to Tune the Interphase Chemistry for Optimized Na‐Ion Electrolyte Formulation

Author(s): Parth Desai, Jiaqiang Huang, Hussein Hijazi, Leiting Zhang, Sathiya Mariyappan, Jean- Marie Tarascon
Published in: Advanced Energy Materials, 2021, ISSN 1600-0404
Publisher: Wiley
DOI: 10.1002/aenm.202101490

Effect of the Particles Morphology on the Electrochemical Performance of Na 3 V 2 (PO 4 ) 2 F 3‐y O y

Author(s): Runhe Fang, Jacob Olchowka, Chloé Pablos, Paula Sanz Camacho, Dany Carlier, Laurence Croguennec, Sophie Cassaignon
Published in: Batteries & Supercaps, 2021, ISSN 2566-6223
Publisher: Chemistry Europe
DOI: 10.1002/batt.202100179

Ionothermal Synthesis of Polyanionic Electrode Material Na 3 V 2 (PO 4 ) 2 FO 2 through a Topotactic Reaction

Author(s): Jacob Olchowka, Long H. B. Nguyen, Emmanuel Petit, Paula Sanz Camacho, Christian Masquelier, Dany Carlier, Laurence Croguennec
Published in: Inorganic Chemistry, 2020, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02546

Towards Reversible High-Voltage Multi-Electron Reactions in Alkali-Ion Batteries Using Vanadium Phosphate Positive Electrode Materials

Author(s): Edouard Boivin, Jean-Noël Chotard, Christian Masquelier, Laurence Croguennec
Published in: Molecules, Issue 26/5, 2021, Page(s) 1428, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules26051428

Challenges of today for Na-based batteries of the future: From materials to cell metrics

Author(s): Ivana Hasa, Sathiya Mariyappan, Damien Saurel, Philipp Adelhelm, Alexey Y. Koposov, Christian Masquelier, Laurence Croguennec, Montse Casas-Cabanas
Published in: Journal of Power Sources, Issue 482, 2021, Page(s) 228872, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2020.228872

Practicality of methyl acetate as a co-solvent for fast charging Na-ion battery electrolytes

Author(s): Parth Desai, John Abou-Rjeily, Jean- Marie Tarascon, Mariyappan Sathiya
Published in: Electrochimica Acta, 2022, ISSN 0013-4686
Publisher: Pergamon Press Ltd.

Particle nanosizing and coating with an ionic liquid: two routes to improve the transport properties of Na3V2(PO4)2FO2

Author(s): Jacob Olchowka, Runhe Fang, Rafael Bianchini Nuernberg, Chloé Pablos, Dany Carlier, Sophie Cassaignon and Laurence Croguennec
Published in: Nanoscale, Issue 20403364, 2022, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2nr01080a

Impact of the F– for O2– substitution in Na3V2(PO4)2F3–yOy on their transport properties and electrochemical performance

Author(s): Runhe Fang, Jacob Olchowka, Chloé Pablos, Rafael Bianchini Nuernberg, Laurence Croguennec, Sophie Cassaignon
Published in: ACS Applied Energy Materials, 2022, ISSN 2574-0962
Publisher: ACS Applied Energy Materials
DOI: 10.1021/acsaem.1c03446

Hard carbon porosity revealed by the adsorption of multiple gas probe molecules (N 2 , Ar, CO 2 , O 2 and H 2 )

Author(s): Adrian Beda, Cyril Vaulot, Camélia Ghimbeu
Published in: Journal of Materials Chemistry, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1039/d0ta10088a

Mastering the synergy between Na 3 V 2 (PO 4 ) 2 F 3 electrode and electrolyte: A must for Na-ion cells

Author(s): Parth Desai, Juan Forero-Saboya, Valentin Meunier, Gwenaëlle Rousse, Michael Deschamps, Artem Abakumov, Jean-Marie Tarascon, Sathiya Mariyappan
Published in: Energy Storage Materials, 2023, ISSN 2405-8297
Publisher: Elsevier
DOI: 10.1016/j.ensm.2023.02.004

River driftwood pretreated via hydrothermal carbonization as a sustainable source of hard carbon for Na-ion battery anodes

Author(s): Abdullah F. Qatarneh, Capucine Dupont, Julie Michel, Loïc Simonin, Adrian Bedal, Camelia MateiGhimbeu, Virginia Ruiz-Villanueva, Denilson da Silva, Hervé Piégay, Mário J. Franca
Published in: Journal of Environmental Chemical Engineering, 2021, Page(s) 106604, ISSN 2213-3437
Publisher: Elsevier BV
DOI: 10.1016/j.jece.2021.106604

Zero volt storage of Na-ion batteries: Performance dependence on cell chemistry

Author(s): Parth Desai, Jiaqiang Huang, Dominique Foix, Jean-Marie Tarascon, Sathiya Mariyappan
Published in: Journal of Power Sources, 2022, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2022.232177

Thermal stability of Na3-xV2(PO4)2F3-yOy: influence of F- for O2- substitution and degradation mechanisms

Author(s): Chloé PABLOS, Jacob OLCHOWKA, Emmanuel PETIT, Gaël Minart, Mathieu Duttine, François Weill, christian masquelier, Dany Carlier, Laurence CROGUENNEC
Published in: ChemRxiv, 2023, ISSN 2573-2293
Publisher: Cambrigde Open Access
DOI: 10.26434/chemrxiv-2023-x2srg

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Deliverables

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