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COUPE - COUPling Excitations

Project description

New theoretical approach to describing the electron-boson coupling

The interaction of electrons with bosons influences the spectral properties of solids in a profound way. Bosons can be crystal lattice vibrations (phonons), collective charge-density fluctuations (plasmons) or bound states of electrons and electron holes (excitons). The GW approximation produces accurate calculations of the quasiparticle energies across a range of materials. Bosonic excitations are described through the time-dependent density-functional theory (TDDFT). Currently, there are few approaches that describe the electron-boson coupling. The EU-funded COUPE project proposes a new combination of GW and TDDFT that couples quasiparticles to all kinds of bosonic excitations. This combination relies on a recently developed 'connector theory' that allows the use of results from the homogeneous electron gas to describe inhomogeneous materials.

Objective

Spectroscopic characterization of matter is ubiquitous in modern material science. Increased resolution and precise control over radiation sources have led to numerous discoveries of previously inaccessible spectroscopic signatures, often linked to complex excitation processes. The main challenge in their interpretation is the fact that excitations are coupled through interactions. A striking signature for this is that spectra often consist of one or more dominant peaks (called quasi-particle), followed by a series of secondary structures (called satellites). The latter, which can be very strong, are pure interaction effects and may be interpreted in terms of coupling of a quasiparticle to a bosonic excitation of the material: a plasmon, exciton, phonon, or any other boson. To solve the electron-boson problem, and, first of all, to set up the description in terms of the most pertinent quasiparticles and bosons, is a major challenge of condensed matter theory. COUPE will face this challenge. Today, quasiparticles are most often described in the GW approximation to many-body perturbation theory, whereas for bosonic excitations one can resort to time-dependent density-functional theory (TDDFT). Only a few approaches exist to describe the coupled problem, with severe limitations. For example, a cumulant expansion on top of GW describes plasmon satellites, but cannot couple to spin excitations, and there is yet no systematic way for improvement. COUPE proposes a new combination of GW and TDDFT which couples quasiparticles to all kinds of bosonic excitations. This combination relies on a recently developed “connector theory” (CT), which allows using results from the homogeneous electron gas to describe inhomogeneous materials. COUPE will further apply it to the simulation of phase transitions in magnetic and superconducting materials under study at the synchrotron SOLEIL in Paris. Preliminary model results confirm the great potential of the approach envisaged in COUPE.

Fields of science (EuroSciVoc)

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Programme(s)

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Topic(s)

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Funding Scheme

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MSCA-IF-EF-ST - Standard EF

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2019

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Coordinator

ECOLE POLYTECHNIQUE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 184 707,84
Address
ROUTE DE SACLAY
91128 PALAISEAU CEDEX
France

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Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 184 707,84
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