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Development of Inorganic Membrane Reactors for Selective Oxidation of Hydrocarbons to Oxygenates in particular n-Butane to Maleic Anhydride

Objective



Objectives and content

Oxidation of hydrocarbons to oxygenates is normally limited by low selectivity due to carbon dioxide formation and by conversion, so the resulting yield is often below 80-90%.

The present research programme focuses on the selective oxidation of n-butane to maleic anhydride where the yield is even below 60%.

Maleic anhydride is an important intermediary in the manufacture of unsaturated polyester resins and the production increases by several per cent annually.

It is the aim of this research programme to develop a reactor based on ceramic membranes where the reaction between butane and air/oxygen takes place either on a catalyst within the membrane tube or at a catalytic surface created within the membrane wall. It is expected that the selectivities achievable in such reactors will be above 90%. The catalyst will be optimized for the membrane reactor. Methods for deposition of catalyst in the membrane reactor wall will be developed and the catalysts and membranes will be thoroughly characterized before and after membrane reactor studies. A package for the design of a pilot or demonstration membrane reactor will be the end product of the project.

It is widely recognized that an industrial breakthrough in the use of high temperature membrane reactors mainly depends on whether or not highly perm-selective and stable membranes will be developed.
Overall, this should lead to a substantially improved process with lower investment costs and lower consumption figures. Besides the increased selectivity, the latter will also involve a substantially reduced emission of carbon dioxide.

The expected development should be transferable to other selective oxidation reactions such as the production of phthalic anhydride and acrylonitrile.

Funding Scheme

CSC - Cost-sharing contracts

Coordinator

HALDOR TOPSOEE A/S
Address
55,Nymoellevej 55
2800 Lyngby
Denmark

Participants (6)

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
France
Address
Avenue Albert Einstein 2
69626 Villeurbanne
Centre National de la Recherche Scientifique
France
Address
2,Place Eugâne Bataillon 2
34095 Montpellier
Du Pont Ibérica SA
Spain
Address
Valle De Tamon - Nubledo
33469 Tabaza
THE UNIVERSITY OF LIVERPOOL
United Kingdom
Address
Ashton Building, Brownlow Hill
L69 3GH Liverpool
UNIVERSIDAD DE ZARAGOZA
Spain
Address
C/ Maria De Luna 3
50015 Zaragoza
University of Limerick
Ireland
Address

61 Limerick