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Content archived on 2024-04-15

Selective catalysts for coal and heavy oil hydrogenation

Objective

The aim of the project is to develop improved catalyst systems for the hydrogenation under mild conditions of coal and conversion of heavy residues of oil as to selectively produce desirable liquid hydrocarbons.

The broad strategy is to test a large number of catalyst formulations in the gas phase hydrogenation of model liquids. The most promising formulations, in terms of activity and selectivity, will be further tested in coal hydrogenation and heavy oil conversion in the liquid phase.
The particular methodology may yield not only improved catalysts but also new knowledge on the course of reactions in these processes which may further lead to process improvements.
The methodology involves consideration of catalyst activity at the level of molecular bonding. The initial screening of catalyst formulations will be carried out in a fixed-bed plug flow reactor where model compounds would be hydrogenated in the vapour-phase. The catalyst formulations would use mainly iron as active components but may also feature other metals in this role together with various carrier materials and structural and chemical promotors; they would be characterised by physical methods. In addition to varying the catalyst composition attention will be paid to different conditions of catalyst pretreatment and also to different reaction conditions in the more promising cases. The model liquids will be chosen so as to demonstrate catalyst activity and selectivity in those reactions of particular interest eg desulphurisation, deoxygenation, denitrification, rearrangement reactions etc...
The application of the most promising formulations to hydrogenation of coal and heavy oil will be performed on the batch scale in stirred autoclaves using model solvents with and without hydrogen transfer properties. The yields of individual substances will be determined by gas chromatography.
An important feature is collaboration with similar EC funded projects in the Netherlands and Spain. This will take the forms of exchange of catalysts coals and oils and the sharing of techniques and should yield good comparability in data and results.

State of advancement:
The first progress report is expected in June 1988.

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Funding Scheme

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CSC - Cost-sharing contracts

Coordinator

UNIVERSITAET KARLSRUHE (TECHNISCHE HOCHSCHULE)
EU contribution
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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