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Content archived on 2024-04-15

TRANSFER MECHANISMS OF RADIONUCLIDES IN THE GEOSPHERE

Objective

IT IS GENERALLY AGREED THAT THE MAIN PROCESSES GOVERNING SOLUTE TRANSPORT IN THE GEOSPHERE ARE : CONVECTION, HYDRODYNAMIC DISPERSION MOLECULAR DIFFUSION (FICK'S LAW) AND INTERACTION WITH THE ROCK MATRIX (ADSORPTION - DESORPTION). IN MOST CASES, WHEN MATHEMATICAL MODELS ARE DESIGNED TO TAKE INTO ACCOUNT ONLY THESE PHYSICAL PHENOMENA, OR EVEN JUST A FEW OF THEM, THEY WILL GIVE A TRUE REPRESENTATION OF REALITY.

IN THE SCIENCE OF NON-EQUILIBRIUM THERMODYNAMICS, WHICH DESCRIBES THE EVOLUTION OF THE SYSTEMS CAUSED BY THERMODYNAMIC FORCES, THIS METHOD DOES AWAY WITH NON-DIAGONAL COUPLINGS OF THE FORCES AND FLUXES. HOWEVER, THIS SIMPLIFICATION IS ONLY VALID IF ONE CAN BE SURE THAT THE EFFECT OF THE COUPLINGS IS NEGLIGIBLE, AND IT IS PROBABLE THAT THE SPECIAL CONDITIONS PREVAILING IN THE VICINITY OF RADIOACTIVE WASTE, IN PARTICULAR THE HIGH TEMPERATURE GRADIENTS, EXCLUDE THE USE OF THE SIMPLIFIED APPROACH.

THE OBJECTIVE OF THIS STUDY IS THEREFORE TO INVESTIGATE THE EFFECTS OF THESE PHYSICAL PHENOMENA AND TO EXPRESS THEM MATHEMATICALLY AS WELL AS TO EVALUATE THE IMPORTANCE OF THEIR ROLE IN THE AFOREMENTIONED SPECIAL CONDITIONS.
The present report describes the work carried out under the framework of the study of nondominant transfer of radionuclides in the geosphere. The objective of the work is to qualitatively assess (and quantitatively through the use of numerical models) the ensemble of phenomena of transport which may play a role in the processes of radionuclide concentration in radioactive waste storage. In effect, the dominant physical phenomena are noticably taken into account in these models which are validated in the majority of cases.
1. THEORETIC RESEARCH :
THIS PHASE MAKES A REVIEW OF THE PRINCIPAL PHENOMENA LIKELY TO PLAY A PART IN THE TRANSFERS OCCURING IN NATURAL MEDIA AND TO EXTRACT AND ADAPT THEIR MATHEMATICAL EXPRESSIONS.

2. BIBLIOGRAPHIC STUDY :
THE BIBLIOGRAPHY, AS EXTENSIVE AS POSSIBLE, IS UNDERTAKEN ON THESE PHENOMENA, IN ORDER MAINLY TO HAVE AN IDEA OF THE SCALE OF THE PARAMETERS INVOLVED.

3. APPLICATIONS :
THE RESULTS OBTAINED WILL BE APPLIED TO THE RADIONUCLIDES TRANSFER IN A GEOLOGICAL MEDIUM, PARTICULARY TO A POROUS MEDIUM. CALCULATIONS WILL BE MADE (1D OR 2D) TO SHOW THE RELATIVE IMPORTANCE OF THE DIFFERENT TRANSFERS, ESPECIALLY REGARDING THE THERMAL EFFECT OF THE DISPOSAL.

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Coordinator

Commissariat à l'Energie Atomique (CEA)
EU contribution
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Address
Centre d'Études de Fontenay-aux-Roses
92265 Fontenay-aux-Roses
France

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Total cost

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