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Content archived on 2024-04-16

A coordinated Research Initiative for Evaluating and Enhancing Chemical Models Used in Radiological Risk Assessment

Objective

The international CHEMVAL Project, initiated in 1987, has been assessing the validity of computer-based models used to describe the geochemistry of radioactive waste disposal systems. The original project /1/2/3/ was concerned, primarily, with the verification of equilibrium models though a number of attempts were made at a priori predictive validation. CHEMVAL2 aims at building on this earlier study by targeting specific areas shown to be of particular concern in radiological assessment. The following aspects are studied:

Temperature effects, ionic strength effects, organic complexation, sorption processes Co: precipitation, coupled modelling.
The international CHEMVAL project has been assessing the validity of computer based models used to describe the chemistry of radioactive waste disposal systems. This project aims to build on earlier studies by targeting specific areas shown to be of particular concern in radiological assessment. Working groups have been established for all technical activities. These will undertake data collation and model verification tests. More demanding validation exercises will be considered only when the new models have been verified adequately but searches for suitable laboratory and field experiments have already begun. In the case of coupled chemical transport modelling, where most of the codes to be used have already been tested to some extent, the situation is more advanced. Bespoke column experiments have been commissioned allowing a methodology for predictive migration modelling to be specified.

A programme of work aimed at assessing the effects of elevated temperatures on the speciation and solubility of radioelements in groundwaters is underway and a series of verification tests have been formulated.

The objectives of work on sorption processes within CHEMVAL2 are to compare the various models which have been incorporated into geochemical speciation codes and to assess their usefulness for simulating observed behaviour in the laboratory and the field. A review of sorption models of varying complexity has been undertaken with emphasis on data availability and the applicability of each approach to predictive modelling studies.
Work programme:

1. Definition and initiation of programme, production of status reviews.
2. Execution of research programmes for each technical area encompassing data review, model development, code verification and model validation.
3. Comparison with experimental studies and reporting.

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Programme(s)

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Topic(s)

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Funding Scheme

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CSC - Cost-sharing contracts

Coordinator

Atkins Wootton Jeffreys Consultants Ltd
EU contribution
No data
Address
Woodcote Grove Ashley Road
KT18 5BW Epsom
United Kingdom

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Total cost

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Participants (8)

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