Objective
The main target of my work is the reductive electrochemical coupling of polychlorinated methanes and related compounds with alkylhalides and other electrophiles in the presence of a sacrificial anode (Mg, Al, Zn) and, if necessary, in the presence of a mediator or transition metal complexes as catalysts. Depending on the nature of the chlorinated compounds the research can be divided into three parts:
Electrolysis of: a) gem-Dichloroalkanes
b) Bromotrifluoromethane, Bromochlorodifluoromethane,
Dibromodifluoromethane
c) Trifluoromethyltoluene, Chlorodifluoromethyltoluene
These compounds will be coupled with electrophiles like aldehydes, ketones, carbon dioxide, alkylhalides, DMF and alkanenitriles. The reactions are planned to be carried out in aprotic solvents in an undivided cell.
These reactions can replace organometallic procedures and have several advantages, especially concerning industrial synthesis. Even organic halides which are not easily converted to the corresponding organometallic species (e.g. trifluoromethyltoluene) can be readilx carboxylated by electrolysis using a sacrificial anode. Especially the fluorinated compounds are usefill intermediates in the synthesis of pharmaceuticals and pesticides.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences organic chemistry aldehydes
- natural sciences chemical sciences organic chemistry ketones
- natural sciences chemical sciences electrochemistry electrolysis
- natural sciences chemical sciences catalysis
- natural sciences chemical sciences organic chemistry aliphatic compounds
You need to log in or register to use this function
We are sorry... an unexpected error occurred during execution.
You need to be authenticated. Your session might have expired.
Thank you for your feedback. You will soon receive an email to confirm the submission. If you have selected to be notified about the reporting status, you will also be contacted when the reporting status will change.
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Data not available
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
94230 Thiais
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.