Objective
Compounds with spinal related structure are interesting as insertion electrodes because of the large number of vacant sites available to insertion and the possibilities for varying the oxidation state and nature of elements, the degree of vacant sites and the distribution of the into the structure.
For this study the spinel host systems has been selected . The nominal composition of the compounds to be studied is: (Cu)[M0.5Snl.5]S4 with M = Mn, Fe, Co and Ni. The aims are:
- the analysis of the inserted Li and electrons in the lattice.
- the modelization of insertion in such materials.
This will be performed by simultaneous X-ray powder diffraction, high resolution NMR, X-ray absorption, Mossbauer measurements and tight binding calculations.
The novelty of this approach is also the attempt to relate physical concepts as may arise in a fundamentally-based model with chemical notions of ionicity and covalence which are of use in finding better routes to synthesis.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
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Programme(s)
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Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
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Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
34095 Montpellier
France
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