Objective
Research objectives and content
Perfluoro cis -2,3- dialkyloxaziridines showed high efficiency for several oxidation reactions. Their use afford good yield, high chemo-,site-, regio- and stereoselectivites .
It would be very interesting to make available oxaziridine in optically active form, due to their specific reactivity and their belonging to a new class of unknown compounds.
New methods for asymmetric synthesis of perfluoro oxaziridines will be studied, starting from azaalkenes and (e.g (+)-monopercamphoric acid) or different chiral peracid. Effect of the oxidizing agent on the chemical and optical yield will be established.
The mechanism between substract and oxaziridines will be investigated, this research will use the kinetic resolution of oxaziridines. The optical purity of resolved oxaziridines will be determined; Normal methods in this case are inaccurate. Development of new method of resolution will be pursued, we have to use a double kinetic resolution with a known optical purity compound.
Training content (objective, benefit and expected impact)
This is a research project in a new field in organic chemistry: "CHIRAL AND NON RACEMIC PERFLUORO cis-2,3- DIALKYLOXAZIRIDINES". I will obtain new knowledge in fluorochemistry and optical purity resolution and improve my former organic synthesis ability.
No real links with industry but possibilities of technology transfer are possible. (Exxon, 3M, Dupont DeNemours)
Links with industry / industrial relevance (22)
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences organic chemistry
- natural sciences chemical sciences electrochemistry electrolysis
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
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Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
20131 Milano
Italy
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.