Objective
Research objectives and content
The objective is to gain control in the generation and photoreactivity of the triplet states of azoalkanes by inclusion inside zeolites. Azoalkanes are the cleanest source of carbon centered radicals. Thermal and photochemical denitrogenation originate radicals. Recently, their triplet states have been observed and characterized and their photochemical behavior has been stablished by carrying out spin-selective product distribution studies. Zeolites are cristalline alumino silicates whose three-dimensional structure is formed by channels and cavities. The free volumen inside the lattice can absorb appropiate-size molecules. It has been found that the photophysical and photochemical properties of these absorbed organic molecules can be modified. This work tries to apply this methodology to azoalkanes by incorporating them into zeolites to gain a more deep insight in the photochemistry of these substrates. The study of polarity and heavy-atom effects and the constrainement experimented by the organics guest inside the cavities are of very much inportance in this work. Training content (objective, benefit and expected impact)
The objective is to expand the employ of zeolites as controlers of the photophysical and photochemical properties of the organic inside. If this work success, we have gained control on these processes of one of the well known families of radical generators.
Links with industry / industrial relevance (22)
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences inorganic chemistry inorganic compounds
- natural sciences chemical sciences physical chemistry photochemistry
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
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Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
97074 Würzburg
Germany
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.