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Content archived on 2024-04-15

STUDY OF THE TRIBOLOGY OF TECHNICAL CERAMICS BASED ON SIC SI 3N4 AND ZRO2 AS A FUNCTION OF TEMPERATURE AND ENVIRONMENT

Objective

The objectives of this project are the understa nding of fundamental aspects of tribological behaviour of technical ceramics as a function of temperature and gaseous atmosphere. It has already been demonstrated in ambient temperature wear tests that changes in the gaseous environment can produce dramatic changes in wear and friction behaviour due to subtle chemical effects. The ceramic couples tested are silicon carbide and silicon nitride. The tribological tests concern both the friction properties and the wear properties. The parameters under study are: - the configuration of the tribological couple (ball-on-disc, limited trapping of debris, disc-on-disc, full trapping of debris), - pressure and velocity, - temperature (up to 1000C), - atmosphere (dry air, air with a controlled humidity, neutral gas).
Silicon carbide and silicon nitride were tested under different atmospheres (controlled humidity air, neutral gas), over a wide temperature range (0 to 1000 C), under different testconfigurations (ball on disc, disc on disc and flat on flat) and under different loads (200 to 10,000 N). Different velocity accommodation mechanisms and third body formation mechanisms were identified through both particle detachment studies and dynamic observations. Third body properties are shown to govern friction and wear behaviour. Solid lubricants can act as very efficient third bodies if they can be made to stay in contact with the first body. A new lubricant which gave good rubbing properties up to and beyond 600 C was developed.

The research covered: investigations into fundamental aspects of tribological behaviour of technical ceramics as a function of temperature and gaseous atmosphere, for applications in engines and other industrial applications with solid lubricants; investigations to maximise the effectiveness of technical ceramics products maximise the effectiveness of dry friction with a new solid lubricant. It was shown that the use of solid lubricants can be a technologically feasible solution to dry friction. A new lubricant was formulated.
THE CERAMIC SAMPLES WILL BE SILICON CARBIDE, SILICON NITRIDE, AND, EVENTUALLY, PARTIALLY STABILIZED ZIRCONIA.

THE TRIBOLOGICAL TESTS WILL CONCERN BOTH THE FRICTION PROPERTIES AND THE WEAR PROPERTIES. THE PARAMETERS UNDER STUDY WILL BE:
- THE CONFIGURATION OF THE TRIBOLOGICAL COUPLE (BALL ON DISK: LIMITED TRAPPING OF DEBRIS; DISK ON DISK: FULL TRAPPING OF DEBRIS).
- PRESSURE AND VELOCITY
- TEMPERATURE (BEYOND 1000 CELSIUS DEGREES)
- ATMOSPHERE (DRY AIR, AIR WITH A CONTROLLED HUMIDITY, NEUTRAL GAS, AND EVENTUALLY "POLLUTED" ATMOSPHERE).

THE NOVEL ASPECTS OF THIS STUDY WILL RELATE TO THE COMBINED EXPERTISE OF THE FOUR PARTNERS WHICH IS EXPECTED TO PRODUCE NEW KNOWLEDGE OF THE COMBINED CHEMICAL AND MECHANICAL MECHANISMS OPERATING IN THE WEAR PROCESSES OF CERAMICS.
ON THE ECONOMIC FRONT, IN ADDITION TO THE APPLICATION EXPECTED IN THERMAL MACHINES (ENGINES) THE STUDY SHOULD HELP IN THE DEVELOPMENT OF TECHNICAL CERAMICS FOR OTHER INDUSTRIAL APPLICATIONS.

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Coordinator

École Nationale Supérieure de Céramiques Industrielles de Limoges
EU contribution
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Address
47-73 avenue Albert Thomas
87065 Limoges
France

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