Objective The main objective of this programme is to understand how colloids could influence the migration behaviour of radionuclides in geological formations. This is being achieved firstly, by identifying the retention mechanisms of colloids and pseudocolloids to mineral surfaces by static and dynamic experiments, and secondly by investigating the formation of pseudocolloids. These studies will provide an insight into retention mechanisms and there upon validate retardation parameters used in transport models, which will be developed to predict colloid transport under conditions relevant to geological disposals. Moreover, this research is focused on model systems (surfaces, colloids) selected from studies carried out on the El Berrocal site (Spain).The main objective of this program is to understand how colloids could influence the migration behaviour of radionuclides in geological formations. This is being achieved firstly by identifying the retention mechanisms of colloids and pseudocolloids (association of radionuclides with colloids) to mineral surfaces by static and dynamic experiments, and secondly by investigating the formation of pseudocolloids. These studies will provide an insight into retention mechanisms and there upon validate retardation parameters used in transport models.Characterization of natural colloids has been achieved through scanning electron microscopy after concentration by ultrafiltration for the determination of composition and size distribution of colloids, and also through photon correlation spectroscopy for the colloid size distribution.The sorption mechanisms of cations onto fine particle suspensions (model colloidal particles such as silica and muscovite mica) and on mineral monoliths (silica, muscovite mica) as a macroscopic equivalent to particle surfaces has been investigated in order to identify processes occurring between particles and cations.The effect of organics coatings on the transport of cations has also been studied. A novel procedure has been developed to coat well defined packing particles (silica) with humic substances.Work has also involved the identification of data needed for the modelling of colloid transport into porous media.Work programme: B.1. Colloid propertiesB.1.1 Colloid characterizationB.1.2 Application to a siteB.2 Sorption mechanismsB.2.1 Association of radioelements with colloidsB.2.2 Interaction of colloids and pseudocolloids on mineral surfacesB.3 Transport mechanismsB.3.1 Transport experiments in model systems without organic coatingsB.3.2 Transport experiments in model systems with organic coatings B.4 Modelling Fields of science natural sciencesphysical sciencescondensed matter physicssoft matter physicsnatural sciencesphysical sciencesopticsmicroscopyelectron microscopyengineering and technologymaterials engineeringcoating and filmsnatural scienceschemical sciencesnuclear chemistryradiation chemistrynatural sciencesphysical sciencestheoretical physicsparticle physicsphotons Programme(s) FP2-RADWASTOM 4C - Specific research and technical development programme (Euratom) in the field of management and storage of radioactive waste, 1990-1994 Topic(s) A.4.3 - Radionuclide migration in the geosphere Call for proposal Data not available Funding Scheme CSC - Cost-sharing contracts Coordinator Commissariat à l'Energie Atomique (CEA) EU contribution No data Address Centre d'Études de Cadarache Sere-Ders 13108 Saint-Paul-lez-Durance France See on map Total cost No data Participants (6) Sort alphabetically Sort by EU Contribution Expand all Collapse all CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE France EU contribution No data Address Université de Paris-sud 11, 104 91405 GOMETZ LA VILLE See on map Total cost No data Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas Spain EU contribution No data Address 22,Avenida Complutense 28040 Madrid See on map Total cost No data GSF-Forschungszentrum für Umwelt und Gesundheit GmbH Germany EU contribution No data Address Ingolstädter Landstraße 1 85764 Neuherberg See on map Total cost No data Intera Information Technologies Ltd United Kingdom EU contribution No data Address Chiltern House 45 Station Road RG9 1AT Henley-on-Thames See on map Total cost No data Universitá degli Studi di Padova Italy EU contribution No data Address Via F. Marzolo 8 35131 Padova See on map Total cost No data Université de Nantes France EU contribution No data Address 2 rue de la Houssinière 44072 Nantes See on map Total cost No data