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Nanomaterial FAte and Speciation in the Environment

Deliverables

Report on modelling the uptake and toxicokinetics of aged NMs in different species under environmental relevant conditions in mesocosms
Protocols and SOPs for ENM characterisation in all environmental compartments
Presentation of exposure assessment framework specification

Presentation of exposure assessment framework specification comprising the stakeholder required outputs desired form format and detail level required for scientific understanding knowledge and guidance

Report on model development and evaluation of model quality for airborne ENM

Report on model development and evaluation of model quality for airborne ENM.

Organisation and minutes for final project progress meeting.
Report on the field tests of airborne ENM on transport, transformation and deposition

Report on the field tests of airborne ENM on transport, transformation and deposition.

Catalogue of potential accidental releases and accidental release model

Catalogue of potential accidental releases and accidental release model.

Report on differences in framework for assessment of intentional versus unintentional terrestrial NM exposures

Report on differences in framework for assessment of intentional versus unintentional terrestrial NM exposures.

NMs behaviour and transformation in sediment pore waters and pore water gradients

NMs behaviour and transformation in sediment pore waters and pore water gradients.

Report on the behaviour of ENM in reactors.
Stochastic model of ENM transport and transformation through  reactors

Stochastic model of ENM transport and transformation through  reactors.

Report on the transfer of ENM through reactors
Report on the pathway analysis
NanoFASE model framework for road–testing

NanoFASE model framework for road–testing.

Inventory of estimates of ENM and nano-enabled products value chain.
Soil property – NM fate relationships

Soil property – NM fate relationships and geographical distribution of possible NM transport distances in Europe.

Characterisation dossiers for ENMs / FFG-transformed ENMs / case studies

Characterisation dossiers for ENMs / FFG-transformed ENMs / case studies.

Publication on review of airborne ENM and possible implications.
Validated EAFr guidance

Validated EAFr guidance.

Report on driving forces of NM behaviour in natural waters for agglomeration and transformation
Final Standardisation Report and Plan

Final Standardisation Report and Plan.

SB4N model framework for road–testing

SB4N model framework for road–testing.

ENM “functional fate classification system” & handbook of functional assays.
Transformation and behaviour of NMs in surface waters in support of modelling since it deals with the same issues only under different water chemistries
Report on the laboratory tests of airborne ENM on surface transformation and atmospheric chemical reactions

Report on the laboratory tests of airborne ENM on surface transformation and atmospheric chemical reactions.

Release estimations during ENMs and nano-enabled products value chain

Release estimations during ENMs and nano-enabled products value chain.

Research report on speciation and transformation of NM in soils.
Exposure assessment framework

Exposure assessment framework. The validated guidance on the use of the individual models, methods and protocols developed within each of the technical WPs will be drawn together into the Exposure Assessment Framework and made freely available as an online catalogue (The “NanoFASE model catalogue”) with the appropriate documentation required (ideally supported by published papers) to enable stakeholders to use and incorporate nano-specific processes into existing exposure and risk assessment models

Report on effects of ageing NMs on in vitro uptake and translocation under relevant gut conditions, including additional parameter sets.
Open training workshop and Training modules

Open training workshop and Training modules.

Description of model framework for agglomeration and removal of NMs

Description of model framework for agglomeration and removal of NMs.

Final model for predicting release of ENM to the environment

Final model for predicting release of ENM to the environment.

Policy and Exploitation Factsheets.
Open stakeholder workshop

Open stakeholder workshop.

Final conference

Final conference.

Open workshop / conference on airborne ENM: Measurements, Implications and Modelling.

Open workshop / conference on airborne ENM: Measurements, Implications and Modelling. To facilitate stakeholder consultation and review of Task 6.4.

Parameter sets for NMs under gut conditions

Parameter sets describing in vitro accumulation efficiency, uptake and translocation of selected pristine NMs under relevant gut conditions reflection different species. Including standard operation procedures on the efficient derivation of the parameters.

Publications

Drift correction of the dissolved signal in single particle ICPMS

Author(s): Geert Cornelis, Sebastien Rauch
Published in: Analytical and Bioanalytical Chemistry, Issue 408/19, 2016, Page(s) 5075-5087, ISSN 1618-2642
Publisher: Springer Verlag
DOI: 10.1007/s00216-016-9509-9

Bioaccumulation of silver in Daphnia magna: Waterborne and dietary exposure to nanoparticles and dissolved silver

Author(s): Fabianne Ribeiro, Cornelis A.M. Van Gestel, Maria D. Pavlaki, Sofia Azevedo, Amadeu M.V.M. Soares, Susana Loureiro
Published in: Science of The Total Environment, Issue 574, 2017, Page(s) 1633-1639, ISSN 0048-9697
Publisher: Elsevier BV
DOI: 10.1016/j.scitotenv.2016.08.204

Effect of Surface and Salt Properties on the Ion Distribution around Spherical Nanoparticles: Monte Carlo Simulations

Author(s): Arnaud Clavier, Fabrice Carnal, Serge Stoll
Published in: The Journal of Physical Chemistry B, Issue 120/32, 2016, Page(s) 7988-7997, ISSN 1520-6106
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcb.6b05104

Influence of bacterial extracellular polymeric substances on the sorption of Zn on γ-alumina: A combination of FTIR and EXAFS studies

Author(s): Cheng-Cheng Lia, Yu-Jun Wanga, Huan Du, Peng Caid, Willie J.G.M. Peijnenburg, Dong-Mei Zhoua,
Published in: Environmental Pollution, Issue 220, 2017, Page(s) 997-1004, ISSN 0269-7491
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.envpol.2016.11.048

Sewage sludge treated with metal nanomaterials inhibits earthworm reproduction more strongly than sludge treated with metal metals in bulk/salt forms

Author(s): E. Lahive, M. Matzke, M. Durenkamp, A. J. Lawlor, S. A. Thacker, M. G. Pereira, D. J. Spurgeon, J. M. Unrine, C. Svendsen, S. Lofts
Published in: Environ. Sci.: Nano, Issue 4/1, 2017, Page(s) 78-88, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6EN00280C

Novel Multi-isotope Tracer Approach To Test ZnO Nanoparticle and Soluble Zn Bioavailability in Joint Soil Exposures

Author(s): Adam Laycock, Ana Romero-Freire, Jens Najorka, Claus Svendsen, Cornelis A. M. van Gestel, Mark Rehkämper
Published in: Environmental Science & Technology, Issue 51/21, 2017, Page(s) 12756-12763, ISSN 0013-936X
Publisher: American Chemical Society
DOI: 10.1021/acs.est.7b02944

The Biological Fate of Silver Nanoparticles from a Methodological Perspective

Author(s): Damjana Drobne, Sara Novak, Iva Talaber, Iseult Lynch, Anita Kokalj
Published in: Materials, Issue 11/6, 2018, Page(s) 957, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma11060957

Emissions and Possible Environmental Implication of Engineered Nanomaterials (ENMs) in the Atmosphere

Author(s): Astrid John, Miriam Küpper, Astrid Manders-Groot, Bruno Debray, Jean-Marc Lacome, Thomas Kuhlbusch
Published in: Atmosphere, Issue 8/12, 2017, Page(s) 84, ISSN 2073-4433
Publisher: Rotoweb Cantelli
DOI: 10.3390/atmos8050084

Models for assessing engineered nanomaterial fate and behaviour in the aquatic environment

Author(s): Richard J Williams, Samuel Harrison, Virginie Keller, Jeroen Kuenen, Stephen Lofts, Antonia Praetorius, Claus Svendsen, Lucie C Vermeulen, Jikke van Wijnen
Published in: Current Opinion in Environmental Sustainability, Issue 36, 2019, Page(s) 105-115, ISSN 1877-3435
Publisher: Elsevier BV
DOI: 10.1016/j.cosust.2018.11.002

The role of PVP in the bioavailability of Ag from the PVP-stabilized Ag nanoparticle suspension

Author(s): Tea Romih, Anita Jemec, Monika Kos, Samo B. Hočevar, Slavko Kralj, Darko Makovec, Damjana Drobne
Published in: Environmental Pollution, Issue 218, 2016, Page(s) 957-964, ISSN 0269-7491
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.envpol.2016.08.044

Aging reduces the toxicity of pristine but not sulphidised silver nanoparticles to soil bacteria

Author(s): Carolin L. Schultz, Joanna Gray, Rudo A. Verweij, Martí Busquets-Fité, Victor Puntes, Claus Svendsen, Elma Lahive, Marianne Matzke
Published in: Environmental Science: Nano, Issue 5/11, 2018, Page(s) 2618-2630, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en00054a

Dissolution and aggregation kinetics of zero valent copper nanoparticles in (simulated) natural surface waters: Simultaneous effects of pH, NOM and ionic strength

Author(s): Daniel Arenas-Lago, Fazel Abdolahpur Monikh, Martina G. Vijver, Willie J.G.M. Peijnenburg
Published in: Chemosphere, Issue 226, 2019, Page(s) 841-850, ISSN 0045-6535
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.chemosphere.2019.03.190

Tannic acid promotes ion release of copper oxide nanoparticles: Impacts from solution pH change and complexation reactions

Author(s): Jing Zhao, Yang Liu, Bo Pan, Guoqian Gao, Ying Liu, Siqian Liu, Ni Liang, Dandan Zhou, Martina G. Vijver, Willie J.G.M. Peijnenburg
Published in: Water Research, Issue 127, 2017, Page(s) 59-67, ISSN 0043-1354
Publisher: Elsevier BV
DOI: 10.1016/j.watres.2017.10.006

Assessment and prediction of joint algal toxicity of binary mixtures of graphene and ionic liquids

Author(s): Zhuang Wang, Fan Zhang, Se Wang, Willie J.G.M. Peijnenburg
Published in: Chemosphere, Issue 185, 2017, Page(s) 681-689, ISSN 0045-6535
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.chemosphere.2017.07.035

Dissipative particle dynamic simulation and experimental assessment of the impacts of humic substances on aqueous aggregation and dispersion of engineered nanoparticles

Author(s): Zhuang Wang, Joris T.K. Quik, Lan Song, Marja Wouterse, Willie J.G.M. Peijnenburg
Published in: Environmental Toxicology and Chemistry, Issue 37/4, 2018, Page(s) 1024-1031, ISSN 0730-7268
Publisher: Society of Environmental Toxicology and Chemistry
DOI: 10.1002/etc.4059

Multiscale Coupling Strategy for Nano Ecotoxicology Prediction

Author(s): Zhuang Wang, Martina G. Vijver, Willie J.G.M. Peijnenburg
Published in: Environmental Science & Technology, Issue 52/14, 2018, Page(s) 7598-7600, ISSN 0013-936X
Publisher: American Chemical Society
DOI: 10.1021/acs.est.8b02895

Fate modelling of nanoparticle releases in LCA: An integrative approach towards “USEtox4Nano”

Author(s): Beatrice Salieri, Roland Hischier, Joris T.K. Quik, Olivier Jolliet
Published in: Journal of Cleaner Production, Issue 206, 2019, Page(s) 701-712, ISSN 0959-6526
Publisher: Elsevier BV
DOI: 10.1016/j.jclepro.2018.09.187

Impact of water chemistry on the behavior and fate of copper nanoparticles

Author(s): Yinlong Xiao, Martina G. Vijver, Willie J.G.M. Peijnenburg
Published in: Environmental Pollution, Issue 234, 2018, Page(s) 684-691, ISSN 0269-7491
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.envpol.2017.12.015

A critical evaluation of nanopesticides and nanofertilizers against their conventional analogues

Author(s): Melanie Kah, Rai Singh Kookana, Alexander Gogos, Thomas Daniel Bucheli
Published in: Nature Nanotechnology, Issue 13/8, 2018, Page(s) 677-684, ISSN 1748-3387
Publisher: Nature Publishing Group
DOI: 10.1038/s41565-018-0131-1

Influence of organic compounds on the sulfidation of copper oxide nanoparticles

Author(s): Alexander Gogos, Andreas Voegelin, Ralf Kaegi
Published in: Environmental Science: Nano, Issue 5/11, 2018, Page(s) 2560-2569, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en00523k

Sulfidation kinetics of copper oxide nanoparticles

Author(s): Alexander Gogos, Basilius Thalmann, Andreas Voegelin, Ralf Kaegi
Published in: Environmental Science: Nano, Issue 4/8, 2017, Page(s) 1733-1741, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en00309a

Transformation of cerium dioxide nanoparticles during sewage sludge incineration

Author(s): Alexander Gogos, Jonas Wielinski, Andreas Voegelin, Hermann Emerich, Ralf Kaegi
Published in: Environmental Science: Nano, 2019, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9en00281b

Heteroaggregation of nanoplastic particles in the presence of inorganic colloids and natural organic matter

Author(s): Olena Oriekhova, Serge Stoll
Published in: Environmental Science: Nano, Issue 5/3, 2018, Page(s) 792-799, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en01119a

Heteroaggregation of CeO2 nanoparticles in presence of alginate and iron (III) oxide

Author(s): Olena Oriekhova, Serge Stoll
Published in: Science of The Total Environment, Issue 648, 2019, Page(s) 1171-1178, ISSN 0048-9697
Publisher: Elsevier BV
DOI: 10.1016/j.scitotenv.2018.08.176

Protein affinity for TiO2 and CeO2 manufactured nanoparticles. From ultra-pure water to biological media

Author(s): Robin Huber, Serge Stoll
Published in: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Issue 553, 2018, Page(s) 425-431, ISSN 0927-7757
Publisher: Elsevier BV
DOI: 10.1016/j.colsurfa.2018.05.091

Determination of nanoparticle heteroaggregation attachment efficiencies and rates in presence of natural organic matter monomers. Monte Carlo modelling

Author(s): Arnaud Clavier, Antonia Praetorius, Serge Stoll
Published in: Science of The Total Environment, Issue 650, 2019, Page(s) 530-540, ISSN 0048-9697
Publisher: Elsevier BV
DOI: 10.1016/j.scitotenv.2018.09.017

In field conditions, commercial pigment grade TiO 2 was not harmful to terrestrial isopods but reduced leaf litter fragmentation

Author(s): Anita Jemec, Monika Kos, Damjana Drobne, Ismo Kalevi Koponen, Jovan Vukić, Nuno G.C. Ferreira, Susana Loureiro, Heather V.A. McShane
Published in: Science of The Total Environment, Issue 571, 2016, Page(s) 1128-1135, ISSN 0048-9697
Publisher: Elsevier BV
DOI: 10.1016/j.scitotenv.2016.07.107

Bismuth film electrode for anodic stripping voltammetric measurement of silver nanoparticle dissolution

Author(s): Tea Romih, Samo B. Hočevar, Anita Jemec, Damjana Drobne
Published in: Electrochimica Acta, Issue 188, 2016, Page(s) 393-397, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2015.11.110

Considering the forms of released engineered nanomaterials in probabilistic material flow analysis

Author(s): Véronique Adam, Alejandro Caballero-Guzman, Bernd Nowack
Published in: Environmental Pollution, Issue 243, 2018, Page(s) 17-27, ISSN 0269-7491
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.envpol.2018.07.108

European country-specific probabilistic assessment of nanomaterial flows towards landfilling, incineration and recycling

Author(s): Véronique Adam, Bernd Nowack
Published in: Environmental Science: Nano, Issue 4/10, 2017, Page(s) 1961-1973, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en00487g

The application of bismuth film electrode for measuring Zn(II) under less acidic conditions in the presence of cell culture medium and ZnO nanoparticles

Author(s): Tea Romih, Samo B. Hočevar, Veno Kononenko, Damjana Drobne
Published in: Sensors and Actuators B: Chemical, Issue 238, 2017, Page(s) 1277-1282, ISSN 0925-4005
Publisher: Elsevier BV
DOI: 10.1016/j.snb.2016.09.090

Changing environments and biomolecule coronas: consequences and challenges for the design of environmentally acceptable engineered nanoparticles

Author(s): Marta Markiewicz, Jolanta Kumirska, Iseult Lynch, Marianne Matzke, Jan Köser, Steve Bemowsky, Dominic Docter, Roland Stauber, Dana Westmeier, Stefan Stolte
Published in: Green Chemistry, Issue 20/18, 2018, Page(s) 4133-4168, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8gc01171k

Sludge concentration, shear rate and nanoparticle size determine silver nanoparticle removal during wastewater treatment

Author(s): G. Cornelis, A. M. Forsberg-Grivogiannis, N. P. Sköld, S. Rauch, J. Perez-Holmberg
Published in: Environmental Science: Nano, Issue 4/11, 2017, Page(s) 2225-2234, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en00734e

Strategies for robust and accurate experimental approaches to quantify nanomaterial bioaccumulation across a broad range of organisms

Author(s): Elijah J. Petersen, Monika Mortimer, Robert M. Burgess, Richard Handy, Shannon Hanna, Kay T. Ho, Monique Johnson, Susana Loureiro, Henriette Selck, Janeck J. Scott-Fordsmand, David Spurgeon, Jason Unrine, Nico W. van den Brink, Ying Wang, Jason White, Patricia Holden
Published in: Environmental Science: Nano, Issue 6/6, 2019, Page(s) 1619-1656, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en01378k

An assessment of the dietary bioavailability of silver nanomaterials in rainbow trout using an ex vivo gut sac technique

Author(s): Nathaniel J. Clark, David Boyle, Richard D. Handy
Published in: Environmental Science: Nano, Issue 6/2, 2019, Page(s) 646-660, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en00981c

Proposal for a tiered dietary bioaccumulation testing strategy for engineered nanomaterials using fish

Author(s): Richard D. Handy, Jukka Ahtiainen, José María Navas, Greg Goss, Eric A. J. Bleeker, Frank von der Kammer
Published in: Environmental Science: Nano, Issue 5/9, 2018, Page(s) 2030-2046, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en01139c

The in vivo effects of silver nanoparticles on terrestrial isopods, Porcellio scaber , depend on a dynamic interplay between shape, size and nanoparticle dissolution properties

Author(s): Sara Novak, Tea Romih, Barbara Drašler, Giovanni Birarda, Lisa Vaccari, Paolo Ferraris, Stephanie Sorieul, Maciej Zieba, Victor Sebastian, Manuel Arruebo, Samo B. Hočevar, Anita Jemec Kokalj, Damjana Drobne
Published in: The Analyst, Issue 144/2, 2019, Page(s) 488-497, ISSN 0003-2654
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8an01387j

Ageing, dissolution and biogenic formation of nanoparticles: how do these factors affect the uptake kinetics of silver nanoparticles in earthworms?

Author(s): M. Baccaro, A. K. Undas, J. de Vriendt, J. H. J. van den Berg, R. J. B. Peters, N. W. van den Brink
Published in: Environmental Science: Nano, Issue 5/5, 2018, Page(s) 1107-1116, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7en01212h

A novel approach to the measurement of surfactant parameters in arthropod digestive juices

Author(s): Tea Romih, Ksenija Kogej, Damjana Drobne
Published in: Journal of Insect Physiology, Issue 88, 2016, Page(s) 48-54, ISSN 0022-1910
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.jinsphys.2016.03.003

On the application of spectral corrections to particle flux measurements

Author(s): Aleid Oosterwijk, Bas Henzing, Leena Järvi
Published in: Environmental Science: Nano, Issue 5/10, 2018, Page(s) 2315-2324, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en00501j

Nanomaterials in the environment: Behavior, fate, bioavailability, and effects-An updated review

Author(s): Jamie R. Lead, Graeme E. Batley, Pedro J. J. Alvarez, Marie-Noële Croteau, Richard D. Handy, Michael J. McLaughlin, Jonathan D. Judy, Kristin Schirmer
Published in: Environmental Toxicology and Chemistry, Issue 37/8, 2018, Page(s) 2029-2063, ISSN 0730-7268
Publisher: Society of Environmental Toxicology and Chemistry
DOI: 10.1002/etc.4147

Tools and rules for modelling uptake and bioaccumulation of nanomaterials in invertebrate organisms

Author(s): Nico W. van den Brink, Anita Jemec Kokalj, Patricia V. Silva, Elma Lahive, Karin Norrfors, Marta Baccaro, Zahra Khodaparast, Susana Loureiro, Damjana Drobne, Geert Cornelis, Steve Lofts, Richard D. Handy, Claus Svendsen, Dave Spurgeon, Cornelis A. M. van Gestel
Published in: Environmental Science: Nano, 2019, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8en01122b

Bioturbation of Ag2S-NPs in soil columns by earthworms

Author(s): Marta Baccaro, Samuel Harrison, Hans van den Berg, Laura Sloot, Davy Hermans, Geert Cornelis, Cornelis A.M. van Gestel, Nico W. van den Brink
Published in: Environmental Pollution, Issue 252, 2019, Page(s) 155-162, ISSN 0269-7491
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.envpol.2019.05.106

Dietary exposure to silver nitrate compared to two forms of silver nanoparticles in rainbow trout: bioaccumulation potential with minimal physiological effects

Author(s): Nathaniel J. Clark, David Boyle, Benjamin P. Eynon, Richard D. Handy
Published in: Environmental Science: Nano, Issue 6/5, 2019, Page(s) 1393-1405, ISSN 2051-8153
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9en00261h

Core–Shell NaHoF 4 @TiO 2 NPs: A Labeling Method to Trace Engineered Nanomaterials of Ubiquitous Elements in the Environment

Author(s): Xianjin Cui, Benjamin Fryer, Diwei Zhou, Rhys W. Lodge, Andrei N. Khlobystov, Eugenia Valsami-Jones, Iseult Lynch
Published in: ACS Applied Materials & Interfaces, Issue 11/21, 2019, Page(s) 19452-19461, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.9b03062

"Nanoparticles as soil pollutants; Book Chapter in ""Soil Pollution: From Monitoring to Remediation"""

Author(s): Loureiro S, Tourinho P, Cornelis G, Van Den Brink NW, Díez-Ortiz M, Vázquez-Campos S, Pomar-Portillo V, Svendsen C, Van Gestel C
Published in: 2017, Page(s) 161-190, ISBN 9780-128498736
Publisher: Elsevier

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