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Tailoring Ylidic Compounds as Ligands for Organometallic Chemistry

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Publications

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogenous Catalysis

Author(s): Thorsten Scherpf, Christopher Schwarz, Lennart T. Scharf, Jana-Alina Zur, Andreas Helbig, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
DOI: 10.1002/anie.201805372

Isolation of the Metalated Ylides [Ph 3 P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation

Author(s): Christopher Schwarz, Lennart T. Scharf, Thorsten Scherpf, Julia Weismann, Viktoria H. Gessner
Published in: Chemistry - A European Journal, Issue 25/11, 2019, Page(s) 2793-2802, ISSN 0947-6539
DOI: 10.1002/chem.201805421

Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

Author(s): Christopher Schwarz, Thorsten Scherpf, Ilja Rodstein, Julia Weismann, Kai‐Stephan Feichtner, Viktoria H. Gessner
Published in: ChemistryOpen, Issue 8/5, 2019, Page(s) 621-626, ISSN 2191-1363
DOI: 10.1002/open.201900094

Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment

Author(s): Chandrajeet Mohapatra, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Kai-Stephan Feichtner, Christopher Schwarz, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, Issue 58/22, 2019, Page(s) 7459-7463, ISSN 1433-7851
DOI: 10.1002/anie.201902831

Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition

Author(s): Thorsten Scherpf, Ilja Rodstein, Maurice Paaßen, Viktoria H. Gessner
Published in: Inorganic Chemistry, Issue 58/12, 2019, Page(s) 8151-8161, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.9b00948

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties

Author(s): Lennart T. Scharf, Viktoria H. Gessner
Published in: Inorganic Chemistry, Issue 56/15, 2017, Page(s) 8599-8607, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.7b00099

The Bonding Situation in Metalated Ylides

Author(s): Lennart T. Scharf, Diego M. Andrada, Gernot Frenking, Viktoria H. Gessner
Published in: Chemistry - A European Journal, Issue 23/18, 2017, Page(s) 4422-4434, ISSN 0947-6539
DOI: 10.1002/chem.201605997

Using Ylide Functionalization to Stabilize Boron Cations

Author(s): Thorsten Scherpf, Kai-Stephan Feichtner, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, Issue 56/12, 2017, Page(s) 3275-3279, ISSN 1433-7851
DOI: 10.1002/anie.201611677