Stereocontrolled Polymerisation: New Frontiers in Synthesis and Supramolecular Self Assembly

Project Information

STEREOPOL

Grant agreement ID: 681559

DOI 10.3030/681559

Project closed

EC signature date 29 April 2016

Start date 1 September 2016

End date 30 April 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 074 731,00

EU contribution € 2 074 731,00

Coordinated by

THE UNIVERSITY OF BIRMINGHAM
United Kingdom

Publications

Peer reviewed articles (29)

Ultra‐Tough Elastomers from Stereochemistry‐Directed Hydrogen Bonding in Isosorbide‐Based Polymers

Author(s): Shannon R. Petersen; Hannah Prydderch; Joshua C. Worch; Connor J. Stubbs; Zilu Wang; Jiayi Yu; Maria C. Arno; Andrey V. Dobrynin; Matthew L. Becker; Andrew P. Dove
Published in: Angewandte Chemie International Edition, Issue 3, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202115904

Sugar-Based Polymers with Stereochemistry-Dependent Degradability and Mechanical Properties

Author(s): Connor J. Stubbs; Joshua C. Worch; Hannah Prydderch; Zilu Wang; Robert T. Mathers; Andrey V. Dobrynin; Matthew L. Becker; Andrew P. Dove
Published in: Journal of the American Chemical Society, Issue 1, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c10278

Concomitant control of mechanical properties and degradation in resorbable elastomer-like materials using stereochemistry and stoichiometry for soft tissue engineering

Author(s): Mary Beth Wandel, Craig A. Bell, Jiayi Yu, Maria C. Arno, Nathan Z. Dreger, Yen-Hao Hsu, Anaïs Pitto-Barry, Joshua C. Worch, Andrew P. Dove, Matthew L. Becker
Published in: Nature Communications, Issue 12/1, 2021, Page(s) 446, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-20610-5

Using Stereochemistry to Control Mechanical Properties in Thiol-Yne Click-Hydrogels.

Author(s): Laura J. Macdougall; Maria M. Pérez-Madrigal; Joshua E Shaw; Joshua C. Worch; Chris Sammon; Stephen M. Richardson; Andrew P. Dove
Published in: 1521-3757, Issue 1, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202107161

Click Nucleophilic Conjugate Additions to Activated Alkynes: Exploring Thiol-yne, Amino-yne, and Hydroxyl-yne Reactions from (Bio)Organic to Polymer Chemistry.

Author(s): Joshua C. Worch; Connor J. Stubbs; Matthew J. Price; Andrew P. Dove
Published in: Chemical Reviews, Issue 1, 2021, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.0c01076

Intrinsically Re-curable Photopolymers Containing Dynamic Thiol-Michael Bonds

Author(s): Connor J. Stubbs; Anissa L. Khalfa; Viviane Chiaradia; Joshua C. Worch; Andrew P. Dove
Published in: Crossref, Issue 3, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c03525

Selective Reactivity of Myrcene for Vat Photopolymerization 3D Printing and Postfabrication Surface Modification

Author(s): Andrew C. Weems, Kayla R. Delle Chiaie, Rachel Yee, Andrew P. Dove
Published in: Biomacromolecules, Issue 21/1, 2020, Page(s) 163-170, ISSN 1525-7797
Publisher: American Chemical Society
DOI: 10.1021/acs.biomac.9b01125

Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets.

Author(s): Anissa L Khalfa; Matthew L. Becker; Andrew P. Dove
Published in: Journal of the American Chemical Society, Issue 3, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c06960

Stereoselective ROP of rac- and meso-Lactides Using Achiral TBD as Catalyst

Author(s): Sébastien Moins, Sébastien Hoyas, Vincent Lemaur, Beste Orhan, Kayla Delle Chiaie, Roberto Lazzaroni, Daniel Taton, Andrew P. Dove, Olivier Coulembier
Published in: Catalysts, Issue 10/6, 2020, Page(s) 620, ISSN 2073-4344
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal10060620

Elastomeric polyamide biomaterials with stereochemically tuneable mechanical properties and shape memory

Author(s): Joshua C. Worch, Andrew C. Weems, Jiayi Yu, Maria C. Arno, Thomas R. Wilks, Robert T. R. Huckstepp, Rachel K. O’Reilly, Matthew L. Becker, Andrew P. Dove
Published in: Nature Communications, Issue 11/1, 2020, Page(s) 3250, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-16945-8

Understanding the CDSA of poly(lactide) containing triblock copolymers

Author(s): Wei Yu, Maria Inam, Joseph R. Jones, Andrew P. Dove, Rachel K. O'Reilly
Published in: Polymer Chemistry, Issue 8/36, 2017, Page(s) 5504-5512, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7PY01056G

Unlocking the Potential of Poly( Ortho Ester)s: A General Catalytic Approach to the Synthesis of Surface-Erodible Materials

Author(s): Mathieu J.-L. Tschan, Nga Sze Ieong, Richard Todd, Jack Everson, Andrew P. Dove
Published in: Angewandte Chemie International Edition, Issue 56/52, 2017, Page(s) 16664-16668, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201709934

Precision Epitaxy for Aqueous 1D and 2D Poly(ε-caprolactone) Assemblies

Author(s): Maria C. Arno, Maria Inam, Zachary Coe, Graeme Cambridge, Laura J. Macdougall, Robert Keogh, Andrew P. Dove, Rachel K. O’Reilly
Published in: Journal of the American Chemical Society, Issue 139/46, 2017, Page(s) 16980-16985, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.7b10199

Poly(oligo(ethylene glycol) vinyl acetate)s: A Versatile Class of Thermoresponsive and Biocompatible Polymers

Author(s): Guillaume G. Hedir, Maria C. Arno, Marvin Langlais, Jonathan T. Husband, Rachel K. O'Reilly, Andrew P. Dove
Published in: Angewandte Chemie International Edition, Issue 56/31, 2017, Page(s) 9178-9182, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201703763

1D vs. 2D shape selectivity in the crystallization-driven self-assembly of polylactide block copolymers

Author(s): Maria Inam, Graeme Cambridge, Anaïs Pitto-Barry, Zachary P. L. Laker, Neil R. Wilson, Robert T. Mathers, Andrew P. Dove, Rachel K. O'Reilly
Published in: Chemical Science, Issue 8/6, 2017, Page(s) 4223-4230, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7SC00641A

pH-Responsive, Functionalizable Spyrocyclic Polycarbonate: A Versatile Platform for Biocompatible Nanoparticles

Author(s): Maria C. Arno, Ruairí P. Brannigan, Gina M. Policastro, Matthew L. Becker, Andrew P. Dove
Published in: Biomacromolecules, Issue 19/8, 2018, Page(s) 3427-3434, ISSN 1525-7797
Publisher: American Chemical Society
DOI: 10.1021/acs.biomac.8b00744

Uniform Biodegradable Fiber-Like Micelles and Block Comicelles via “Living” Crystallization-Driven Self-Assembly of Poly( l -lactide) Block Copolymers: The Importance of Reducing Unimer Self-Nucleation via Hydrogen Bond Disruption

Author(s): Yunxiang He, Jean-Charles Eloi, Robert L. Harniman, Robert M. Richardson, George R. Whittell, Robert T. Mathers, Andrew P. Dove, Rachel K. O’Reilly, Ian Manners
Published in: Journal of the American Chemical Society, Issue 141/48, 2019, Page(s) 19088-19098, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b09885

Controlling the Size of Two-Dimensional Polymer Platelets for Water-in-Water Emulsifiers

Author(s): Maria Inam, Joseph R. Jones, Maria M. Pérez-Madrigal, Maria C. Arno, Andrew P. Dove, Rachel K. O’Reilly
Published in: ACS Central Science, Issue 4/1, 2017, Page(s) 63-70, ISSN 2374-7943
Publisher: American Chemical Society
DOI: 10.1021/acscentsci.7b00436

Isoselective Ring-Opening Polymerization of rac -Lactide from Chiral Takemoto’s Organocatalysts: Elucidation of Stereocontrol

Author(s): Beste Orhan, Mathieu J.-L. Tschan, Anne-Laure Wirotius, Andrew P. Dove, Olivier Coulembier, Daniel Taton
Published in: ACS Macro Letters, Issue 7/12, 2018, Page(s) 1413-1419, ISSN 2161-1653
Publisher: American Chemical Society
DOI: 10.1021/acsmacrolett.8b00852

Unsaturated Poly(ester-urethanes) with Stereochemically Dependent Thermomechanical Properties

Author(s): Connor J. Stubbs, Joshua C. Worch, Hannah Prydderch, Matthew L. Becker, Andrew P. Dove
Published in: Macromolecules, Issue 53/1, 2019, Page(s) 174-181, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.9b01700

Exploiting the role of nanoparticle shape in enhancing hydrogel adhesive and mechanical properties

Author(s): Maria C. Arno, Maria Inam, Andrew C. Weems, Zehua Li, Abbie L. A. Binch, Christopher I. Platt, Stephen M. Richardson, Judith A. Hoyland, Andrew P. Dove, Rachel K. O’Reilly
Published in: Nature Communications, Issue 11/1, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-15206-y

Stereochemical enhancement of polymer properties

Author(s): Joshua C. Worch, Hannah Prydderch, Sètuhn Jimaja, Panagiotis Bexis, Matthew L. Becker, Andrew P. Dove
Published in: Nature Reviews Chemistry, Issue 3/9, 2019, Page(s) 514-535, ISSN 2397-3358
Publisher: Springer-Nature
DOI: 10.1038/s41570-019-0117-z

Self-healing, stretchable and robust interpenetrating network hydrogels

Author(s): Laura J. Macdougall, Maria M. Pérez-Madrigal, Joshua E. Shaw, Maria Inam, Judith A. Hoyland, Rachel O'Reilly, Stephen M. Richardson, Andrew P. Dove
Published in: Biomaterials Science, Issue 6/11, 2018, Page(s) 2932-2937, ISSN 2047-4830
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8bm00872h

Nonswelling Thiol–Yne Cross-Linked Hydrogel Materials as Cytocompatible Soft Tissue Scaffolds

Author(s): Laura J. Macdougall, Maria M. Pérez-Madrigal, Maria C. Arno, Andrew P. Dove
Published in: Biomacromolecules, Issue 19/5, 2017, Page(s) 1378-1388, ISSN 1525-7797
Publisher: American Chemical Society
DOI: 10.1021/acs.biomac.7b01204

Design of synthetic extracellular matrices for probing breast cancer cell growth using robust cyctocompatible nucleophilic thiol-yne addition chemistry

Author(s): Laura J. Macdougall, Katherine L. Wiley, April M. Kloxin, Andrew P. Dove
Published in: Biomaterials, Issue 178, 2018, Page(s) 435-447, ISSN 0142-9612
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.biomaterials.2018.04.046

Synthesis of Degradable Poly(vinyl alcohol) by Radical Ring-Opening Copolymerization and Ice Recrystallization Inhibition Activity

Author(s): Guillaume Hedir, Christopher Stubbs, Phillip Aston, Andrew P. Dove, Matthew I. Gibson
Published in: ACS Macro Letters, Issue 6/12, 2017, Page(s) 1404-1408, ISSN 2161-1653
Publisher: American Chemical Society
DOI: 10.1021/acsmacrolett.7b00905

Renewable and recyclable covalent adaptable networks based on bio-derived lipoic acid

Author(s): Maher A. Alraddadi; Viviane Chiaradia; Connor J. Stubbs; Joshua C. Worch; Andrew P. Dove
Published in: Polymer Chemistry, Issue 2, 2021, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1py00754h

Harnessing the Chemical Diversity of the Natural Product Magnolol for the Synthesis of Renewable, Degradable Neolignan Thermosets with Tunable Thermomechanical Characteristics and Antioxidant Activity

Author(s): Kevin T. Wacker, Andrew C. Weems, Soon-Mi Lim, Sarosh Khan, Simcha E. Felder, Andrew P. Dove, Karen L. Wooley
Published in: Biomacromolecules, Issue 20/1, 2018, Page(s) 109-117, ISSN 1525-7797
Publisher: American Chemical Society
DOI: 10.1021/acs.biomac.8b00771

Understanding structure–property relationships of main chain cyclopropane in linear polyesters

Author(s): Connor J. Stubbs, Andrew P. Dove
Published in: Polymer Chemistry, Issue 11/39, 2020, Page(s) 6251-6258, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0py01004a