Organic Functionalisation of N2 Using Metal-Main Group and Metal-Metal Cooperativity

Project Information

OrFuNCo

Grant agreement ID: 757501

DOI 10.3030/757501

Project closed

EC signature date 15 September 2017

Start date 1 March 2018

End date 31 August 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 499 640,00

EU contribution € 1 499 640,00

Coordinated by

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

Publications

Peer reviewed articles (12)

Protonation Behavior of a Tetrahydrido Molybdenum(IV) Complex with Organic and Inorganic Acids

Author(s): Nicolas Queyriaux, Nina Durvin, Daniel Leon, Marie-Christine Boegli, Laure Vendier, Antoine Simonneau
Published in: European Journal of Inorganic Chemistry, 2023, ISSN 1099-0682
Publisher: Wiley
DOI: 10.1002/ejic.202300426

Assessing Combinations of B(C6F5)3 and N2-Derived Molybdenum Nitrido Complexes for Heterolytic Bond Activation

Author(s): Anaïs Coffinet, David Specklin, Quentin Le Dé, Soukaina Bennaamane, Luna Muñoz, Laure Vendier, Eric Clot, Nicolas Mézailles, Antoine Simonneau
Published in: Chemistry – A European Journal, 2023, ISSN 1521-3765
Publisher: Wiley
DOI: 10.1002/chem.202203774

Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes.

Author(s): David Specklin; Anaïs Coffinet; Laure Vendier; Iker del Rosal; Chiara Dinoi; Antoine Simonneau
Published in: Inorganic Chemistry, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c03271

Transition metal-mediated dinitrogen functionalisation with boron

Author(s): Antoine Simonneau
Published in: New Journal of Chemistry, 2021, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1nj01290h

An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)]

Author(s): Quentin Le Dé, Amal Bouammali, Christian Bijani, Laure Vendier, Iker del Rosal, Dmitry A. Valyaev, Chiara Dinoi, Antoine Simonneau
Published in: Angewandte Chemie International Edition, 2023, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202305235

Syntheses of N2-bridged heterobimetallic complexes, their structural and qualitative bonding analyses

Author(s): Quentin Le Dé, Fourat Orbay, Antoine Simonneau
Published in: Journal of Organometallic Chemistry, 2023, ISSN 0022-328X
Publisher: Elsevier BV
DOI: 10.1016/j.jorganchem.2022.122604

Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition

Author(s): Anaïs Coffinet; Dan Zhang; Laure Vendier; Sébastien Bontemps; Antoine Simonneau
Published in: "Dalton Transactions, , 2021, 50 (16), pp.5582-5589. ⟨10.1039/D1DT00317H⟩", 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt00317h

Dinitrogen-derived (diarylboryl)diazenido Complexes with Differing Coordination to the Thallium Cation

Author(s): Amal Bouammali; Anaïs Coffinet; Laure Vendier; Antoine Simonneau
Published in: Dalton Transactions, 2022, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt03905a

Enhanced Activation of Coordinated Dinitrogen with p-Block Lewis Acids

Author(s): Antoine Simonneau, Michel Etienne
Published in: Chemistry - A European Journal, Issue 24/48, 2018, Page(s) 12458-12463, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201800405

Frustrated Lewis Pair Chemistry Enables N 2 Borylation by Formal 1,3‐Addition of a B−H Bond in the Coordination Sphere of Tungsten

Author(s): Anaïs Coffinet, David Specklin, Laure Vendier, Michel Etienne, Antoine Simonneau
Published in: Chemistry – A European Journal, 2019, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201904084

Reaction of Methyllithium with Group 6 Phosphine Dinitrogen Complexes

Author(s): Amal Bouammali, Christian Bijani, Laure Vendier, Michel Etienne, Antoine Simonneau
Published in: European Journal of Inorganic Chemistry, Issue 2020/15-16, 2020, Page(s) 1423-1427, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201901346

An orbitally adapted push-pull template for N2 activation and reduction to diazene-diide

Author(s): David Specklin, Marie-Christine Boegli, Anaïs Coffinet, Léon Escomel, Laure Vendier, Mary Grellier, Antoine Simonneau
Published in: Chemical Science, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc04390h

Book chapters (1)

Push–Pull Activation of N2: Coordination of Lewis Acids to Dinitrogen Complexes

Author(s): Anaïs Coffinet, Antoine Simonneau, David Specklin
Published in: Encyclopedia of Inorganic and Bioinorganic Chemistry, 2020
Publisher: Wiley