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Organic Functionalisation of N2 Using Metal-Main Group and Metal-Metal Cooperativity

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Publications

Peer reviewed articles (17)
Protonation Behavior of a Tetrahydrido Molybdenum(IV) Complex with Organic and Inorganic Acids (opens in new window)

Author(s): Nicolas Queyriaux, Nina Durvin, Daniel Leon, Marie-Christine Boegli, Laure Vendier, Antoine Simonneau
Published in: European Journal of Inorganic Chemistry, 2023, ISSN 1099-0682
Publisher: Wiley
DOI: 10.1002/ejic.202300426

Assessing Combinations of B(C6F5)3 and N2-Derived Molybdenum Nitrido Complexes for Heterolytic Bond Activation (opens in new window)

Author(s): Anaïs Coffinet, David Specklin, Quentin Le Dé, Soukaina Bennaamane, Luna Muñoz, Laure Vendier, Eric Clot, Nicolas Mézailles, Antoine Simonneau
Published in: Chemistry – A European Journal, 2023, ISSN 1521-3765
Publisher: Wiley
DOI: 10.1002/chem.202203774

Nitrogen Fixation by Manganese Complexes – Waiting for the Rush? (opens in new window)

Author(s): Quentin Le Dé, Dmitry A. Valyaev, Antoine Simonneau
Published in: Chemistry – A European Journal, Issue 30, 2024, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202400784

Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes. (opens in new window)

Author(s): David Specklin; Anaïs Coffinet; Laure Vendier; Iker del Rosal; Chiara Dinoi; Antoine Simonneau
Published in: Inorganic Chemistry, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c03271

Transition metal-mediated dinitrogen functionalisation with boron (opens in new window)

Author(s): Antoine Simonneau
Published in: New Journal of Chemistry, 2021, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1nj01290h

An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)] (opens in new window)

Author(s): Quentin Le Dé, Amal Bouammali, Christian Bijani, Laure Vendier, Iker del Rosal, Dmitry A. Valyaev, Chiara Dinoi, Antoine Simonneau
Published in: Angewandte Chemie International Edition, 2023, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202305235

Syntheses of N2-bridged heterobimetallic complexes, their structural and qualitative bonding analyses (opens in new window)

Author(s): Quentin Le Dé, Fourat Orbay, Antoine Simonneau
Published in: Journal of Organometallic Chemistry, 2023, ISSN 0022-328X
Publisher: Elsevier BV
DOI: 10.1016/j.jorganchem.2022.122604

Reactivity of metal hydrides with CO<sub>2</sub>: going beyond formate with a high-valent cationic pentahydride Mo(<scp>vi</scp>) complex (opens in new window)

Author(s): Nicolas Queyriaux, Jorge J. Cabrera-Trujillo, Nina Durvin, Laure Vendier, Karinne Miqueu, Antoine Simonneau
Published in: Chemical Science, Issue 15, 2024, Page(s) 20582-20589, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc04345f

Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition (opens in new window)

Author(s): Anaïs Coffinet; Dan Zhang; Laure Vendier; Sébastien Bontemps; Antoine Simonneau
Published in: "Dalton Transactions, , 2021, 50 (16), pp.5582-5589. &#x27E8;10.1039/D1DT00317H&#x27E9;", 2021, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt00317h

Dinitrogen-derived (diarylboryl)diazenido Complexes with Differing Coordination to the Thallium Cation (opens in new window)

Author(s): Amal Bouammali; Anaïs Coffinet; Laure Vendier; Antoine Simonneau
Published in: Dalton Transactions, 2022, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt03905a

Enhanced Activation of Coordinated Dinitrogen with p-Block Lewis Acids (opens in new window)

Author(s): Antoine Simonneau, Michel Etienne
Published in: Chemistry - A European Journal, Issue 24/48, 2018, Page(s) 12458-12463, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201800405

Frustrated Lewis Pair Chemistry Enables N 2 Borylation by Formal 1,3‐Addition of a B−H Bond in the Coordination Sphere of Tungsten (opens in new window)

Author(s): Anaïs Coffinet, David Specklin, Laure Vendier, Michel Etienne, Antoine Simonneau
Published in: Chemistry – A European Journal, 2019, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201904084

Reaction of Methyllithium with Group 6 Phosphine Dinitrogen Complexes (opens in new window)

Author(s): Amal Bouammali, Christian Bijani, Laure Vendier, Michel Etienne, Antoine Simonneau
Published in: European Journal of Inorganic Chemistry, Issue 2020/15-16, 2020, Page(s) 1423-1427, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201901346

Seven‐Coordinate Group 6 Metal Hydrides Obtained by H<sub>2</sub> Activation at B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> Adducts of N<sub>2</sub> Complexes: Frustrated Lewis Pair‐Type Reactivity of The B−N Linkage (opens in new window)

Author(s): Marie‐Christine Boegli, Anaïs Coffinet, Christian Bijani, Antoine Simonneau
Published in: Chemistry – An Asian Journal, Issue 19, 2024, ISSN 1861-4728
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/asia.202400451

An orbitally adapted push-pull template for N2 activation and reduction to diazene-diide (opens in new window)

Author(s): David Specklin, Marie-Christine Boegli, Anaïs Coffinet, Léon Escomel, Laure Vendier, Mary Grellier, Antoine Simonneau
Published in: Chemical Science, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc04390h

Low-valent group 6 metals/Al(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> donor–acceptor systems for CO<sub>2</sub> activation and cleavage (opens in new window)

Author(s): Léon Escomel, Quentin Le Dé, Maxime Benonie, Laure Vendier, Antoine Simonneau
Published in: Chemical Communications, Issue 60, 2024, Page(s) 13235-13238, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc02349h

Coordination of Al(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub><i>vs.</i> B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> on group 6 end-on dinitrogen complexes: chemical and structural divergences (opens in new window)

Author(s): Léon Escomel, Frederico F. Martins, Laure Vendier, Anaïs Coffinet, Nicolas Queyriaux, Vera Krewald, Antoine Simonneau
Published in: Chemical Science, Issue 15, 2024, Page(s) 11321-11336, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc02713b

Book chapters (1)
Push–Pull Activation of N2: Coordination of Lewis Acids to Dinitrogen Complexes

Author(s): Anaïs Coffinet, Antoine Simonneau, David Specklin
Published in: Encyclopedia of Inorganic and Bioinorganic Chemistry, 2020
Publisher: Wiley

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Last update: 1 September 2025

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