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Plas2Cat: Synergism of Plasmonics and other Catalytic processes for Reforming Plastics

Project description

Turning plastic waste into valuable resources

Plastic harms ecosystems and drives 5 % of greenhouse gas emissions. By 2050, it could release 2.6 gigatonnes of CO2 annually. Yet, only 10 % is recycled, mostly into less useful forms. With the support of the Marie Skłodowska-Curie Actions programme, the Plas2Cat project is developing advanced plasmonic nanoparticles to break down hard-to-recycle plastics such as polystyrene into valuable chemicals. Using light from the visible to the infrared, these nanoparticles – made from metals like gold, palladium and earth-abundant alternatives – will drive catalytic reactions. Plas2Cat paves the way for sustainable upcycling, transforming waste into reusable resources and breathing new life into the circular economy.

Objective

Plastic waste, once valued for its durability, now presents severe environmental and economic challenges due to its persistence and complex disposal. Contributing 5% to global greenhouse gas emissions with projections of 2.6 Gt of CO2 annually by 2050, urgent solutions are needed. Currently, only 10% of plastics are repurposed into lower-value products, highlighting the necessity for innovative cradle-to-cradle approaches. The Plas2Cat project, which will be hosted by Prof. Erwin Reisner’s lab and the NanoPhotonics Centre (NPC) at the University of Cambridge, aims to address these challenges. The Reisner lab’s expertise in solar reforming and NPC’s advanced plasmonic cavities will underpin the development of core-shell plasmonic nanoparticles (NPs) with tailored properties. By utilising gold, palladium, and exploring copper, nickel, and metal oxides, the project seeks to enhance catalytic performance and sustainability. Plasmonic nanomaterials will enable the harnessing of lower-energy visible to infrared light, broadening the usable light spectrum for catalytic transformations. The project will employ these NPs to drive catalytic transformations of plastic waste. Using photoelectrochemical and spectroscopic techniques, the study will investigate interactions between NPs and plastic molecules, track intermediates and products, and elucidate plasmonic redox properties. Aiming to tackle the challenging recycling of polystyrene (PS), the project will focus on breaking C–H and C–C bonds in PS to produce valuable feedstocks like benzoic acid and styrene. Initial efforts will target smaller compounds and shorter PS chains, with plans to eventually use longer chains and real PS waste. The project will emphasize sustainability by developing plasmonic nanomaterials from earth-abundant metals and oxides like magnesium and manganese oxide. By integrating plasmonics with catalytic processes, Plas2Cat seeks to revolutionize plastic upcycling and advance the circular economy.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2024-PF-01

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Coordinator

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
Net EU contribution
€ 260 347,92
Address
TRINITY LANE THE OLD SCHOOLS
CB2 1TN CAMBRIDGE
United Kingdom
Region
East of England East Anglia Cambridgeshire CC
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data