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Advancing Exciton Dynamics in In-situ/Operando Spectroscopic Study of Lanthanide-based OLEDs

Project description

Uncovering loss efficiency mechanisms of organic light-emitting diodes

Lanthanide-based organic light-emitting diodes (Ln-OLEDs) hold great potential for energy-efficient lighting and display technologies owing to their unique optical properties such as high photoluminescence and colour tunability and narrow linewidths. However, despite their high photoluminescence quantum yields, their practical efficiency is limited as the external quantum efficiency reaches only about 10 %. With the support of the Marie Skłodowska-Curie Actions programme, the EXD-LnOLED project will study exciton dynamics and energy transfer in operating Ln-OLEDs using advanced spectroscopic techniques such as ultrafast transient absorption and time-resolved electroluminescence. The proposed research should help uncover the mechanisms behind efficiency losses and improve charge balance to achieve state-of-the-art Ln-OLEDs with near 100 % exciton energy utilisation.

Objective

"This research project, ""EXD-LnOLED,"" aims to enhance the efficiency and functionality of lanthanide-based organic light-emitting diodes (Ln-OLEDs). OLEDs are efficient electroluminescent (EL) light sources for panel displays, light communication, and laser diode applications. To maximize efficiency, it is crucial to fully utilize excitons, which consist of 25% singlet and 75% triplet exciton states. Lanthanide complexes are ideal for OLEDs due to their unique optical properties, such as high photoluminescence quantum yield (PLQY), color tunability, and narrow linewidths. This triplet sensitization allows for potentially 100% utilization of exciton energy, leading to cost-effective EL devices. However, despite their high PLQY of around 80%, the external quantum efficiency (EQE) in operational OLEDs is limited to about 10%, restricting practical applications. The primary objective of this project is to develop in-situ/operando spectroscopic techniques to study exciton dynamics and energy transfer within operating Ln-OLEDs. By using advanced methods such as ultrafast transient absorption spectroscopy and time-resolved electroluminescence under in-situ/operando conditions, the research will uncover the mechanisms limiting current Ln-OLED efficiency. Additionally, the project will create innovative methods for detecting changes from electron injection, enhancing understanding of charge balance and dynamics in Ln-OLEDs. Ultimately, the project seeks to address efficiency challenges and achieve state-of-the-art Ln-OLEDs with the highest EQE. These insights will inform the design of high-efficiency devices, aiming for 100% exciton energy utilization, thus advancing energy-saving technologies and next-generation lighting solutions."

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2024-PF-01

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Coordinator

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
Net EU contribution
€ 276 187,92
Address
TRINITY LANE THE OLD SCHOOLS
CB2 1TN CAMBRIDGE
United Kingdom
Region
East of England East Anglia Cambridgeshire CC
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data