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A membraneless electrolyzer for electrochemical hydrogenation of nitrobenzene to aniline with water as the proton source

Project description

Membrane-free electrohydrogenation electrolyser supports greener hydrogenation

Hydrogenation – adding hydrogen to unsaturated organic compounds – traditionally relies on fossil fuel-derived hydrogen. It is used in over 70 % of fine chemical production processes. Renewable-powered electrochemical hydrogenation (electrohydrogenation) is a cleaner alternative that sources hydrogen from water. Current systems are expensive and suffer from incompatibility between membranes and reaction systems. With the support of the Marie Skłodowska-Curie Actions programme, the MemFreeElectro project aims to develop a novel membrane-free electrohydrogenation electrolyser, demonstrated through the conversion of nitrobenzene to aniline. Progressing from proof of concept to a lab-scale prototype and techno-economic assessment, this interdisciplinary approach combining electrochemistry, reactor design and process engineering could deliver a scalable, cost-effective green hydrogenation platform adaptable to a wide range of chemical processes.

Objective

The ongoing green transition requires the replacement of carbon-intensive chemical processes with green alternatives. One such important process is hydrogenation, which is involved in more than 70% of fine chemical production processes. Hydrogenation is the addition of hydrogen to unsaturated organic compounds, a process that has been traditionally carbon-intensive due to the use of fossil-fuel-derived hydrogen. As a green alternative, renewable-powered electrochemical hydrogenation or electrohydrogenation, where hydrogen is sourced directly from water as protons, offers a solution that not only eliminates the CO2 emissions, but also comes with economic and logistical advantages. The MemFreeElectro project addresses these opportunities by proposing a novel membraneless electrochemical cell or electrolyzer for electrohydrogenation of nitrobenzene to aniline as the present case study. The proposed electrolyzer design is based on a membraneless design concept that solves the problem of membrane-reaction system incompatibility, in electrohydrogenation with common membrane/separator-based designs. Additionally, the membraneless design also has lower capital and operational expenditures. In this project, a novel membraneless electrohydrogenation electrolyzer design will be established, from the proof-of-concept to a 50 cm² lab-scale prototype, followed by a technoeconomic assessment. This interdisciplinary project combines electro-organic synthesis, reactor design, and process engineering to establish a scalable and green electrohydrogenation process technology, that can be adapted to other important electrochemical processes. Thus, the MemFreeElectro project falls in line with the Sustainable Development Goal (SDG) 13 i.e. Climate Action, also contributing to EU’s scientific excellence. The project will also have a significant impact on my career, enabling me to develop highly important technical as well as management, leadership, and valorization related skills.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

RUHR-UNIVERSITAET BOCHUM
Net EU contribution
€ 272 456,40
Address
UNIVERSITAETSSTRASSE 150
44801 Bochum
Germany
Region
Nordrhein-Westfalen Arnsberg Bochum, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data

Partners (3)