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Understanding the structural origins of embrittlement in amorphous alloys

Project description

A multi-scale approach to understanding structural decay in metallic glasses

Metallic glasses feature a disordered atomic microstructure that renders them valuable for energy-efficient electronics and biomedical devices. However, their potential is limited because these materials unpredictably turn brittle as they age. Supported by the Marie Skłodowska-Curie Actions programme, the UN-STRUCT project will launch a multi-scale investigation to help uncover why this degradation happens over time. The study will combine atomic-scale computer simulations with synchrotron X-ray analysis and mechanical testing, spanning from the macroscopic down to the nano scales. It will examine how heat treatment changes the glass at an atomic level to cause this sudden brittleness. Decoding these structural changes will ensure metallic glasses can be safely deployed in real-world applications without sudden failure.

Objective

From the glass in windows to plastics and gels, amorphous materials are everywhere in our daily lives. A particular class of amorphous materials are metallic glasses (MGs), which possess a disordered glassy microstructure that is exploited in high-tech applications, including biomedical micro- and nano-electromechanical systems and energy-efficient soft magnetic devices. Whilst exceptional in many regards, MGs suffer from unpredictable property changes that are driven by aging of the glass structure. Indeed, a long-standing question in MG-research is to uncover the structural origin of annealing-induced embrittlement in the glassy solid domain. This is what UN-STRUCT will answer. Building on novel insights from atomistic simulations of glassy microstructural evolution, the project proposes a unique cross-scale experimental approach. This approach combines macro- and nanoscale probing of mechanical performance in the evolving glassy microstructure and its structural correlation lengths, integrated with synchrotron-based extended X-ray absorption fine structure analysis. In concert, the proposed approach will quantify the annealing-induced structural origins of abrupt toughness losses that MGs suffer from. Atomic-scale structural and nano-scale mechanical probing along annealing isotherms will be pursued by the applicant in the hosting group, whereas the link to macroscale mechanical performance will be conducted during a two-months secondment abroad. If successful, UN-STRUCT will solve a long-standing fundamental challenge in glass science, enabling the reliable and safe use of MGs in engineering applications operating at practical, application-relevant time scales. The applicant, experienced in nanomechanical testing, will significantly expand her technical knowledge, methodology skills, and professional network, all of which are relevant for her future employability as principal investigator in the materials engineering field.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

BUNDESANSTALT FUER MATERIALFORSCHUNG UND -PRUEFUNG
Net EU contribution
€ 202 125,12
Address
Unter den Eichen 87
12205 Berlin
Germany
Region
Berlin Berlin Berlin
Activity type
Research Organisations
Links
Total cost
No data

Partners (1)