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Beyond Fullerenes: Next-Generation Electron-Materials in Perovskite Tandem Solar Cells

Project description

Overcoming the material bottleneck to building long-lasting tandem solar cells

Standard silicon solar panels are rapidly approaching their physical efficiency limits. This prompts scientists to develop tandem solar cells that layer a perovskite material on top of silicon to capture more sunlight. However, a major bottleneck threatening this technology is the highly unstable internal layer responsible for transporting electrons. Made from fullerene (carbon-based) molecules, it is susceptible to oxygen-induced degradation and blocks light that should be converted into electricity, undermining the panel’s performance. Supported by the Marie Skłodowska-Curie Actions programme, the NEXT-ETM project aims to redesign this layer using a dual-pronged approach. First, researchers will work to protect the existing carbon layer by developing protecting oxide coatings. The project will first develop protective oxide coatings for the existing fullerene layer while also exploring robust, ultra-transparent replacement materials.

Objective

Perovskite tandem solar cells represent the most promising path to surpass the efficiency limits of conventional silicon photovoltaics. However, their progress is critically hampered by the incumbent electron transport layer (ETL), C60, which suffers from two intrinsic flaws: parasitic absorption of incident light, and chemical instability in the presence of oxygen, which together cap the maximum achievable efficiency and operational lifetime. This project, NEXT-ETM, will overcome this C60 bottleneck through a systematic, dual-pronged approach. Initially, the project will investigate novel encapsulation strategies using metal oxides and polyoxometalates to stabilize the C60 layer and mitigate its degradation. Should this prove insufficient for long-term stability, we will enact a paradigm shift by developing and integrating entirely new, C60-free ETLs. These will be drawn from two innovative material classes: (1) highly transparent inorganic materials (e.g. modified SnO2, POMs), and (2) custom-synthesized organic non-fullerene acceptors (e.g. PDI/NDI derivatives) specifically engineered for optical transparency and chemical robustness. The ultimate goal is to deliver a monolithic tandem solar cell with a certified power conversion efficiency exceeding 36% and a significantly enhanced operational lifetime compared to current fullerene-based devices. By solving this critical material challenge, NEXT-ETM will unlock the full potential of tandem technology and contribute to its commercial viability, reinforcing Europe's leadership in renewable energy.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

LUDWIG-MAXIMILIANS-UNIVERSITAET MUENCHEN
Net EU contribution
€ 217 965,12
Address
GESCHWISTER SCHOLL PLATZ 1
80539 Planegg
Germany
Region
Bayern Oberbayern München, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data